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Development of Novel Electrochemical Capacitor Using Discharged Graphite-fluoride Lithium Primary Battery

Research Project

Project/Area Number 26410250
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Device related chemistry
Research InstitutionGunma University

Principal Investigator

Shiraishi Soshi  群馬大学, 大学院理工学府, 教授 (40292627)

Research Collaborator FUJIMOTO Hiroyuki  大阪ガス株式会社, シニアリサーチャー
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords電気化学キャパシタ / リチウム一次電池 / フッ化黒鉛 / リチウム / 電池 / キャパシタ / ナトリウム
Outline of Final Research Achievements

Graphite fluoride is a graphite intercalation compounds and used as lubricate and cathode material of primary battery. The graphite fluoride-lithium primary (GF-Li) battery has been commercially used because of its high energy density, excellent discharge performance, and low self-discharge property.
The research representative found that the discharged GF-Li battery can be re-charged as new hybrid electrochemical capacitor (Graphite-fluoride Lithium Capacitor: GF-Li Cap.) In this project, the research representative succeeds in realizing the GF-Li Cap. with about 40 Wh L-1 volumetric energy density (normalized by the volume of negative and positive electrodes) and more than 1000 charge-discharge cycle-ability. Additionally, it has been revealed that the positive electrode (discharged graphite-fluoride electrode of GF-Li battery) is charge-discharged as capacitor electrode mainly by electrochemical desorption/adsorption of Li+ cation.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (12 results)

All 2017 2016 2015 2014

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results) Book (1 results)

  • [Journal Article] A carbon electrode prepared by defluorination for use in an electrochemical capacitor2016

    • Author(s)
      白石壮志
    • Journal Title

      TANSO

      Volume: 2016 Issue: 273 Pages: 75-82

    • DOI

      10.7209/tanso.2016.75

    • NAID

      130005164764

    • ISSN
      0371-5345, 1884-5495
    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] フッ化黒鉛アルカリ金属キャパシタの開発と充放電機構の解明2017

    • Author(s)
      白石壮志, 川島 毅, 片桐規晟, 藤本宏之
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 使用済みフッ化黒鉛リチウム一次電池を利用した 新規ハイブリッドキャパシタ(II)2016

    • Author(s)
      川島 毅, 白石壮志, 藤本宏之
    • Organizer
      第43回炭素材料学会年会
    • Place of Presentation
      千葉大学
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] フッ化黒鉛アルカリ金属キャパシタの特性と充放電機構2016

    • Author(s)
      白石壮志, 川島 毅, 白石晏義, 藤本宏之
    • Organizer
      学振117委員会「炭素材料」第319回研究会
    • Place of Presentation
      大阪電気通信大学 駅前キャンパス
    • Year and Date
      2016-09-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] フッ化黒鉛アルカリ金属一次電池からの電気化学キャパシタの構築2016

    • Author(s)
      川島 毅, 白石壮志, 藤本宏之
    • Organizer
      第54回炭素材料夏季セミナー
    • Place of Presentation
      長野県上水内郡飯綱町・富士通労働組合総合センター
    • Year and Date
      2016-08-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] Electrochemical Capacitor Using Graphite-fluoride and Alkali Metal2016

    • Author(s)
      Soshi Shiraishi, Tsuyoshi Kawashima, Yasuyoshi Shiraishi and Hirosyuki Fujimoto
    • Organizer
      炭素国際会議 Carbon2016
    • Place of Presentation
      米国・ステートカレッジ
    • Year and Date
      2016-07-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Graphite-Fluoride Lithium Hybrid Capacitor2015

    • Author(s)
      S. Shiraishi, Y. Shiraishi, and H. Fujimoto
    • Organizer
      66th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2015-10-06
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Graphite-Fluoride Lithium Electrochemical Capacitor2014

    • Author(s)
      Yasuyoshi Shiraishi, Soshi Shiraishi, and Hiroyuki Fujimoto
    • Organizer
      The 4th International Symposium Element Innovation
    • Place of Presentation
      群馬大学(群馬県桐生市)
    • Year and Date
      2014-10-24
    • Related Report
      2014 Research-status Report
  • [Presentation] フッ化黒鉛リチウム一次電池を用いた電気化学キャパシタ(III)2014

    • Author(s)
      白石壮志,白石晏義, 藤本宏之
    • Organizer
      2014年電気化学会秋季大会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-09-27
    • Related Report
      2014 Research-status Report
  • [Presentation] New Electrochemical Capacitors Using Classic Carbon Materials2014

    • Author(s)
      Soshi Shiraishi
    • Organizer
      2nd Spain-Japan Joint Symposium for Advanced Supercapacitors
    • Place of Presentation
      Spain, Malaga
    • Year and Date
      2014-09-18
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] New Hybrid Capacitor Using Discharged Graphite-Fluoride/Li Primary Battery (II)2014

    • Author(s)
      Soshi Shiraishi and Hiroyuki Fujimoto
    • Organizer
      4th German-Japanese Joint Symposium on Carbon materials
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-07-07
    • Related Report
      2014 Research-status Report
  • [Book] Advanced Fluoride-Based Materials for Energy Conversion2015

    • Author(s)
      Soshi Shiraishi and OsamuTanaike
    • Total Pages
      16
    • Publisher
      Elsevier
    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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