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Fabrication of high ionic conductive electrolyte thin films by sputtering and their application to fuel cells

Research Project

Project/Area Number 26420284
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionTsuruoka National College of Technology

Principal Investigator

UCHIYAMA KIYOSHI  鶴岡工業高等専門学校, その他部局等, 教授 (80403327)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords燃料電池 / 薄膜 / 低温作動化 / 配向性制御 / 導電性酸化物 / プロトン伝導体 / 酸化物薄膜 / 中温域 / プロトン伝導
Outline of Final Research Achievements

In this study, we used Pd-plated porous stainless-steel substrates as a substrate for thin film SOFCs (Solid Oxide Fuel Cells). Low temperature operation as low as 400 C was obtained; however, it showed small power generation property of several mW/cm2, which needs 2 decades improvements for the actual SOFC applications. The origin of this low power generations was appeared to be the result of the solid structure of a cathode, which limits oxygen supply to the reaction field. Thus, we investigated new materials which is suitable for our SOFCs and found sol-gel derived LaNiO3 is a suitable candidate as the cathode material. We have been fabricating new SOFCs with this new cathode to optimize SOFC properties.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (29 results)

All 2016 2015 2014

All Journal Article (4 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 4 results) Presentation (25 results) (of which Int'l Joint Research: 14 results,  Invited: 2 results)

  • [Journal Article] Fabrication of highly (110)-oriented BaCeO3-based proton-conductive oxide thin films by RF magnetron sputtering method2016

    • Author(s)
      Tomoya Sato, Takaaki Inoue, Daichi Ichinose, Hiroshi Funakubo and Kiyoshi Uchiyama
    • Journal Title

      Jpn.J.Appl.Phys.

      Volume: 55 Issue: 2S Pages: 02BC19-02BC19

    • DOI

      10.7567/jjap.55.02bc19

    • NAID

      210000146088

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fabrication of Highly Oriented Proton Conductive Oxide Thin Films2016

    • Author(s)
      Tomoya Sato, Daichi Ichinose, Hiroshi Funakubo and Kiyoshi Uchiyama
    • Journal Title

      Science of Advanced Materials

      Volume: 未定

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Low Temperature Operation of Solid Oxide Fuel Cells (SOFCs) with Proton Conductive Electrolyte Deposited on Pd Foil Substrates2016

    • Author(s)
      Tetsuro Kariya, Hiroki Tanaka, Kiyoshi Uchiyama, Tomoki Hirono2, Tetsuji Kuse2, Mitsunori Henmi4, Mitsutaka Hirose, Isao Kimura, Koukou Suu, and Hiroshi Funakubo
    • Journal Title

      Science of Advanced Materials

      Volume: 未定

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Intermediate-temperature operation of solid oxide fuel cells (IT-SOFCs) with thin film proton conductive electrolyte2015

    • Author(s)
      T Kariya, K Uchiyama, H Tanaka, T Hirono, T Kuse, K Yanagimoto, M Henmi, M Hirose, I Kimura, K Suu and H Funakubo
    • Journal Title

      J. Phys.: Conf. Ser.

      Volume: 660 Pages: 012057-012057

    • DOI

      10.1088/1742-6596/660/1/012057

    • Related Report
      2015 Research-status Report
    • Acknowledgement Compliant
  • [Presentation] Evaluation of proton-conductive oxide thin-films and their application for Solid Oxide Fuel Cells2016

    • Author(s)
      T. Inoue, T. Sato, M. Yamaguchi, K.i Uchiyama
    • Organizer
      JSTS 2016/ISTS 2016
    • Place of Presentation
      ガジャマダ大学、インドネシア
    • Year and Date
      2016-07-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] {110}一軸配向ペロブスカイト型酸化物薄膜の作製と結晶構造解析2016

    • Author(s)
      佐藤 智也  木村 純一  一ノ瀬 大地  三村 和仙  舟窪 浩  内山 潔
    • Organizer
      第63回 応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学 大岡山キャンパス(目黒)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] エアロゾルデポジション法による多孔質酸化物膜の作製2016

    • Author(s)
      井上 貴明  志藤 泰紀  佐藤 智也  明渡 純  内山 潔
    • Organizer
      第63回 応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学 大岡山キャンパス(目黒)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] スピンコートによるLaNiO3薄膜の微構造制御2016

    • Author(s)
      熊谷 佳郎  内山 潔
    • Organizer
      第63回 応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学 大岡山キャンパス(目黒)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 交流インピーダンス法による酸化物薄膜の伝導性評価2016

    • Author(s)
      山口 雅仁  井上 貴明 佐藤 智也 内山 潔
    • Organizer
      第63回 応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学 大岡山キャンパス(目黒)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] High Quality Deposition of Proton Conductive Oxide Thin Films and its Application to Fuel Cells2016

    • Author(s)
      K. Uchiyama, T. Kariya, T. Sato, M. Yamaguchi, T. Inoue, T. Kumagai, H. Tanaka, T. Hirono, T. Kuse, K. Yanagimoto, H. Funakubo
    • Organizer
      International Conference on Technologically Advanced Materials and Asian Meeting on Ferroelectricity (ICTAM-AMF10)
    • Place of Presentation
      デリー大学、インド
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Deposition of high quality proton conductive perovskites and their application to fuel cells2016

    • Author(s)
      K. Uchiyama, T. Kariya, T. Sato, M. Yamaguchi, T. Inoue, T. Kumagai, H. Tanaka, T. Hirono, T. Kuse, K. Yanagimoto, H. Funakubo
    • Organizer
      European Materials Society 2016 Spring Meeting
    • Place of Presentation
      Lille Grand Palais、フランスリール市
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Optimization of Deposition Conditions of Y-Doped SrZrO3 Thin Films Fabricated by PulsedLaser Deposition Method2016

    • Author(s)
      K. UCHIYAMA, H. TANAKA, T. OIKAWA, H. FUNAKUBO
    • Organizer
      International Union of Materials Research Societies-International Conference on Electronic Materials (IUMRS-ICEM2016)
    • Place of Presentation
      SINTEC、シンガポール
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Growth of {110}-oriented Perovskite-type Proton Conductive Oxide Thin Films by RF Magnetron Sputtering Method2016

    • Author(s)
      T. Sato, T. Kiguchi, T.J. Konno, J. Kimura, D. Ichinose, T. Mimura, H. Funakubo, K. Uchiyama
    • Organizer
      18th International Conference on Crystal Growth and Epitaxy (ICCGE-18)
    • Place of Presentation
      名古屋国際会議場、名古屋
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High quality depositions of proton conductive perovskite thin film2016

    • Author(s)
      内山潔、佐藤智也、一ノ瀬 大地、舟窪浩
    • Organizer
      第26回日本MRS年次大会(MRS-J2016) 国際シンポジウムセッション
    • Place of Presentation
      横浜市開港記念会館他、横浜市
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Porous LaNiO3 Thin-film on SrZr0.8Y0.2O3-δ and Its Chemical Stability on High Temperature and Humidified Atmosphere2016

    • Author(s)
      熊谷佳郎、内山潔
    • Organizer
      第26回日本MRS年次大会(MRS-J2016) 国際シンポジウムセッション
    • Place of Presentation
      横浜市開港記念会館他、横浜市
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Evaluation of dependence on protonconductive oxide thin films with doping amount of Yttrium2016

    • Author(s)
      山口雅仁、佐藤智也、井上貴明、内山潔
    • Organizer
      第26回日本MRS年次大会(MRS-J2016) 国際シンポジウムセッション
    • Place of Presentation
      横浜市開港記念会館他、横浜市
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Intermediate-Temperature Solid Oxide Fuel Cells using Thin Film Electrolyte of Proton-Conductive Oxide deposited on a Pdplated Porous Stainless-Steel2016

    • Author(s)
      井上貴明、佐藤智也、熊谷佳郎、山口雅仁、内山潔
    • Organizer
      第26回日本MRS年次大会(MRS-J2016) 国際シンポジウムセッション
    • Place of Presentation
      横浜市開港記念会館他、横浜市
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pt/Si 基板上への{110}高配向ぺロブスカイト薄膜の直接成膜2016

    • Author(s)
      内山 潔,佐藤智也,一ノ瀬大地,木村純一,井上貴明,三村和仙,舟窪 浩
    • Organizer
      第33回 強誘電体応用会議
    • Place of Presentation
      コープイン京都、京都市
    • Related Report
      2016 Annual Research Report
  • [Presentation] Evaluation of Chemical Stability of RF-magnetron Sputtered Proton Conductive Oxide Thin Films2015

    • Author(s)
      T. Sato, D. Ichinose, H. Funakubo and K. Uchiyama
    • Organizer
      MRS-J 2015
    • Place of Presentation
      横浜情報文化センター他(横浜市)
    • Year and Date
      2015-12-08
    • Related Report
      2015 Research-status Report
  • [Presentation] Intermediate-temperature operation of solid oxide fuel cells (IT-SOFCs) with thin film proton conductive electrolyte2015

    • Author(s)
      T Kariya, K Uchiyama, H Tanaka, T Hirono, T Kuse, K Yanagimoto, M Henmi, M Hirose, I Kimura, K Suu and H Funakubo
    • Organizer
      PowerMEMS 2015
    • Place of Presentation
      Royal Sonesta Boston、USA
    • Year and Date
      2015-12-01
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electric Property of Strained {110}-oriented (Ba0.5Sr0.5)TiO3 (BST) Thin Films Fabricated by RF-magnetron Sputtering2015

    • Author(s)
      内山 潔  大島 直也  江原 祥隆  及川 貴弘  田中 宏樹  佐藤 智也  内田 寛  山田 智明  舟窪 浩
    • Organizer
      IUMRS-ICAM2015
    • Place of Presentation
      済州国際コンベンションセンター(韓国済州島)
    • Year and Date
      2015-10-25
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of Highly Oriented Proton Conductive Oxide Thin Films2015

    • Author(s)
      佐藤 智也  一ノ瀬 大地  舟窪 浩  内山 潔
    • Organizer
      IUMRS-ICAM2015
    • Place of Presentation
      済州国際コンベンションセンター(韓国済州島)
    • Year and Date
      2015-10-25
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高配向性プロトン伝導性酸化物薄膜の作製と化学的安定性評価2015

    • Author(s)
      佐藤 智也  一ノ瀬 大地  舟窪 浩  内山 潔
    • Organizer
      日本セラミックス協会 東北北海道支部研究発表会
    • Place of Presentation
      米沢市市民文化会館(米沢)
    • Year and Date
      2015-10-16
    • Related Report
      2015 Research-status Report
  • [Presentation] RFマグネトロンスパッタリング法による{110}高配向Ba(Ce,Y)O3ペロブスカイト薄膜の作製2015

    • Author(s)
      佐藤 智也  一ノ瀬 大地  舟窪 浩 内山 潔
    • Organizer
      第76回 応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(名古屋)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electric Measurement of Proton Conductive Perovskite Thin Films2015

    • Author(s)
      Tomoya SATO, Takaaki INOUE, Hiroshi FUNAKUBO, Kiyoshi UCHIYAMA
    • Organizer
      EM-NANO 2015
    • Place of Presentation
      朱鷺メッセ(新潟市)
    • Year and Date
      2015-06-16 – 2015-06-19
    • Related Report
      2014 Research-status Report
  • [Presentation] Electric Measurement of Proto Conductive Perovskite Thin Films2015

    • Author(s)
      佐藤 智也  井上 貴明  舟窪 浩  内山 潔
    • Organizer
      EM-NANO2015
    • Place of Presentation
      朱鷺メッセ(新潟)
    • Year and Date
      2015-06-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Proton Conductive Oxide Thin Films for Fuel Cells2014

    • Author(s)
      K. Uchiyama, T. Sato, H. Funakubo
    • Organizer
      第24回日本MRS年次大会
    • Place of Presentation
      開港記念館(横浜市)
    • Year and Date
      2014-12-10 – 2014-12-12
    • Related Report
      2014 Research-status Report
  • [Presentation] プロトン伝導性SrZrO3薄膜の作製と評価2014

    • Author(s)
      稲毛一昭、佐藤 智也、内山潔
    • Organizer
      日本セラミックス協会東北北海道支部研究発表会
    • Place of Presentation
      にぎわい交流館AU(秋田市)
    • Year and Date
      2014-11-06 – 2014-11-07
    • Related Report
      2014 Research-status Report
  • [Presentation] スパッタ法を用いたプロトン伝導性酸化物薄膜の成膜条件依存性2014

    • Author(s)
      佐藤 智也、内山 潔
    • Organizer
      2014応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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