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Geometry design of CO2 solid sorbent used in Active Carbon Recycling Energy System for iron making process

Research Project

Project/Area Number 26420159
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Thermal engineering
Research InstitutionWaseda University

Principal Investigator

Takao Nakagaki  早稲田大学, 理工学術院, 教授 (30454127)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsリチウムシリケート / 多孔質体 / 円筒形状 / 拡散律速 / CO2分離回収 / 充填層 / 物質移動 / 未反応核モデル / 円筒 / 比表面積 / 化学反応 / 吸収速度 / 拡散抵抗
Outline of Final Research Achievements

In order to apply the high temperature CO2 separation technology for iron and steel making process, calcination of lithium silicate and pelletization procedure were developed, and the absorption test using cylindrical-hollow-shaped LS pellet designed by numerical calculation. The numerical analysis employed the combination model of chemical reaction and mass transport in the porous media and improved the prediction accuracy of the absorption behavior. The pellet produced according to the optimized design was tested by TG-DTA at 650 degrees C and 30% CO2 concentration. The pellet reached maximum absorption within 10 minutes and kept 78.4% of the initial CO2 loading after 5 heat cycles. Furthermore, the unsteady absorption behavior in the packed-bed reactor was simulated taking heat and mass transport into account. Consequently, the amount of CO2 absorption and the temperature peak shift caused by absorption heat was accurately simulated and agreed with the experimental result.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (8 results)

All 2017 2015 2014 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (4 results) Remarks (3 results)

  • [Journal Article] Numerical Analysis for CO<sub>2</sub> Absorption and Regeneration Behavior in Porous Solid Sorbent by Modified Unreacted-Core Model2014

    • Author(s)
      Takahiro Tanaka, Eiki Tabata, Takao Nakagaki, Mamoru Mizunuma, Yasuko Y. Maruo
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 47 Issue: 7 Pages: 561-568

    • DOI

      10.1252/jcej.13we310

    • NAID

      130004056964

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 溶体モデルによる温度と反応率に対する平衡分圧を考慮したCO2セラミックスの吸収挙動予測2017

    • Author(s)
      津守 悟,若狭 弘隆,渡邊 佑哉,中垣 隆雄
    • Organizer
      第54回日本伝熱シンポジウム
    • Place of Presentation
      大宮ソニックシティ
    • Year and Date
      2017-05-23
    • Related Report
      2016 Annual Research Report
  • [Presentation] 充填効率と拡散抵抗を考慮したCO2吸収セラミックスの形状設計2015

    • Author(s)
      渡邉 佑哉,太田 憲吾,許 曙宏,中垣 隆雄
    • Organizer
      日本機械学会2015年度年次大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2015-09-14
    • Related Report
      2015 Research-status Report
  • [Presentation] Effect of Temperature and Porosity Change on Numerical Analysis of CO2 Absorption Behavior in Porous Solid Sorbent Using the Unreacted-core Model2014

    • Author(s)
      Shuhong Xu,Takahiro Tanaka,Takao Nakagaki
    • Organizer
      The 15th International Heat Transfer Conference
    • Place of Presentation
      Kyoto International Conference Center
    • Year and Date
      2014-08-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 未反応核モデルによる吸収速度に基づくCO2吸収材充填層の吸収挙動の数値解析2014

    • Author(s)
      許曙宏,田中貴紘,中垣隆雄
    • Organizer
      第51回伝熱シンポジウム
    • Place of Presentation
      アクトシティ浜松・コングレスセンター
    • Year and Date
      2014-05-21
    • Related Report
      2014 Research-status Report
  • [Remarks] 早稲田大学 エクセルギー工学研究室

    • URL

      http://www.f.waseda.jp/takao.nakagaki/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 中垣研ホームページ

    • URL

      http://www.f.waseda.jp/takao.nakagaki/

    • Related Report
      2015 Research-status Report
  • [Remarks] 中垣研究室トップページ

    • URL

      http://www.f.waseda.jp/takao.nakagaki/

    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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