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Study on phenomena of freezing of orbital degree of freedom and nano-structure control with ion diffusion

Research Project

Project/Area Number 26420681
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionKyushu Institute of Technology

Principal Investigator

Horibe Yoichi  九州工業大学, 大学院工学研究院, 准教授 (80360048)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsナノ構造 / 透過型電子顕微鏡 / 電子回折 / 軌道整列
Outline of Final Research Achievements

Evolution and control factors of checkerboard nano-structure with orbital ordering accompanied by ionic diffusion in Mn-based transition-metal spinel oxides have been investigated by simultaneous observations in real- and reciprocal spaces by transmission electron microscopy. The checkerboard nano-structure in this system is suggested to be consisted under subtle balance between local and long-range strain field, resulting in collapse with large domain size after evolution. Furthermore, the presence of oxygen vacancies is found to play a key role to form the checkerboard nano-structure.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (16 results)

All 2017 2016 2015 2014

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 1 results) Presentation (11 results) (of which Int'l Joint Research: 1 results,  Invited: 2 results)

  • [Journal Article] Characteristic Features of the Modulated Structure Appearing in the Multiferroic Material Bi1-xSmxFeO3 around x = 0.152017

    • Author(s)
      M. Nomoto, T. Inoshita, Y. Inoue, Y. Horibe, and Y. Koyama
    • Journal Title

      Materials Science Forum

      Volume: 879 Pages: 1393-1398

    • DOI

      10.4028/www.scientific.net/msf.879.1393

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Large-scale phase separation with nano-twin domains in manganite spinel (Co,Fe,Mn)3O42016

    • Author(s)
      Y. Horibe, S. Takeyama, and S. Mori
    • Journal Title

      AIP Conf. Proc

      Volume: 1763 Pages: 050005-050005

    • DOI

      10.1063/1.4961358

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Crystallographic features in the vicinity of the morphotropic phase boundary in the multiferroic material Bi1-xSmxFeO32016

    • Author(s)
      M. Nomoto, T. Inoshita, Y. Inoue, Y. Horibe, and Y. Koyama
    • Journal Title

      MRS Advances

      Volume: 1 Issue: 9 Pages: 573-578

    • DOI

      10.1557/adv.2016.155

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Features of the ferroelectric domain structure in the multiferroic material YbMnO32016

    • Author(s)
      T. Inoshita, Y. Inoue, Y. Horibe, and Y. Koyama
    • Journal Title

      MRS Advances

      Volume: 1 Issue: 9 Pages: 591-596

    • DOI

      10.1557/adv.2016.154

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The hysteresis properties analysis of Fe-4 wt% Si prepared by high purity metallurgy2016

    • Author(s)
      Z. Lei, T. Horiuchi, I. Sasaki, C. Kaido, M. Takezawa, S. Hata, Y. Horibe, T. Ogawa, and H. Era
    • Journal Title

      Journal of the Magnetics Society of Japan

      Volume: 40 Pages: 8-12

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] ビスマスフェライトBi1-xNdxFeO3における構造相転移2017

    • Author(s)
      堀部陽一、渡邉謙、野元将志、井上靖秀、小山泰正
    • Organizer
      日本物理学会2017年年会
    • Place of Presentation
      大阪
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 六方晶遷移金属化合物の構造階層性に由来する特異なドメイン構造2017

    • Author(s)
      堀部陽一
    • Organizer
      日本金属学会2015年春期大会
    • Place of Presentation
      東京
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 置換型ビスマスフェライトBi1-xNdxFeO3における反強誘電変位2016

    • Author(s)
      堀部陽一、渡邉謙、木口賢紀、今野豊彦、野元将志、井上靖秀、小山泰正
    • Organizer
      日本物理学会2016年秋期大会
    • Place of Presentation
      金沢
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Transmission- Electron Microscopy Studies on Topological Domain Structure in Transition Metal Compounds2016

    • Author(s)
      Y. Horibe
    • Organizer
      4th International Symposium on Applied Engineering and Sciences
    • Place of Presentation
      北九州
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 遷移金属カルコゲナイドFexTaS2における反位相カイラルドメイン構造2015

    • Author(s)
      堀部陽一, J. J. Yang, Y. -H. Cho, X. Luo, S. B. Kim, 浅田敏広, 谷村誠, Y. S. Oh, S.-W. Cheong
    • Organizer
      日本金属学会2015年秋期大会
    • Place of Presentation
      福岡
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Nd置換型BiFeO3における4倍超構造の結晶学的特徴2015

    • Author(s)
      渡邉謙, 堀部陽一
    • Organizer
      日本金属学会2015年秋期大会
    • Place of Presentation
      福岡
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Nd置換したBiFeO3における反強誘電相の結晶学的特徴2015

    • Author(s)
      渡邉謙, 堀部陽一
    • Organizer
      平成27年度合同学術講演会
    • Place of Presentation
      福岡
    • Year and Date
      2015-06-06
    • Related Report
      2015 Research-status Report
  • [Presentation] 暗視野法を用いた遷移金属カルコゲナイドFe1/4TaS2における反位相ドメイン分布の決定2015

    • Author(s)
      堀部陽一, 浅田敏広, 谷村誠, S. B. Kim, S.-W. Cheong
    • Organizer
      日本顕微鏡学会第71回学術講演会
    • Place of Presentation
      京都
    • Year and Date
      2015-05-13
    • Related Report
      2015 Research-status Report
  • [Presentation] インターカレート型遷移金属カルコゲナイドFexTaS2におけるトポロジカル分域構造2015

    • Author(s)
      堀部陽一, J. J. Yang,Y.-H. Cho,X. Luo,S. B. Kim, 浅田敏広, 谷村誠, Y. S. Oh, S.-W. Cheong
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Research-status Report
  • [Presentation] opological domain structures in intercalated transition metal dichalcogenide FexTaS22015

    • Author(s)
      Yoichi Horibe
    • Organizer
      Quantum Materials Symposium 2015
    • Place of Presentation
      Muju, South Korea
    • Year and Date
      2015-02-09 – 2015-02-13
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] "スピネル型酸化物(Co,Fe,Mn)3O4におけるナノチェッカーボード組織変化の直接観察2014

    • Author(s)
      堀部陽一, 森茂生, S.-W. Cheong
    • Organizer
      日本金属学会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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