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Development of a highly efficiency thermoelectric nanocomposite including one, two layers graphene sheets in a ceramic

Research Project

Project/Area Number 26420672
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

HOSHIKAWA Yasuto  東北大学, 多元物質科学研究所, 助教 (90527839)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords複合材料・物性 / ナノ材料 / セラミックス / 電気・電子材料 / 構造・機能材料 / 炭素材料 / 電子・電気材料
Outline of Final Research Achievements

Inorganic nanoparticles coated by one, two graphene layers are very attractive for a raw material that has excellent physical and chemical properties of both the graphene and the nanoparticle. In this study, carbon-coated ceramic nanoparticles were prepared by CVD method and new functional nanocomposites were developed by using their nanoparticles. A monolithic carbon-tungsten carbide nanocomposite was prepared from carbon-coated tungsten carbide nanoparticles synthesized from tungstic acid by CVD using organic reagent. The monolith has high conductivity (106 S/m), negative thermoelectric power (-15 μV/K) and low thermal conductivity (10 W/mK), and shows a good thermoelectric property (ZT=0.08 - 0.15) as a result. A carbon monolith with good conductivity (4.2×103 S/m) and open-through nanopores was prepared by using carbon-coated alumina nanoparticles. The monolith entrapping enzymes reduces oxygens in a pH 5.0 buffer solution; i.e. it shows functionality as an enzymatic electrode.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (34 results)

All 2016 2015 2014 Other

All Journal Article (7 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Acknowledgement Compliant: 2 results) Presentation (21 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results) Remarks (6 results)

  • [Journal Article] Analysis of the interaction between rubber polymer and carbon black surfaces by efficient removal of physisorbed polymer from carbon-rubber composites2016

    • Author(s)
      Yasuto Hoshikawa, Baigang An, Susumu Kashihara, Takafumi Ishii, Mariko Ando, Syuji Fujisawa, Koutarou Hayakawa, Satoshi Hamatani, Hiroshi Yamada, Takashi Kyotani
    • Journal Title

      Carbon

      Volume: 99 Pages: 148-156

    • DOI

      10.1016/j.carbon.2015.12.003

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Real Understanding of the Nitrogen-Doping Effect on the Electrochemical Performance of Carbon Materials by Using Carbon-Coated Mesoporous Silica as a Model Material2016

    • Author(s)
      Alberto Castro-Muñiz, Yasuto Hoshikawa, Takatoshi Kasukabe, Hiroshi Komiyama, Takashi Kyotani
    • Journal Title

      Langmuir

      Volume: 32 Issue: 8 Pages: 2127-2135

    • DOI

      10.1021/acs.langmuir.5b03667

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improving the Direct Electron Transfer in Monolithic Bioelectrodes Prepared by Immobilization of FDH Enzyme on Carbon-Coated Anodic Aluminum Oxide Films2016

    • Author(s)
      Alberto Castro-Muñiz, Yasuto Hoshikawa, Hiroshi Komiyama, Wataru Nakayama, Tetsuji Itoh, Takashi Kyotani
    • Journal Title

      Frontiers in Materials

      Volume: 3

    • DOI

      10.3389/fmats.2016.00007

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Size-Dependent Filling Behavior of UV-Curable Di(meth)acrylate Resins into Carbon-Coated Anodic Aluminum Oxide Pores of around 20 nm2016

    • Author(s)
      M. Nakagawa, A. Nakaya, Y. Hoshikawa, S. Ito, N. Hiroshiba, T. Kyotani
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 8 Issue: 44 Pages: 30628-30634

    • DOI

      10.1021/acsami.6b10561

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 酵素電極の電極面に固定化するラッカーゼの配向制御法2016

    • Author(s)
      干川康人
    • Journal Title

      ぶんせき

      Volume: 4 Pages: 146-146

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Size-tailored synthesis of gold nanoparticles and their facile deposition on AAO-templated carbon nanotubes via electrostatic self-assembly: Application to H2O2 detection2015

    • Author(s)
      4.P. Pannopard, C. Boonyuen, C. Warakulwit, Y. Hoshikawa, T. Kyotani, J. Limtrakul
    • Journal Title

      Carbon

      Volume: 94 Pages: 836-844

    • DOI

      10.1016/j.carbon.2015.07.057

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A quantitative analysis of carbon edge sites and an estimation of graphene sheet size in high-temperature treated, non-porous carbons2014

    • Author(s)
      Takafumi Ishii, Susumu Kashihara, Yasuto Hoshikawa, Jun-ichi Ozaki, Naokatsu Kannari, Kazuyuki Takai, Toshiaki Enoki, Takashi Kyotani
    • Journal Title

      Carbon

      Volume: 80 Pages: 135-145

    • DOI

      10.1016/j.carbon.2014.08.048

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Carbon Coating to Inorganic Nanoporous Materials by CVD Method and Their Electrochemical Applications2016

    • Author(s)
      Yasuto Hoshikawa, Alberto Castro-Muñiz, Takashi Kyotani
    • Organizer
      第43回炭素材料学会年会 International Session
    • Place of Presentation
      千葉大学けやき会館(千葉県・千葉市)
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ゴム-フィラー界面構造解析を目的とした炭素被覆アルミナナノ粒子/ゴム複合材料の作製2016

    • Author(s)
      川口 玲, 赤羽秀信, 石井孝文, 山田 浩, 干川康人, 京谷 隆
    • Organizer
      第43回炭素材料学会年会
    • Place of Presentation
      千葉大学けやき会館(千葉県・千葉市)
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] ナノポーラスカーボンモノリスを用いた酵素電極の開発2016

    • Author(s)
      今井 雄大, Castro-Muniz Alberto, 野崎功一, 山根祥平, 伊藤徹二, 干川康人, 京谷 隆
    • Organizer
      第43回炭素材料学会年会
    • Place of Presentation
      千葉大学けやき会館(千葉県・千葉市)
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 表面化学性状の異なる 炭素被覆アルミナナノ粒子を用いた ゴム-フィラー界面構造の解析2016

    • Author(s)
      干川康人, 川口玲, 石井孝文, 京谷 隆, 赤羽秀信, 山田 浩
    • Organizer
      学振炭素材料117委員会第320回委員会
    • Place of Presentation
      東京大学本郷キャンパス工学部8号館(東京都・文京区)
    • Year and Date
      2016-11-11
    • Related Report
      2016 Annual Research Report
  • [Presentation] Preparations of carbon-coated alumina nanoparticles with different surface chemical properties and applications as fillers for rubbers2016

    • Author(s)
      Rei Kawaguchi, Hidenobu Akahane, Takafumi Ishii, Hiroshi Yamada, Yasuto Hoshikawa, Takashi Kyotani
    • Organizer
      平成28年度化学系学協会東北大会
    • Place of Presentation
      いわき明星大学(福島県・いわき市)
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] 酵素担持を目的とした三次元ナノポーラスカーボンモノリスの作製2016

    • Author(s)
      干川康人, 今井雄大, 京谷 隆, 野崎功一, 天野良彦, 山根祥平, 伊藤徹二
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学 東広島キャンパス(広島県・東広島市)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 表面化学性状の異なる炭素被覆アルミナナノ粒子の調製とゴム用フィラーとしての応用2016

    • Author(s)
      干川康人, 川口 玲, 石井孝文, 京谷 隆, 赤羽秀信, 山田 浩
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学 東広島キャンパス(広島県・東広島市)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 表面化学性状の異なる炭素被覆アルミナナノ粒子の調製とゴム用フィラーとしての応用2016

    • Author(s)
      川口 玲, 赤羽秀信, 石井孝文, 山田 浩, 干川康人, 京谷 隆
    • Organizer
      第54回炭素材料夏季セミナー
    • Place of Presentation
      富士通労働組合総合センター(長野県飯縄町)
    • Year and Date
      2016-08-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] Orientation Control of Laccase Immobilized in a Carbon-coated Anodic Aluminum Oxide Film for Enhancing Electrocatalytic Activity2016

    • Author(s)
      Yasuto Hoshikawa, Castro-Muniz Alberto, Hanako Tawata, Takashi Kyotani, Kouichi Nozaki, Shohei Yamane, Tetsuji Itoh
    • Organizer
      Carbon2016
    • Place of Presentation
      USA,State College
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Carbon-Coated Mesoporous Silica as a Model Material of Porous Carbons in Electrochemical Applications2016

    • Author(s)
      Alberto Castro-Muniz, 干川康人, 粕壁隆敏, 込山 拓, 京谷 隆
    • Organizer
      学振117委員会第317回委員会
    • Place of Presentation
      東京都市大学世田谷キャンパス(東京都・世田谷区)
    • Year and Date
      2016-04-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Analysis of the interaction between rubber polymer and carbon black surface2015

    • Author(s)
      干川康人, 安 百鋼, 柏原 進, 石井孝文, 安東真理子, 藤澤秀忠, 早川光太郎, 浜谷悟司, 山田 浩, 京谷 隆
    • Organizer
      第42回炭素材料学会年会
    • Place of Presentation
      関西大学千里山キャンパス(吹田)
    • Year and Date
      2015-12-02
    • Related Report
      2015 Research-status Report
  • [Presentation] アルミナナノ粒子を利用したカーボンモノリスの作製と酵素電極への応用2015

    • Author(s)
      今井雄大, Castro-Muniz Alberto, 野崎功一, 伊藤徹二, 干川康人, 京谷 隆
    • Organizer
      第42回炭素材料学会年会
    • Place of Presentation
      関西大学千里山キャンパス(吹田
    • Year and Date
      2015-12-02
    • Related Report
      2015 Research-status Report
  • [Presentation] 炭素-炭化タングステンナノ複合体の作製と熱電素子への応用2015

    • Author(s)
      菅原 敬, 干川康人, 宮崎 譲, 小野木伯薫, 京谷 隆
    • Organizer
      第42回炭素材料学会年会
    • Place of Presentation
      関西大学千里山キャンパス(吹田
    • Year and Date
      2015-12-02
    • Related Report
      2015 Research-status Report
  • [Presentation] ラッカーゼを固定化した炭素被覆ナノポーラスアルミナ膜の作製と酵素電極としての評価2015

    • Author(s)
      干川康人, Castro- Muniz Alberto, 多和田華子, 京谷 隆, 野崎功一, 天野良彦, 山根祥平, 伊藤徹二
    • Organizer
      日本セラミックス協会第28回秋季シンポジウム
    • Place of Presentation
      富山大学五福キャンパス(富山)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Mesoporous Silica Coated with Nitrogen-Doped Carbon as Model Material for Electrochemical Application2015

    • Author(s)
      Alberto Castro-Muniz, Yasuto Hoshikawa, Dae-Soo Yang, Hirotomo Nishihara, Jong-Sung Yu, Takashi Kyotani
    • Organizer
      平成27年度化学系学協会東北大会
    • Place of Presentation
      弘前大学文京キャンパス(弘前)
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report
  • [Presentation] CVD法を用いた無機ナノ材料への均一炭素被覆と電気デバイスへの応用2015

    • Author(s)
      干川康人, Castro-Muñiz Alberto, 京谷隆
    • Organizer
      第53回炭素材料夏季セミナー
    • Place of Presentation
      東京ソラマチ(東京都墨田区)
    • Year and Date
      2015-08-10
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Quantitative analysis of rubber polymers chemically bonded to the edge sites of carbon black2015

    • Author(s)
      Yasuto Hoshikawa, Baigang An, Susumu Kashihara, Takafumi Ishii, Mariko Ando, Syuji Fujisawa, Koutarou Hayakawa, Satoshi Hamatani, Hiroshi Yamada, Takashi Kyotani
    • Organizer
      CARBON2015
    • Place of Presentation
      German, Dresden
    • Year and Date
      2015-07-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Uniform coating of N-doped carbon on pore walls in mesoporous silica for electrochemical applications2014

    • Author(s)
      Alberto Castro-Muniz, Yasuto Hoshikawa, Hiroshi Komiyama, Takashi Kyotani
    • Organizer
      第41回炭素材料学会年会
    • Place of Presentation
      福岡
    • Year and Date
      2014-12-08 – 2014-12-10
    • Related Report
      2014 Research-status Report
  • [Presentation] Siラジカルを利用したメソポーラスシリカの均一炭素被覆2014

    • Author(s)
      干川康人、Castro-Muniz Alberto、込山拓、京谷隆
    • Organizer
      2014年度第2回ナノカーボン研究会
    • Place of Presentation
      東京
    • Year and Date
      2014-11-17
    • Related Report
      2014 Research-status Report
  • [Presentation] 炭素被覆アルミナナノ粒子を用いた高導電性炭素-アルミナナノ複合体の作製2014

    • Author(s)
      干川康人,野村啓太,石井孝文,岡井誠,赤津隆,篠田豊,京谷隆
    • Organizer
      日本セラミックス協会第27回秋季シンポジウム
    • Place of Presentation
      鹿児島
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Research-status Report
  • [Presentation] Preparation of carbon-alumina nanocomposite with excellent electrical conductivity from carbon-coated alumina nanoparticles2014

    • Author(s)
      Keita Nomura, Yasuto Hoshikawa, Takafumi Ishii, Makoto Okai, Takashi Akatsu, Yutaka Shinoda, Takashi Kyotani
    • Organizer
      Carbon2014
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Remarks] 東北大学多元物質科学研究所高分子・ハイブリッド材料研究センター京谷研究室

    • URL

      http://www.tagen.tohoku.ac.jp/labo/kyotani/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 東北大学多元物質科学研究所京谷研究室

    • URL

      http://www.tagen.tohoku.ac.jp/labo/kyotani/

    • Related Report
      2015 Research-status Report
  • [Remarks] 東北大学多元物質科学研究所高分子・ハイブリッド材料研究センター

    • URL

      http://www.tagen.tohoku.ac.jp/center/PHyM/research.html

    • Related Report
      2015 Research-status Report
  • [Remarks] ナノマクロ物質・デバイス・システム創製アライアンス研究者データベース

    • URL

      http://star-five.net/

    • Related Report
      2015 Research-status Report
  • [Remarks] 多元物質科学研究所業績データベース

    • URL

      http://db.tagen.tohoku.ac.jp/php/db/

    • Related Report
      2015 Research-status Report
  • [Remarks] 東北大学多元物質科学研究所 京谷研究室

    • URL

      http://www.tagen.tohoku.ac.jp/labo/kyotani/

    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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