| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Outline of Final Research Achievements |
Metal nanoparticle-embedded porous diamond spherical particles were fabricated for active and stable heterogeneous catalyst. From the result of a test using cyclohexane dehydrogenation reaction, the Pt nanoparticle-embedded porous diamond spherical particle (PtNP@PDSP) was found to be more active and stable than commercial Pt-supported carbon black catalyst. Pd nanoparticle-embedded porous diamond spherical particle, fabricated by a similar procedure to PtNP@PDSP, showed higher catalytic activity to Suzuki coupling reaction with various conditions than conventional Pd-supported activated carbon catalyst. Therefore, the concept of metal nanoparticle-embedded porous diamond spherical particle should be a versatile and effective way to fabricate active and stable heterogeneous catalysts.
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