• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Construction of innovative proton conductors by using inorganic-organic hybrid layered crystals

Research Project

Project/Area Number 26410245
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionTokai University

Principal Investigator

Ito Takeru  東海大学, 理学部, 准教授 (50376935)

Co-Investigator(Renkei-kenkyūsha) OZEKI Tomoji  日本大学, 文理学部, 教授 (60214136)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsハイブリッド材料 / ポリ酸 / 層状結晶 / 界面活性剤 / 伝導性 / 単結晶
Outline of Final Research Achievements

Inorganic-organic hybrid crystals containing polyoxometalate inorganic cluster anion and cationic surfactant were successfully synthesized by a simple cation-exchange solution process. Precise control of surfactant molecular structures and synthetic conditions enabled the introduction of proton, lithium, sodium, and magnesium ions. Besides, these hybrid crystals were conductive at 298 to 573 K, which could possibly applicable to new solid electrolytes for fuel-cell, lithium ion, or sodium-ion batteries.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (37 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (6 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 5 results,  Open Access: 4 results) Presentation (21 results) (of which Int'l Joint Research: 8 results,  Invited: 5 results) Book (1 results) Remarks (6 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] Pohang Accelerator Laboratory(韓国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] POSTECH(韓国)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Isomerization-Induced Introduction of Metal Cations into Polyoxomolybdate-Surfactant Hybrid Crystals2016

    • Author(s)
      K. Mikurube, K. Hasegawa, T. Matsumoto, J. Kobayashi, H. Naruke, T. Ito
    • Journal Title

      Inorg. Chem. Commun.

      Volume: 73 Pages: 45-48

    • DOI

      10.1016/j.inoche.2016.09.011

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Conductive Hybrid Crystal Composed from Polyoxomolybdate and Deprotonatable Ionic-Liquid Surfactant2016

    • Author(s)
      J. Kobayashi, R. Kawahara, S. Uchida, S. Koguchi, T. Ito
    • Journal Title

      Int. J. Mol. Sci.

      Volume: 17 Issue: 7 Pages: 994-994

    • DOI

      10.3390/ijms17070994

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Inorganic-Organic Hybrid Surfactant Crystals: Structural Aspects and Functions2016

    • Author(s)
      T. Ito
    • Journal Title

      Crystals

      Volume: 6 Issue: 3 Pages: 24-24

    • DOI

      10.3390/cryst6030024

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Layered and Molecular-Structural Control in Polyoxomolybdate Hybrid Crystals by Surfactant Chain Length2016

    • Author(s)
      T. Ito, M. Nakagawa, J. Kobayashi, T. Matsumoto, S. Otobe, H. Naruke
    • Journal Title

      J.Mol. Struct.

      Volume: 1106 Pages: 220-226

    • DOI

      10.1016/j.molstruc.2015.10.093

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Decisive Interactions between the Heterocyclic Moiety and the Cluster Observed in Polyoxometalate-Surfactant Hybrid Crystals2015

    • Author(s)
      S. Otobe, N. Fujioka, T. Hirano, E. Ishikawa, H. Naruke, K. Fujio and T. Ito
    • Journal Title

      Int. J. Mol. Sci.

      Volume: 16 Issue: 4 Pages: 8505-8516

    • DOI

      10.3390/ijms16048505

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Decisive Interactions between Heterocyclic Moiety and Cluster Observed in Polyoxometalate-Surfactant Hybrid Crystals2015

    • Author(s)
      S. Otobe, N. Fujioka, T. Hirano, E. Ishikawa, H. Naruke, K. Fujio, T. Ito
    • Journal Title

      Int. J. Mol. Sci.

      Volume: 印刷中

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Conductive Oxide Cluster-Surfactant Crystals as Inorganic-Organic Hybrid Solid Electrolyte2017

    • Author(s)
      T. Ito
    • Organizer
      BIT 5th Annual Conference of AnalytiX-2017 (AnalytiX-2017)
    • Place of Presentation
      Fukuoka (Japan)
    • Year and Date
      2017-03-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of inorganic-organic hybrid crystals composed of decavanadate and a surfactant with π electrons2017

    • Author(s)
      T. Misawa, M. Taira, K. Fujio, T. Ito
    • Organizer
      BIT 5th Annual Conference of AnalytiX-2017 (AnalytiX-2017)
    • Place of Presentation
      Fukuoka (Japan)
    • Year and Date
      2017-03-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 含プロトン性デカバナジン酸‐複素環式界面活性剤ハイブリッド結晶の合成2017

    • Author(s)
      三澤 寿之, 平良 みなこ, 藤尾 克彦, 伊藤 建
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属イオン含有型イソポリ酸-重合性イオン液体ハイブリッド結晶の合成2017

    • Author(s)
      清田 祥生, 小林 純, 内田 さやか, 小口 真一, 伊藤 建
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Polymerizable Ionic-Liquid Hybrids with Polyoxometalate Clusters (重合性イオン液体-ポリ酸クラスター複合体)2016

    • Author(s)
      清田 祥生, 小田 龍馬, 渡邉 真幸, 小野 誠司, 小口 真一, 岡村 陽介, 樋口 昌史, 長瀬 裕, 伊藤 建
    • Organizer
      第26回日本MRS年次大会
    • Place of Presentation
      波止場会館(横浜)
    • Year and Date
      2016-12-20
    • Related Report
      2016 Annual Research Report
  • [Presentation] Conductive Polyoxometalate-Surfactant Hybrid Crystals toward Solid Electrolyte (固体電解質への展開を志向した伝導性ポリ酸-界面活性剤ハイブリッド結晶の構築)2016

    • Author(s)
      伊藤 建
    • Organizer
      第26回日本MRS年次大会
    • Place of Presentation
      波止場会館(横浜)
    • Year and Date
      2016-12-20
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Oxide Cluster-Surfactant Hybrid Single Crystals toward Solid Electrolyte2016

    • Author(s)
      T. Ito
    • Organizer
      International Conference on Applied Crystallography (Crystallography 2016)
    • Place of Presentation
      Houston (USA)
    • Year and Date
      2016-10-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 含プロトン性デカバナジン酸‐双頭型界面活性剤ハイブリッド結晶の合成2016

    • Author(s)
      清田 祥生, 小島 達弘, 平良 みなこ, 河野 正規, 伊藤 建
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] サリチル酸チタン錯体の単結晶構造解析とその性質2016

    • Author(s)
      岩崎 克紀, 伊藤 建, 小林 純, 冨田 恒之, 垣花 眞人
    • Organizer
      日本セラミックス協会2016年年会
    • Place of Presentation
      早稲田大学西早稲田キャンパス
    • Year and Date
      2016-03-14
    • Related Report
      2015 Research-status Report
  • [Presentation] Rearrangement of Styrene Oxide by Nickel Complexes in Ionic Liquid2016

    • Author(s)
      W. Prakokich, S. Koguchi, T. Ito, A. Mihoya, J. Kobayashi, W. Chavasiri
    • Organizer
      Pure and applied chemistry international conference 2016 (PACCON 2016)
    • Place of Presentation
      Bangkok (Thailand)
    • Year and Date
      2016-02-09
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Control of Composition and Structure in Decavanadate-Alkylamine Hybrid Layered Crystals2015

    • Author(s)
      Y. Kiyota, T. Kojima, H. Naruke, M. Kawano, T. Ito
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Syntheses of Inorganic-Organic Hybrid Crystals Composed of Octamolybdates and Heterocyclic Surfactants2015

    • Author(s)
      J. Kobayashi, E. Ishikawa, H. Naruke, S. Koguchi, T. Ito
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Conductive Oxide Cluster-Surfactant Hybrid Crystals toward Solid Electrolyte2015

    • Author(s)
      T. Ito
    • Organizer
      International Conference on Small Science 2015 (ICSS 2015)
    • Place of Presentation
      Phuket (Thailand)
    • Year and Date
      2015-11-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 「リチウムイオンを含有したデカバナジン酸-アミン系界面活性剤ハイブリッド結晶の合成及び構造解析2015

    • Author(s)
      清田 祥生, 平良 みなこ, 成毛 治朗, 伊藤 建
    • Organizer
      第5回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2015-10-14
    • Related Report
      2015 Research-status Report
  • [Presentation] Inorganic-Organic Hybrid Crystals Comprising Oxide Clusters and Surfactants toward Solid Electrolyte2015

    • Author(s)
      T. Ito, M. Taira, K. Mikurube, H. Naruke
    • Organizer
      2015 Collaborative Conference on 3D and Materials Research (CC3DMR 2015)
    • Place of Presentation
      Busan (South Korea)
    • Year and Date
      2015-06-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] デカバナジン酸‐双頭型界面活性剤ハイブリッド層状結晶における構造制御2015

    • Author(s)
      清田 祥生, 平良 みなこ, 成毛 治朗, 伊藤 建
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] ケギン型ポリ酸とヘテロ環式界面活性剤を用いた無機-有機ハイブリッド層状結晶の合成と結晶構造2015

    • Author(s)
      乙部 嵯稀, 成毛 治朗, 藤尾 克彦, 伊藤 建
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] Alkali Metal-Introduced Hybrid Crystals Comprising Oxide Cluster and Surfactant (アルカリ金属を導入した酸化物クラスター-界面活性剤ハイブリッド層状結晶)2014

    • Author(s)
      小林 純, 石川 英里, 成毛 治朗, 伊藤 建
    • Organizer
      第24回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館
    • Year and Date
      2014-12-11
    • Related Report
      2014 Research-status Report
  • [Presentation] ポリモリブデン酸-界面活性剤ハイブリッド層状結晶への金属イオンの導入2014

    • Author(s)
      小林 純, 成毛 治朗, 伊藤 建
    • Organizer
      第4回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2014-10-14
    • Related Report
      2014 Research-status Report
  • [Presentation] ヘテロ環式界面活性剤を用いたポリタングステン酸ハイブリッド層状結晶の構造2014

    • Author(s)
      乙部 嵯稀, 藤岡 奈津実, 成毛 治朗, 伊藤 建
    • Organizer
      第4回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2014-10-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Conductive hybrid crystals comprising oxide clusters and surfactants2014

    • Author(s)
      T. Ito, K. Mikurube, M. Taira, H. Naruke
    • Organizer
      IUCr 2014
    • Place of Presentation
      Montreal (Canada)
    • Year and Date
      2014-08-09
    • Related Report
      2014 Research-status Report
  • [Book] 理工系 基礎化学実験2014

    • Author(s)
      岩岡 道夫, 藤尾 克彦, 伊藤 建, 小松 真治, 小口 真一
    • Total Pages
      117
    • Publisher
      三共出版
    • Related Report
      2014 Research-status Report
  • [Remarks]

    • URL

      http://www.u-tokai.ac.jp/staff/academics/852010

    • Related Report
      2016 Annual Research Report
  • [Remarks]

    • URL

      http://www.u-tokai.ac.jp/undergraduate/science/chemistry/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks]

    • URL

      http://www.u-tokai.ac.jp/staff/academics/852010

    • Related Report
      2015 Research-status Report
  • [Remarks]

    • URL

      http://www.u-tokai.ac.jp/undergraduate/science/chemistry/index.html

    • Related Report
      2015 Research-status Report
  • [Remarks]

    • URL

      http://www.u-tokai.ac.jp/staff/academics/852010

    • Related Report
      2014 Research-status Report
  • [Remarks]

    • URL

      http://www.u-tokai.ac.jp/undergraduate/science/chemistry/index.html

    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] ポリ酸と重合性イミダゾリウム化合物の複合体モノマー2016

    • Inventor(s)
      伊藤 建, 長瀬 裕, 小口 真一, 樋口 昌史, 岡村 陽介
    • Industrial Property Rights Holder
      学校法人東海大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-142255
    • Filing Date
      2016-07-20
    • Related Report
      2016 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2022-02-16  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi