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Approaches to 10 times intensification of rare-earth doped materials: Identification of luminescence quenching factors using microwave absorption properties

Research Project

Project/Area Number 26420287
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

ISHII Masashi  国立研究開発法人物質・材料研究機構, 先端材料解析研究拠点 表界面物理計測グループ, 主幹研究員 (90281667)

Research Collaborator Hamilton Bruce  
FUJIWARA Yasufumi  
Taikan OHMI  
Crowe Iain  
FUCHI Shingo  
YOSHIKAZU Takeda  
HIROSAKI Naoto  
KOIZUMI Atsushi  
YOSHIMATSU Ryo  
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords希土類 / マイクロ波 / 蛍光体 / 半導体 / 伝搬係数 / 高調波 / 応答解析 / ノイズ分析 / ゆらぎ / 雑音解析 / ガラス
Outline of Final Research Achievements

Since rare-earths are luminous at various wavelengths intrinsic to the elements, assembling rare-earth doped materials into devices realizes selectable-color emitters suitable for diverse industrial purposes. The rare-earth dopants which couple with surroundings electronically and/or energetically may have positive and negative effects in the emission intensity. We identified the atomic scale interactions by using electromagnetic technique in microwave region. Various high frequency properties such as microwave propagation, charge response, emission response, propagation of harmonics, and electronic noise, are successfully applied to the evaluations of local charge and energy transfers/dissipations. The microwave properties explained emission properties of the doped rare-earth consistently. From the results, guidelines for intensification of frontier devices such as GaN:Eu red LED are drawn up.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (42 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (11 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 10 results,  Acknowledgement Compliant: 10 results,  Open Access: 5 results) Presentation (26 results) (of which Int'l Joint Research: 8 results,  Invited: 4 results) Remarks (3 results)

  • [Int'l Joint Research] University of Manchester/University of Surrey(英国)

    • Related Report
      2015 Research-status Report
  • [Int'l Joint Research] McMaster University(Canada)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Dimerization of emission centers in Eu-doped GaN red light-emitting diode: cooperative charge capturing using valence states coupling2016

    • Author(s)
      M. Ishii, A. Koizumi, and Y. Fujiwara
    • Journal Title

      Journal of Physics: Condensed Matter

      Volume: 29 Issue: 2 Pages: 025702-025702

    • DOI

      10.1088/0953-8984/29/2/025702

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] 「ゆらぎ」で知る発光の機構2016

    • Author(s)
      石井真史
    • Journal Title

      Phosphor Research Society, The 363rd Meeting Technical Digest

      Volume: 363 Pages: 1-6

    • Related Report
      2016 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] 「光らなかった」過程を測る2016

    • Author(s)
      石井真史
    • Journal Title

      応用物理

      Volume: 85 Pages: 223-227

    • NAID

      130007715318

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Trapping of injection charges in emission centers of GaN:Eu red LED characterized with 1/f noise involved in forward current2016

    • Author(s)
      M. Ishii, A. Koizumi, and Y. Fujiwara
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 1 Pages: 015801-015801

    • DOI

      10.7567/jjap.55.015801

    • NAID

      210000145898

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Three-dimensional spectrum mapping of bright emission centers: investigating the brightness-limiting process in Er-doped GaN red LEDs2015

    • Author(s)
      M. Ishii, A. Koizumi, and Y. Fujiwara
    • Journal Title

      Applied Physics Letters

      Volume: 107 Issue: 8 Pages: 0821061-4

    • DOI

      10.1063/1.4929531

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Interaction of Nd dopants with broadband emission centers in Bi2O3-B2O3 glass: Local energy balance and its influence on optical properties2015

    • Author(s)
      M. Ishii, S. Fuchi, and Y. Takeda
    • Journal Title

      Journal of Physics: Condensed Matter

      Volume: 27 Issue: 39 Pages: 3954021-8

    • DOI

      10.1088/0953-8984/27/39/395402

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Nanoscale determinant to brighten up GaN:Eu red light-emitting diode: Local potential of Eu-defect complexes2015

    • Author(s)
      Masashi Ishii, Atsushi Koizumi, and Yasufumi Fujiwara
    • Journal Title

      Journal of Applied Physics

      Volume: 117 Issue: 15 Pages: 1553071-7

    • DOI

      10.1063/1.4918662

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enhancement in light efficiency of a GaN:Eu red light-emitting diode by pulse-controlled injected charges2014

    • Author(s)
      M. Ishii, A. Koizumi, and Y. Fujiwara
    • Journal Title

      Applied Physics Letters

      Volume: 105 Issue: 17

    • DOI

      10.1063/1.4900840

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] “Linkage emission” of infrared-excited Auger electrons: A luminescence quenching mechanism for conductive Si nanocrystals2014

    • Author(s)
      M. Ishii, I. F. Crowe, M. P. Halsall, A. P. Knights, R. M. Gwilliam, and B. Hamilton
    • Journal Title

      Journal of Applied Physics

      Volume: 116 Issue: 6

    • DOI

      10.1063/1.4893029

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Time-resolved analysis of charge responses determining luminescence properties2014

    • Author(s)
      M. Ishii
    • Journal Title

      Journal of Materials Research

      Volume: 29 Issue: 20 Pages: 2367-2373

    • DOI

      10.1557/jmr.2014.252

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Discrimination between energy transfer and back transfer processes for GaAs host and Er luminescent dopants using electric response analysis2014

    • Author(s)
      M. Ishii, A. Koizumi, Y. Takeda, and Y. Fujiwara
    • Journal Title

      Journal of Applied Physics

      Volume: 115 Issue: 13

    • DOI

      10.1063/1.4870808

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] GaN:Eu赤色LEDの発光ゆらぎ:「遅れ」再発光過程の観測2017

    • Author(s)
      石井真史、稲葉智宏、藤原康文
    • Organizer
      応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Dimerized emission centers in Eu-doped GaN red light-emitting diode: cooperative charge capturing and multiple satellite emission of Eu emission centers2016

    • Author(s)
      M. Ishii, A. Koizumi, Y. Fujiwara
    • Organizer
      2016 MRS Fall Meeting & Exhibition
    • Place of Presentation
      Hynes Convention Center,Boston
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] GaN:Eu赤色LEDの発光中心の二量化:高調波成分分析を使ったEu-Eu結合評価2016

    • Author(s)
      石井真史、小泉淳、藤原康文
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fluorescence lifetime fluctuation: A new approach to photoexcitation/relaxation mechanisms2016

    • Author(s)
      M. Ishii, R. Yoshimatsu, N. Hirosaki, K. Ohmi
    • Organizer
      International Conference on Rare Earths
    • Place of Presentation
      Hokkaido University
    • Year and Date
      2016-06-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Delayed Eu2+ excitaiton in (Sr, Ba)Al2Si3O4N4:Eu2+: Excitation energy transfer from host material to emission centers discovered with fluorescence fluctuation2016

    • Author(s)
      M. Ishii, R. Yoshimatsu, N. Hirosaki, K. Ohmi
    • Organizer
      International Conference on Rare Earths
    • Place of Presentation
      Hokkaido University
    • Year and Date
      2016-06-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] GaN:Eu赤色LED発光中心の三次元マッピングによる解析2016

    • Author(s)
      石井 真史,小泉淳,藤原康文
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京都
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 蛍光寿命ゆらぎ:蛍光体発光機構解明の新しいアプローチ2016

    • Author(s)
      石井真史, 吉松良, 廣崎尚登, 大観光徳
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京都
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Relationship between electrical and luminescence properties of GaN/Eu-doped GaN multiple-nanolayer structures investigated with impedance spectroscopy2016

    • Author(s)
      Wanxin Zhu, Masashi Ishii, Atsushi Koizumi, Yasufumi Fujiwara
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京都
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 「ゆらぎ」で知る発光の機構2016

    • Author(s)
      石井真史
    • Organizer
      第363回蛍光体同学会講演会
    • Place of Presentation
      化学会館ホール
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Optoelectronic communications with GaN:Eu red LED: Messages from atomic scale emission centers2015

    • Author(s)
      M. Ishii
    • Organizer
      The 2nd International Workshop on Luminescent Materials 2015
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2015-12-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Gap between energetically and optically favorable emission centers in GaN:Eu red LED: Necessity of local distortion control2015

    • Author(s)
      M. Ishii, A. Koizumi, and Y. Fujiwara
    • Organizer
      The 6th International Symposium on Growth of III-Nitrides
    • Place of Presentation
      Hamamatsu, Japan
    • Year and Date
      2015-11-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Boost in intensity of GaN:Eu red LED by motion control of injection charges and its application to diagnosis of Eu emission centers2015

    • Author(s)
      M. Ishii, A. Koizumi, and Y. Fujiwara
    • Organizer
      The 6th International Symposium on Growth of III-Nitrides
    • Place of Presentation
      Hamamatsu, Japan
    • Year and Date
      2015-11-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] GaN:Eu赤色LEDの強発光中心の選択解析:サイト選択型PDES法による注入電荷2015

    • Author(s)
      石井 真史,小泉淳,藤原康文
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] GaN:Eu赤色LEDのノイズ分析:発光中心の電荷捕獲特性を知る新しいアプローチ2015

    • Author(s)
      石井 真史,小泉淳,藤原康文
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] ステップ光を使ったP添加Siナノ結晶の発光効率の倍増:発光と電導の時間的分離2015

    • Author(s)
      石井真史, Iain Crowe, Matthew Halsall, Andrew Knights, Russell Gwilliam, Bruce Hamilton
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] Brightening GaN:Eu red LED by back-and-forth motion of injection charges and its applied to site-selective analyses of emission centers2015

    • Author(s)
      M. Ishii, A. Koizumi, and Y. Fujiwara
    • Organizer
      The 4th International Conference on the Physics of Optical Materials and Devices
    • Place of Presentation
      Budva, Montenegro
    • Year and Date
      2015-08-31
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 「光らなかった」過程から観た希土類添加ガラス:欠陥‐希土類相互作用によるエネルギー損失の直接観測2015

    • Author(s)
      石井 真史,渕 真悟,竹田 美和
    • Organizer
      第32回希土類討論会
    • Place of Presentation
      鹿児島市
    • Year and Date
      2015-05-21
    • Related Report
      2015 Research-status Report
  • [Presentation] Electrical activation of confined phosphorus donors in size controlled silicon nanocrystals2015

    • Author(s)
      I F Crowe, M Ishii, M P Halsall, R M Gwilliam, A P Knights, B Hamilton
    • Organizer
      European Materials Research Society 2015 Spring Meeting
    • Place of Presentation
      Lille, France
    • Year and Date
      2015-05-11
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] GaN:Eu赤色LEDの発光効率改善法:パルス駆動による注入電荷共振2015

    • Author(s)
      石井 真史,小泉淳,藤原康文
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      平塚市
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 「光らなかった」過程から観た希土類添加ガラス:欠陥電荷の局在/非局在と消光の関係2015

    • Author(s)
      石井 真史,渕 真悟,竹田 美和
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      平塚市
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Charge transfer dynamics of “Bright” and “Dark” Si-nc’s2014

    • Author(s)
      M. Ishii
    • Organizer
      Workshop on Advancement of Group IV Nanostructures Nanophotonics and Nanoelectronics
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      2014-11-18 – 2014-11-19
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Si-nc:Pにおける赤外励起オージェ電子放出と熱励起放出の相補性2014

    • Author(s)
      石井 真史,Iain Crowe,Matthew Halsall,Andrew Knights,Russell Gwilliam,Bruce Hamilton
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      札幌
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 希土類添加ガラスのマイクロ波応答:「光らなかった」過程の動的分析2014

    • Author(s)
      石井 真史,渕 真悟,竹田 美和
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      札幌
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Selective atomic-scale-evaluation of luminescent rare-earth dopants: Site-selective x-ray absorption fine structure using x-ray excited optical luminescence (XEOL-XAFS)2014

    • Author(s)
      M. Ishii
    • Organizer
      19th International Conference on Ternary and Multinary Compounds
    • Place of Presentation
      Niigata, Japan
    • Year and Date
      2014-09-01 – 2014-09-05
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 半導体に添加したErへのエネルギー伝搬・逆伝搬の実観測2014

    • Author(s)
      石井真史、小泉淳、藤原康文
    • Organizer
      第31回希土類討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-05-22 – 2014-05-23
    • Related Report
      2014 Research-status Report
  • [Presentation] Energy transfer and back transfer between GaAs host and luminescent Er dopants discriminated with electric response measurement2014

    • Author(s)
      M. Ishii, A. Koizumi, Y. Takeda, Y. Fujiwara
    • Organizer
      The 5th International Workshop on Photoluminescence in Rare-Earths: Photonic Materials and Devices
    • Place of Presentation
      Sebastian, Spain
    • Year and Date
      2014-05-13 – 2014-05-16
    • Related Report
      2014 Research-status Report
  • [Remarks] 物質材料研究機構 先端材料解析研究拠点 表界面物理計測グループ

    • URL

      http://www.nims.go.jp/research/group/surface-physics-characterization/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 表界面物理計測グループ

    • URL

      http://www.nims.go.jp/research/group/surface-physics-characterization/

    • Related Report
      2015 Research-status Report
  • [Remarks] NIMS Researchers Database SAMURAI

    • URL

      http://samurai.nims.go.jp/ISHII_Masashi-j.html

    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2022-02-03  

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