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Control of Localized Structure around Eu Ion in Nitride Semiconductor and its Application to Optical Device

Research Project

Project/Area Number 26420271
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionToyohashi University of Technology

Principal Investigator

SEKIGUCHI HIROTO  豊橋技術科学大学, 工学(系)研究科(研究院), 准教授 (00580599)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
KeywordsGaN / Euイオン / 希土類元素 / 発光サイト / 窒化物半導体 / LED / ユーロピウム / 希土類添加半導体 / 希土類添加窒化物半導体
Outline of Final Research Achievements

Eu doped GaN-based semiconductor can be applied to a superior optical device utilizing the great features such as sharp line spectrum and temperature stability of emission wavelength. In this study, to improve the emission efficiency of this material, (1) Selection of host material, (2) emission enhancement mechanism by Mg codoping, (3) growth of high-concentration Eu doped GaN nanocolumn, (4) Fabrication of nanocolumn LED with Eu doped GaN active layer, and (5) fabrication of regularly arranged InGaN:Eu/GaN quantum well nanocolumn were investigated. We successfully achieved the optically activation of Eu ions by widegap-AlGaN, the suppression of concentration quenching by nanocolumn crystals, the sharp emission from nanocolumn LED by current injection, and optical site control by structural control of nanocolumn shape and clarified the preferential formation of specific optical site with high excitation cross section by Mg codoping, the importance of selection of nitrogen source.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (34 results)

All 2017 2016 2015 2014 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 2 results) Presentation (27 results) (of which Int'l Joint Research: 5 results,  Invited: 3 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Stable-wavelength operation of europium-doped GaN nanocolumn light-emitting diodes grown by rf-plasma-assisted molecular beam epitaxy2017

    • Author(s)
      H. Sekiguchi, T. Imanishi, R. Matsuzaki, K. Ozaki, K. Yamane, H. Okada, K. Kishino, A. Wakahara
    • Journal Title

      Elctronics Letters

      Volume: in press Issue: 10 Pages: 666-668

    • DOI

      10.1049/el.2017.0447

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical sites in Eu- and Mg-codoped GaN grown by NH3-source molecular beam epitaxy2016

    • Author(s)
      H. Sekiguchi, M. Sakai, T. Kamada, H. Tateishi, A. Syouji and A. Wakahara
    • Journal Title

      Applied Physics Letter

      Volume: 109 Issue: 15 Pages: 151106-151106

    • DOI

      10.1063/1.4964519

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural and optical properties of Eu-doped GaN nanocolumns on (111) Si substrates grown by RF-plasma-assisted molecular beam epitaxy2016

    • Author(s)
      H. Sekiguchi, S. Nishikawa, T. Imanishi, K. Ozaki, K. Yamane, H. Okada, K. Kishino, A. Wakahara
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 5S Pages: 05FG07-05FG07

    • DOI

      10.7567/jjap.55.05fg07

    • NAID

      210000146532

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Eu3+ luminescence properties of Eu- and Mg codoped AlGaN2015

    • Author(s)
      M. Kanemoto, H. Sekiguchi, K. Yamane, H. Okada, A. Wakahara
    • Journal Title

      Journal of luminescence

      Volume: 印刷中 Pages: 60-66

    • DOI

      10.1016/j.jlumin.2015.04.036

    • Related Report
      2015 Research-status Report 2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Eu,Mg共添加GaNにおける単一発光サイトの観測2017

    • Author(s)
      関口寛人,酒井優,若原昭浩
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜, 神奈川県
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 規則配列GaNナノコラム上へのInGaN:Eu/GaN量子井戸の形成2017

    • Author(s)
      関口寛人,今西智彦,伊達浩平,立石紘己,山根啓輔,岡田浩,岸野克巳,若原昭浩
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜, 神奈川県
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] NH3-MBE法を用いたEu添加GaNナノコラムの成長2017

    • Author(s)
      尾崎耕平,関口寛人,今西智彦,山根啓輔,岡田浩,岸野克巳,若原昭浩
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜, 神奈川県
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] RF-MBE法を用いたEu添加GaNナノコラムLEDデバイスの作製2017

    • Author(s)
      松崎良相,関口寛人,今西智彦,尾崎耕平,山根啓輔,岡田浩,岸野克巳,若原昭浩
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜, 神奈川県
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] RF-MBE法を用いたEu添加GaNを活性層とする赤色LEDの作製2017

    • Author(s)
      友保健介,関口寛人,立石紘己,山根啓輔,岡田浩,若原昭浩
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜, 神奈川県
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Stable luminous Eu site with high excitation efficiency in NH3-MBE grown GaN co-doped with Mg2016

    • Author(s)
      A. Wakahara, H. Sekiguchi, M. Sakai
    • Organizer
      2016 Material Research Society fall meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] RF-MBE法を用いたEu添加GaNナノコラムのⅤ/Ⅲ族供給比依存性2016

    • Author(s)
      今西智彦、関口寛人、尾崎耕平、山根啓輔、岡田浩、岸野克巳、若原昭浩
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷲メッセ, 新潟県
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] MBE法において窒素源がEu,Mg共添加GaNの発光サイト形成に与える影響2016

    • Author(s)
      立石紘己, 関口寛人, 酒井優, 山根啓輔, 岡田浩, 若原昭浩
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷲メッセ, 新潟県
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Growth of Eu doped GaN thin film and nanocolumns grown by molecular beam epitaxy2016

    • Author(s)
      H. Sekiguchi, H. Tateishi, T. Imanishi, K. Yamane, H. Okada, K. Kishino, A. Wakahara
    • Organizer
      Energy Materials Nanotechnology meeting on Epitaxy
    • Place of Presentation
      Budapest, Hungary
    • Year and Date
      2016-09-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effect of nitrogen sourcEffect of nitrogen source on optical properties of Eu- and Mg-codoped GaN grown by molecular beam epitaxy2016

    • Author(s)
      立石紘己, 関口寛人, 山根啓輔, 岡田浩, 若原昭浩
    • Organizer
      第35回電子材料シンポジウム
    • Place of Presentation
      ラフォーレ琵琶湖, 滋賀県
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Structural and optical properties of Eu doped GaN nanocolumns grown by RF-plasma-assisted molecular beam epitaxy2016

    • Author(s)
      尾崎耕平,関口寛人,今西智彦,山根啓輔,岡田浩,岸野克巳,若原昭浩
    • Organizer
      第35回電子材料シンポジウム
    • Place of Presentation
      ラフォーレ琵琶湖, 滋賀県
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Eu concentration dependence of Eu doped GaN nanocolumns grown by RF-plasma-assisted molecular beam epitaxy2016

    • Author(s)
      T. Imanishi, H. Sekiguchi, K. Ozaki, K. Yamane, H. Okada, K. Kishino, A. Wakahara
    • Organizer
      the 43rd International Symposium on Compound Semiconductors
    • Place of Presentation
      Toyama International Conference Center, Toyama, Japan
    • Year and Date
      2016-06-26
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] RF-MBE法を用いたEu添加GaNナノコラムのEu濃度依存性2016

    • Author(s)
      今西智彦、関口寛人、西川聡志、尾崎耕平、山根啓輔、岡田浩、岸野克巳、若原昭浩
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学,東京都目黒区
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Growth of Eu doped GaN nanocolumns grown by rf-MBE2015

    • Author(s)
      S. Nishikawa, H. Sekiguchi, S. Nishikawa, T. Imanishi, K. Ozaki, K. Yamane, H. Okada, K. Kishino, A. Wakahara
    • Organizer
      6th International Symposium on Growth of III-Nitride
    • Place of Presentation
      Hamamatsu, Japan
    • Year and Date
      2015-11-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Eu incorporation mechanism of Eu doped GaN grown by rf-MBE2015

    • Author(s)
      H. Tahara, H. Sekiguchi, K. Yamane, H. Okada, A. Wakahara
    • Organizer
      6th International Symposium on Growth of III-Nitride
    • Place of Presentation
      Hamamatsu, Japan
    • Year and Date
      2015-11-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Eu,Mg共添加GaNの発光サイトの安定性の検討2015

    • Author(s)
      立石紘己,関口寛人,山根啓輔,岡田浩,若原昭浩
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場,愛知県名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] RF-MBE 法を用いたEu 添加GaNナノコラムの成長2015

    • Author(s)
      西川聡志,関口寛人,今西智彦,山根啓輔,岡田浩,岸野克巳,若原昭浩
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場,愛知県名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] RF-MBE法によるEu添加GaN成長におけるEu取り込みに関する検討2015

    • Author(s)
      田原浩行, 関口寛人, 山根啓輔, 岡田浩, 若原昭浩
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場,愛知県名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] RF-MBE法によるEu添加GaN成長の成長条件依存性2015

    • Author(s)
      田原浩行, 関口寛人, 山根啓輔, 岡田浩, 若原昭浩
    • Organizer
      第34回電子材料シンポジウム
    • Place of Presentation
      ラフォーレ琵琶湖, 滋賀県守山市
    • Year and Date
      2015-07-15
    • Related Report
      2015 Research-status Report
  • [Presentation] GaNナノコラム上Eu添加GaNナノコラムの成長2015

    • Author(s)
      西川聡志,関口寛人,今西智彦,山根啓輔,岡田浩,若原昭浩
    • Organizer
      第34回電子材料シンポジウム
    • Place of Presentation
      ラフォーレ琵琶湖, 滋賀県守山市
    • Year and Date
      2015-07-15
    • Related Report
      2015 Research-status Report
  • [Presentation] Eu, Mg共添加AlGaNのAl組成が発光サイトに与える影響2015

    • Author(s)
      金本匡祥,関口寛人,山根啓輔,岡田浩,若原昭浩
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-11 – 2015-03-15
    • Related Report
      2014 Research-status Report
  • [Presentation] 貫通転位がEu添加GaNの発光特性に及ぼす影響2015

    • Author(s)
      田原浩行, 関口寛人, 山根啓輔, 岡田浩, 若原昭浩
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-11 – 2015-03-15
    • Related Report
      2014 Research-status Report
  • [Presentation] Eu, Mg共添加GaNのEu濃度が発光サイトに及ぼす影響2015

    • Author(s)
      鎌田拓歩, 関口寛人, 山根啓輔, 岡田浩, 若原昭
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-11 – 2015-03-15
    • Related Report
      2014 Research-status Report
  • [Presentation] Sharp red light-emitting diodes using optical site selected Eu doped GaN active layer2015

    • Author(s)
      Hiroto Sekiguchi, Masayoshi Kanemoto, Keisuke Yamane, Hiroshi Okada, Akihiro Wakahara
    • Organizer
      Materials Challenges in Alternative & Renewable Energy
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-02-24 – 2015-02-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Eu, Mg共添加GaNの発光特性のEu濃度依存性2014

    • Author(s)
      9.鎌田拓歩, 関口寛人, 山根啓輔, 岡田浩, 若原昭浩
    • Organizer
      第3回結晶工学未来塾年末講演会
    • Place of Presentation
      学習院大学
    • Year and Date
      2014-11-13
    • Related Report
      2014 Research-status Report
  • [Presentation] EuドープAlGaNへのMg共添加による影響2014

    • Author(s)
      10.金本匡祥,関口寛人,酒井優,東海林篤,岡田浩,若原昭浩
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Optical site control of Eu doped GaN by Mg codoping2014

    • Author(s)
      Hiroto Sekiguchi, Ryota Matsumura, Masayoshi Kanemoto, Takuho Kamada, Masaru Sakai, Atsushi Syouji, Akihiro Wakahara
    • Organizer
      18th International Conference on Molecular Beam Epitaxy
    • Place of Presentation
      Flagstaff, Arizona, USA
    • Year and Date
      2014-09-07 – 2014-09-12
    • Related Report
      2014 Research-status Report
  • [Book] OPTRONICS2016

    • Author(s)
      関口寛人
    • Total Pages
      4
    • Publisher
      オプトロニクス社
    • Related Report
      2015 Research-status Report
  • [Book] 化学工業2015

    • Author(s)
      関口寛人、若原昭浩
    • Total Pages
      5
    • Publisher
      化学工業社
    • Related Report
      2015 Research-status Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www.int.ee.tut.ac.jp/oeg/

    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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