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Research on high-k germanates and their direct formations on germanium substrates at low-temperature

Research Project

Project/Area Number 26420281
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionTokyo University of Science, Suwa

Principal Investigator

Fukuda Yukio  諏訪東京理科大学, 工学部, 教授 (50367546)

Co-Investigator(Kenkyū-buntansha) 岡本 浩  弘前大学, 理工学研究科, 教授 (00513342)
王谷 洋平  諏訪東京理科大学, 工学部, 准教授 (40434485)
佐藤 哲也  山梨大学, 総合研究部, 准教授 (60252011)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords誘電体薄膜 / 表面・界面物性 / 超薄膜 / MOS構造 / プラズマ酸化 / 原子層堆積法 / 金属ジャーマネイト / ゲルマニウム / 誘電体物性 / ラジカル酸化 / MIS構造 / MIS構造
Outline of Final Research Achievements

In the present research subject, we have investigated background kinetics of metal-germanate formations on germanium substrates by radical-enhanced atomic layer deposition (REALD), where microwave-generated oxygen radicals are used as an oxidant of surface-adsorbed metal precursors, and its application to the formations of gate-dielectrics of Ge-MOSFETs. We have found that argon ions with kinetic energies of ~5 eV enhance the germanate formations. We have also succeeded in the formations of Ge-MOS capacitor with an oxide-equivalent thickness of 1 nm.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (18 results)

All 2016 2015 2014 Other

All Journal Article (2 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (14 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results) Remarks (2 results)

  • [Journal Article] Role of low-energy ion irradiation in the formation of an aluminum germanate layer on a germanium substrate by radical-enhanced atomic layer deposition2016

    • Author(s)
      Y. Fukuda, D. Yamada, T. Yokohira, K. Yanachi, C. Yamamoto, B. Yoo, J. Yamanaka, T. Sato, T. Takamatsu, and H. Okamoto
    • Journal Title

      Journal of Vacuum Science & Technology A

      Volume: 34 Issue: 2

    • DOI

      10.1116/1.4932039

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Interface State Density Evaluation of p-Type and n-Type Ge/GeNx Structures by Conductance Technique2015

    • Author(s)
      T. Iwasaki, T. Ono, Y. Otani, Y. Fukuda, and H. Okamoto
    • Journal Title

      Electronics and Communications in Japan

      Volume: 98 Issue: 6 Pages: 8-15

    • DOI

      10.1002/ecj.11655

    • NAID

      210000188429

    • Related Report
      2015 Research-status Report
  • [Presentation] Effects of gate-electrode metals and postdeposition treatments on the electrical properties of Al2O3/GeO2 gate stack grown on Ge substrate by radical-enhanced atomic layer deposition2016

    • Author(s)
      Yukio Fukuda, Daichi Yamada, Yohei Otani, Chiaya Yamamoto, Junji Yamanaka, Tetsuya Sato, Hiroshi Okamoto
    • Organizer
      ALD 2016 Ireland
    • Place of Presentation
      Dublin Convention Center, Dublin
    • Year and Date
      2016-07-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ラジカル援用原子層堆積法で形成したAl2O3/GeO2/p-Ge基板上のゲート電極金属が電気的特性に及ぼす影響2016

    • Author(s)
      山田大地、王谷洋平、山本千綾、山中淳二、佐藤哲也、岡本浩、福田幸夫
    • Organizer
      応用物理学会北陸・信越支部第3回有機・無機エレクトロニクスシンポジウム
    • Place of Presentation
      石川県政記念しいのき迎賓館
    • Year and Date
      2016-07-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Radical-enhanced ALD法によるGe-MIS構造の欠陥評価(2)2016

    • Author(s)
      成田英史、山田大地、福田幸夫、岡本浩
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Effects of postdeposition treatments on the electrical properties of Al2O3/GeO2 gate stack grown on Ge substrate by radical enhanced atomic layer deposition2016

    • Author(s)
      H. Okamoto, D. Yamada, H. Narita, Y. Otani, C. Yamamoto, J. Yamanaka, T. Sato, and Y. Fukuda
    • Organizer
      9th International Workshop on New Group IV Semiconductor Nanoelectronics
    • Place of Presentation
      Tohoku University
    • Year and Date
      2016-01-11
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] REALD形成Al2O3/GeO2/p-GeMOSキャパシターの電気的特性に及ぼすゲート電極金属の影響2016

    • Author(s)
      山田大地、王谷洋平、山本千綾、山中淳二、佐藤哲也、岡本浩、福田幸夫
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      新潟市・朱鷺メッセ
    • Related Report
      2016 Annual Research Report
  • [Presentation] Radical-enhanced ALD法によるGe-MIS構造の欠陥評価2015

    • Author(s)
      成田英史、山田大地、福田幸夫、鹿糠洋介、岡本浩
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] Radical-enhanced ALD法によって形成したAlジャーマネイト/Ge界面とその近傍の欠陥評価2015

    • Author(s)
      成田英史、山田大地、福田幸夫、鹿糠洋介、岡本浩
    • Organizer
      電子通信情報学会電子部品・材料研究会(CPM)
    • Place of Presentation
      弘前大学
    • Year and Date
      2015-08-10
    • Related Report
      2015 Research-status Report
  • [Presentation] Role of low-energy ion irradiation in the formation of aluminum germanate layer on germanium substrate by radical-enhanced atomic layer deposition2015

    • Author(s)
      T. Yokohira, K. Yanachi, D. Yamada, C. Yamamoto, B. Yoo, J. Yamanaka, T. Sato, T. Takamatsu, H. Okamoto, and Y. Fukuda
    • Organizer
      The 13th International Symposium on Sputtering and Plasma Process
    • Place of Presentation
      Kyoto Research Park
    • Year and Date
      2015-07-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Radical-Enhanced ALD法によるGe基板上Alジャーマネイトの形成機構に関する検討2015

    • Author(s)
      横平知也、梁池昂生、柳炳學、山本千綾、山中淳二、佐藤哲也、岡本浩、福田幸夫
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] RE-ALD形成Al2O3/GeO2/p-Geの電気的特性に及ぼす熱処理と酸素ラジカル照射の効果2015

    • Author(s)
      梁池昂生、 横平知也、 山田大地、 王谷洋平、 柳炳學、 関渓太、 佐藤哲也、 福田幸夫
    • Organizer
      応用物理学会第20回ゲートスタック研究会
    • Place of Presentation
      三島
    • Year and Date
      2015-01-30
    • Related Report
      2014 Research-status Report
  • [Presentation] Formation mechanism of aluminum germanate layer on germanium substrate by radical-enhanced atomic layer deposition2015

    • Author(s)
      H. Okamoto, T. Yokohira, K. Yanachi, C. Yamamoto, B. Yoo, J. Yamanaka, T. Takamatsu, H. Narita, and Y. Fukuda
    • Organizer
      The 8th International Workshop on New Group IV Semiconductor Nanoelectronics
    • Place of Presentation
      Sendai
    • Year and Date
      2015-01-29 – 2015-01-30
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] ALD形成Al2O3/GeO2/p-Geの電気的特性に及ぼす熱処理効果の検討2014

    • Author(s)
      梁池昂生、横平知也、山田大地、王谷洋平、関渓太、佐藤哲也、福田幸夫
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Al2O3/GeO2/p-Geの電気的特性に及ぼす酸素ラジカル照射の効果2014

    • Author(s)
      王谷洋平、梁池昂生、横平知也、山田大地、関渓太、佐藤哲也、福田幸夫
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Formation of Metal Germanate Interlayer for High-k/Ge Metal-Oxide-Semiconductor Structures by Atomic Layer Deposition Assisted by Microwave-generated Atomic Oxygen2014

    • Author(s)
      Y. Otani, K. Yanachi, H. Ishizaki, Y. Fukuda, C. Yamamoto, J. Yamanaka, and T.Sato
    • Organizer
      The 14th International Conference on Atomic Layer Deposition
    • Place of Presentation
      Kyoto
    • Year and Date
      2014-06-15 – 2014-06-18
    • Related Report
      2014 Research-status Report
  • [Remarks]

    • URL

      http://www/tsus.ac.jp/ridai/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 理大データベース

    • URL

      http://www/tus.ac.jp/ridai/

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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