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VOC gas sensor using ZnO hierarchical structures

Research Project

Project/Area Number 26420688
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

Saito Noriko  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主任研究員 (20354417)

Co-Investigator(Renkei-kenkyūsha) SAKAGUCHI Isao  物質・材料研究機構, 機能性材料研究拠点, グループリーダー (20343866)
ADACHI Yutaka  物質・材料研究機構, 機能性材料研究拠点, 主幹研究員 (30354418)
WATANABE Ken  九州大学, 総合理工学研究科, 准教授 (90552480)
HANEDA Hajime  物質・材料研究機構, 経営企画部門経営戦略室, 調査役 (70354420)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsセンサ / 酸化亜鉛 / ガスセンサ / 粒子 / 階層構造
Outline of Final Research Achievements

Volatile Organic Compounds (VOC) gas sensor using ZnO with hierarchical structures was investigated.
ZnO particles were synthesized solvothermally from the solution of zinc acetate and hexamethylenetetramine in ethylene glycol and water. ZnO spherical particles composed of pyramid-shaped crystallites, which were radially aligned along the c-axis, and the broken particles were obtained. We evaluated their gas sensing properties to ethanol gas and demonstrated that the collapse of the spherical particles led to a high sensitivity.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (21 results)

All 2016 2015 2014 Other

All Int'l Joint Research (1 results) Journal Article (6 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 6 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (12 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] レンヌ第一大学(フランス)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Gas sensing properties of <i>c</i>-axis-oriented Al-incorporated ZnO films epitaxially grown on (11-20) sapphire substrates using pulsed laser deposition2016

    • Author(s)
      Y. Adachi, K. Watanabe, N. Saito, I. Sakaguchi, T. Suzuki
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 124 Issue: 6 Pages: 668-672

    • DOI

      10.2109/jcersj2.15319

    • NAID

      130005155655

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Isotope tracer investigation and ab-initio simulation of anisotropic hydrogen transport and possible multi-hydrogen centers in tin dioxide2016

    • Author(s)
      K. Watanabe, I. Sakaguchi, M. Hashiguchi, N. Saito, E. Ross, H. Haneda, T. Ohsawa, N. Ohashi
    • Journal Title

      Journal of Applied Physics

      Volume: 119 Issue: 22 Pages: 225704-225704

    • DOI

      10.1063/1.4953387

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Evaluation of sensor property for hydrogen and ethanol of zinc-doped tin-dioxide thin films fabricated by rf sputtering2016

    • Author(s)
      I. Sakaguchi, N. Saito, K. Watanabe, Y. Adachi, T. Suzuki
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 124 Issue: 6 Pages: 714-716

    • DOI

      10.2109/jcersj2.16015

    • NAID

      130005155663

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Inorganic Molybdenum Octahedral Nanosized Cluster Units, Versatile Functional Building Block for Nanoarchitectonics2015

    • Author(s)
      S. Cordier, F. Grasset, Y. Molard, M. Amela-Cortes, R. Boukherroub, S. Ravaine, M. Mortier, N. Ohashi, N. Saito, H. Haneda
    • Journal Title

      Journal of Inorganic and Organometallic Polymers and Materials

      Volume: 25 Issue: 2 Pages: 189-204

    • DOI

      10.1007/s10904-014-0112-2

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Microscopic and Isotope Tracer Study on the Growth of Spherical ZnO Particles in Water-Ethylene Glycol Solvent2015

    • Author(s)
      Saito, Noriko; Matsumoto, Kenji; Watanabe, Ken; Hashiguchi, Minako; Sakaguchi, Isao; Haneda, Hajime
    • Journal Title

      Crystal Growth & Design

      Volume: 印刷中 Issue: 6 Pages: 2609-2619

    • DOI

      10.1021/cg5014297

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of ZnO Particles with Hierarchical Structures2014

    • Author(s)
      齋藤紀子
    • Journal Title

      Journal of the Japan Society of Powder and Powder Metallurgy

      Volume: 61 Issue: 9 Pages: 443-447

    • DOI

      10.2497/jjspm.61.443

    • NAID

      130004713478

    • ISSN
      0532-8799, 1880-9014
    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 酸化亜鉛粒子のソルボサーマル合成とガスセンサへの応用2016

    • Author(s)
      齋藤紀子
    • Organizer
      第34回IEEE CPMT Society (2016)
    • Place of Presentation
      東京大学(東京都)
    • Year and Date
      2016-12-02
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 安達裕,坂口勲, 鈴木拓,齋藤紀子2016

    • Author(s)
      エピタキシャルZnO薄膜のガスセンシング特性
    • Organizer
      The 9th International Workshop on ZnO and Related Materials
    • Place of Presentation
      国立台湾大学(台北市,台湾)
    • Year and Date
      2016-10-30
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Solvothermal Synthesis of ZnO Particles and Gas Sensor Application2016

    • Author(s)
      齋藤紀子,坂口勲, 渡邉賢,羽田肇,島ノ江憲剛
    • Organizer
      The 6th NIMS-UR1-CNRS-SG workshop
    • Place of Presentation
      アクロス福岡(福岡県福岡市)
    • Year and Date
      2016-10-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] タングステン添加酸化亜鉛薄膜の水素とエタノールガスのセンサ特性2016

    • Author(s)
      坂口勲, 齋藤紀子,安達裕,渡邉賢, 鈴木拓
    • Organizer
      第36回エレクトロセラミックス研究討論会
    • Place of Presentation
      富士通勤労会館(神奈川県川崎市)
    • Year and Date
      2016-10-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 酸化亜鉛薄膜ガスセンサ特性の結晶面依存性2016

    • Author(s)
      安達裕,坂口勲, 齋藤紀子,鈴木拓
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      新潟コンベンションセンター(新潟県、新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] ソルボサーマル法により合成した酸化亜鉛粒子のガスセンサ特性2016

    • Author(s)
      齋藤紀子,坂口勲, 渡邉賢,羽田肇
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      広島大学(広島県広島市)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 不純物添加がZnO薄膜のガスセンシング特性に及ぼす影響2016

    • Author(s)
      安達裕,坂口勲, 齋藤紀子,鈴木拓
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学(広島県広島市)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] W添加酸化亜鉛とZn添加酸化スズ薄膜のセンサ特性2016

    • Author(s)
      坂口勲,安達裕,渡邉賢,齋藤紀子,鈴木拓
    • Organizer
      日本セラミックス協会2016年 年会
    • Place of Presentation
      早稲田大学、東京
    • Year and Date
      2016-03-14
    • Related Report
      2015 Research-status Report
  • [Presentation] Elemental and isotopic analysis of Solid state Interface and Nano-materials with Secondary Ion Massspectrometry2015

    • Author(s)
      H. HANEDA, I. SAKAGUCGI, K. WATANABE, N. SAITO, and N. OHASHI
    • Organizer
      5th UR1 - CNRS - NIMS - Saint-Gobain Workshop
    • Place of Presentation
      フランス レンヌ市
    • Year and Date
      2015-10-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of Al-doped Li7La3Zr2O12 Powder by Polymerized Complex Method2015

    • Author(s)
      Noriko Saito, Shouichi Sugata, Ken Watanabe, Akio Watanabe, Tsuyoshi Ohnishi, Hajime Haneda, Yosuke Suzuki and Itaru Honma
    • Organizer
      5th UR1 - CNRS - NIMS - Saint-Gobain Workshop
    • Place of Presentation
      フランス レンヌ市
    • Year and Date
      2015-10-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 酸化亜鉛薄膜のガスセンサ特性2015

    • Author(s)
      安達裕,渡邉賢,齋藤紀子,鈴木拓,坂口勲,大橋直樹
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場、名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] エチレングリコール溶媒中での酸化亜鉛ナノ粒子の単結晶基板上配向析出2014

    • Author(s)
      齋藤紀子、坂口勲、羽田肇
    • Organizer
      日本セラミックス協会 第27回秋季シンポジウム
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2014-09-09
    • Related Report
      2014 Research-status Report
  • [Remarks] アルコールセンサを革新する六角錐形の酸化亜鉛ナノ粒子を合成

    • URL

      http://www.nims.go.jp/publicity/nimsnow/vol16/201605.html

    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 酸化亜鉛粒子、その製造方法およびそれを用いたガスセンサ2016

    • Inventor(s)
      齋藤紀子、羽田肇、坂口勲、渡邉賢、島ノ江憲剛
    • Industrial Property Rights Holder
      齋藤紀子、羽田肇、坂口勲、渡邉賢、島ノ江憲剛
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-08-26
    • Related Report
      2016 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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