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Fabrication of crystalline-oriented solid electrolyte of lanthanum silicate oxyapatite and characterization of its oxide ionic conduction

Research Project

Project/Area Number 26420690
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

UCHIKOSHI Tetsuo  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, グループリーダー (90354216)

Co-Investigator(Kenkyū-buntansha) 石垣 隆正  法政大学, 生命科学部, 教授 (40343842)
鈴木 達  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, グループリーダー (50267407)
辻本 吉廣  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主任研究員 (50584075)
Co-Investigator(Renkei-kenkyūsha) KOBAYASHI KIYOSHI  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主幹研究員 (90357020)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsランタンシリケート / 酸化物イオン伝導体 / 結晶磁気異方性 / 固体酸化物形燃料電池 / c軸配向 / 結晶配向 / コロイドプロセス / SOFC
Outline of Final Research Achievements

Single-phased lanthanum silicate oxyapatite (LSO) powder was fabricated by solid state reaction between lanthanum hydroxide and silica powders. Dense, c-axis-oriented LSO ceramics were successfully fabricated using magnetic field-assisted colloidal processing technique followed by sintering. Anisotropic electric property and microstructure were characterized using the textured dense, polycrystalline LSO bulk ceramics. It was revealed that the c-axis of LSO is the easy-magnetization axis and higher electric conductivity was observed along the c-axis direction. About 3 times higher SOFC performance was demonstrated by using c-axis oriented LSO electrolyte compared to the use of randomly oriented LSO electrolyte.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (27 results)

All 2016 2015 2014 Other

All Int'l Joint Research (1 results) Journal Article (7 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Open Access: 1 results) Presentation (19 results) (of which Int'l Joint Research: 4 results,  Invited: 8 results)

  • [Int'l Joint Research] CETMIC(アルゼンチン)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Electrophoretic deposition for obtaining dense lanthanum silicate2016

    • Author(s)
      Gustavo Suarez, Ngan T.K. Nguyen, Nicolas M. Rendtorff, Yoshio Sakka, Tetsuo Uchikoshi
    • Journal Title

      Ceramics International

      Volume: 42 Issue: 16 Pages: 19283-19288

    • DOI

      10.1016/j.ceramint.2016.09.095

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Sinterable powder fabrication of lanthanum silicate oxyapatite based on solid-state reaction method2015

    • Author(s)
      K. Kobayashi, K. Hirai, T. S. Suzuki, T. Uchikoshi, T. Akashi, Y. Sakka
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 123 Issue: 1436 Pages: 274-279

    • DOI

      10.2109/jcersj2.123.274

    • NAID

      130005064023

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] コロイドプロセスによる粒子固化成形と微構造制御2015

    • Author(s)
      打越哲郎、鈴木達
    • Journal Title

      第46回Continuing Educationシリーズ講習会テキスト

      Volume: 1 Pages: 58-71

    • Related Report
      2015 Research-status Report
  • [Journal Article] 静電吸着法により設計された粉末均一混合体からのランタンシリケートオキシアパタイトセラ ミックスの作製2014

    • Author(s)
      高橋聡志, 打越哲郎, 小林清, 鈴木達, 目義雄, 石垣隆正
    • Journal Title

      JOURNAL OF THE SOCIETY OF INORGANIC MATERIALSJAPAN

      Volume: 21 Pages: 155-161

    • NAID

      40020091172

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] セラミックス粒子の分散・凝集とコロイドプロセス2014

    • Author(s)
      打越哲郎, 鈴木達
    • Journal Title

      JOURNAL OF THE SOCIETY OF POWDER TECHNOLOGY JAPAN

      Volume: 51 Pages: 462-472

    • NAID

      130004856081

    • Related Report
      2014 Research-status Report
  • [Journal Article] ゼータ電位と分散・凝集2014

    • Author(s)
      打越哲郎
    • Journal Title

      セラミックス

      Volume: 49 Pages: 296-301

    • Related Report
      2014 Research-status Report
  • [Journal Article] 液中微粒子分散制御によるセラミックス材料の組織設計と新材料への応用2014

    • Author(s)
      打越哲郎
    • Journal Title

      粉砕誌

      Volume: 57 Pages: 36-42

    • Related Report
      2014 Research-status Report
  • [Presentation] Microstructure control in bulk ceramics by colloidal processing2016

    • Author(s)
      T. S. Suzuki, K. Kobayashi, T. Uchikoshi, Y. Sakka
    • Organizer
      Workshop on Advanced Inorganic Materials (WAIM 2016)
    • Place of Presentation
      Liston Hotel Shanghai、中国
    • Year and Date
      2016-10-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of Dense Ceramics and the Electrical Conductivity Anisotropy of the Textured MgO-doped Lanthanum Silicate Oxyapatite / Fabrication of Dense Ceramics and the Electrical Conductivity Anisotropy of the Textured MgO-doped Lanthanum Silicate Oxyapatite2016

    • Author(s)
      Y. Shimura, K. Kobayashi, T. S. Suzuki, T. Uchikoshi, Y. Sakka, T. Akashi
    • Organizer
      PRiME2016
    • Place of Presentation
      ホノルル、米国
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] MgOドープオキシアパタイト型ランタンシリケートの高配向性焼結体のイオン伝導異方性2016

    • Author(s)
      志村裕紀、小林清、鈴木達、打越哲郎、目義雄、平井拳也、明石孝也
    • Organizer
      日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      広島大学、広島
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 磁場成形による微構造設計のエネルギー材料への適用2016

    • Author(s)
      鈴木達、小林清、山田英登、打越哲郎、目義雄
    • Organizer
      粉体工学会 春期研究発表会
    • Place of Presentation
      京都リサーチパーク、京都
    • Year and Date
      2016-05-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] Title Texture developing and some properties of feeble magnetic ceramics / Texture developing and some properties of feeble magnetic ceramics2016

    • Author(s)
      Y. Sakka, T. S. Suzuki, T. Uchikoshi
    • Organizer
      ICCPS-13
    • Place of Presentation
      東大寺総合文化センター、奈良
    • Year and Date
      2016-05-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 強磁場中成形法を用いたMgOドープオキシアパタイト型ランタンシリケートの高配向焼結体作製と電気伝導異方性2016

    • Author(s)
      志村裕紀、小林清、鈴木達、打越哲郎、目義雄、平井拳也、明石孝也
    • Organizer
      日本セラミックス協会年会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2016-03-14
    • Related Report
      2015 Research-status Report
  • [Presentation] コロイドプロセスによる粒子固化成形と微構造制御2015

    • Author(s)
      打越哲郎、鈴木達
    • Organizer
      化学工学会第46回Continuing Educationシリーズ講習会
    • Place of Presentation
      東京大学本郷浅野キャンパス
    • Year and Date
      2015-11-30
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] セラミックス粒子の外場制御コロイドプロセス2015

    • Author(s)
      打越哲郎
    • Organizer
      第3回ナノ物質集積複合化技術研究会
    • Place of Presentation
      豊橋技術科学大学
    • Year and Date
      2015-10-23
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Fabrication of c-axis oriented ceramic of lanthanum silicate oxyapatite by silp casting in a strong magnetic field using highly sinterable powder2015

    • Author(s)
      K. HIrai, K. Kobayashi, T. S. Suzuki, T. Uchikoshi, T. Akashi, Y. Sakka
    • Organizer
      STAC-9
    • Place of Presentation
      エポカルつくば
    • Year and Date
      2015-10-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Fabrication and characterization of dense, c-axis-oriented lanthanumsilicate oxyapatite cearmics2015

    • Author(s)
      T. Uchikoshi
    • Organizer
      5th Workshop NIMS-UR1-Saint Gobain
    • Place of Presentation
      Univ. Rennes-1, France
    • Year and Date
      2015-10-11
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] コロイド粒子の電気泳動現象を用いたセラミックスの成形2015

    • Author(s)
      打越哲郎
    • Organizer
      第15回NIMSフォーラム
    • Place of Presentation
      東京国際フォーラム
    • Year and Date
      2015-10-07
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 拭く酸化物表面へのポリマー修飾が電気泳動堆積プロセスに及ぼす効果2015

    • Author(s)
      打越哲郎、鈴木晴絵、松永知佳、小林清、鈴木達、武藤浩行、松田厚範
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      富山大学五福キャンパス
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 高配向性オキシアパタイト型ランタンシリケートの作製とその異方的特性評価2015

    • Author(s)
      平井拳也、小林清、鈴木達、打越哲郎、明石孝也、目義雄
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      富山大学五福キャンパス
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Fabrication and characterization of textured bulk ceramics of lanthanum silicate oxyapatite2015

    • Author(s)
      T. Uchikoshi, S. Takahashi, K. Kobayashi, T. S. Suzuki, Y. Sakka, T. Ishigaki
    • Organizer
      PacRim-11
    • Place of Presentation
      ICC Jeju, Korea
    • Year and Date
      2015-08-30
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 強磁場鋳込み成形法によるオキシアパタイト型ランタンシリケート配向バルク体の組織制御と電気伝導異方性の評価2015

    • Author(s)
      打越哲郎、高橋聡志、小林清、鈴木達、目義雄、石垣隆正
    • Organizer
      粉体粉末冶金協会
    • Place of Presentation
      早稲田大学国際会議場
    • Year and Date
      2015-05-26
    • Related Report
      2015 Research-status Report
  • [Presentation] オキシアパタイト型ランタンシリケート配向多結晶バルク体の作製とその特性評価2015

    • Author(s)
      打越哲郎, 高橋聡志, 小林清, 鈴木達, 目義雄, 石垣隆正
    • Organizer
      日本セラミックス協会 2015年年会
    • Place of Presentation
      慶応大・日吉キャンパス
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] オキシアパタイト型ランタンシリケート配向バルク体の作製とその特性評価2014

    • Author(s)
      打越哲郎, 高橋聡志, 小林清, 鈴木達, 目義雄, 石垣隆正
    • Organizer
      無機マテリアル学会 第129回講演会
    • Place of Presentation
      アヴァンセ佐賀
    • Year and Date
      2014-11-20 – 2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] New Developments in Electrophoretic Deposition Process2014

    • Author(s)
      T. Uchikoshi
    • Organizer
      2nd Workshop of YU Korea and NIMS Japan
    • Place of Presentation
      韓国・ヨンナム大
    • Year and Date
      2014-05-21 – 2014-05-22
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] コロイドプロセスによるセラミックス成形2014

    • Author(s)
      打越哲郎
    • Organizer
      第146回電子セラミック・プロセス研究会
    • Place of Presentation
      横浜市泉区民文化センター テアトルフォンテ
    • Year and Date
      2014-05-17
    • Related Report
      2014 Research-status Report
    • Invited

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Published: 2014-04-04   Modified: 2018-03-22  

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