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Mechanism of resistance to hydrogen embrittlement and reliability of multi-phase Nb-TiNi alloys

Research Project

Project/Area Number 26420719
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionKanazawa University

Principal Investigator

ISHIKAWA KAZUHIRO  金沢大学, 機械工学系, 教授 (10312448)

Co-Investigator(Kenkyū-buntansha) 山田 良穂  金沢大学, 機械工学系, 教授 (20126626)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords水素透過 / 組織制御 / 水素吸蔵 / 耐水素脆化性 / 拡散 / 構造変化 / 結晶方位 / 微細組織
Outline of Final Research Achievements

The tungsten added Nb35W5Ti30Ni30 alloy showed similar microstructure, crystal structure and hydrogen solubility coefficient to W free alloy, its hydrogen permeation property was not degraded by W addition. Furthermore, hydrogen capacity of W added alloy was reduced by 20%, which is expected to improve resistance to hydrogen embrittlement of the alloy. Hydrogen permeability and hydrogen absorption properties of the as-cast Nb-TiNi and Nb-TiCo alloys were investigated. Hydrogen permeation in Nb-TiNi and Nb-TiCo alloys was contributed by hydrogen solubility coefficient and hydrogen diffusion coefficient, respectively.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (42 results)

All 2017 2016 2015 2014

All Journal Article (6 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 4 results) Presentation (36 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Hydrogen permeation in anisotropic Nb-TiNi two-phase alloys formed by forging and rolling2017

    • Author(s)
      K. Ishikawa, S. Tokui, K. Aoki
    • Journal Title

      Int. J. Hydrogen Energy

      Volume: in press Issue: 16 Pages: 11411-11421

    • DOI

      10.1016/j.ijhydene.2017.03.127

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] エネルギー材料としての水素化物の研究開発2017

    • Author(s)
      折茂慎一、中村優美子、石川和宏、西村睦、亀川厚則
    • Journal Title

      まてりあ

      Volume: 56 Pages: 130-134

    • NAID

      130005396213

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Hydrogen permeability degradation of Pd-coated Nb-TiNi alloy caused by its interfacial diffusion2016

    • Author(s)
      N. Ohtsu, K. Ishikawa and Y. Kobori
    • Journal Title

      Appl. Surf. Sci.

      Volume: 360 Pages: 566-571

    • DOI

      10.1016/j.apsusc.2015.10.206

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Formation of surface oxides and its effects on the hydrogen permeability of Nb40Ti30Ni30 alloy2016

    • Author(s)
      K. Ishikawa, h. Habaguchi, N. Obata, Y. Kobori and K. Aoki
    • Journal Title

      Int. J. Hydrogen Energy

      Volume: 41 Issue: 10 Pages: 5269-5275

    • DOI

      10.1016/j.ijhydene.2016.01.109

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Relationship between hydrogen permeation and microstructure in Nb-TiCo two-phase alloys2015

    • Author(s)
      Y. Saeki, Y. Yamada and K. Ishikawa
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 印刷中

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Relationship between hydrogen permeation and microstructure in Nb-TiNi two-phase alloys2014

    • Author(s)
      Y. Saeki, Y. Yamada and K. Ishikawa
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 39 Issue: 23 Pages: 12204-12230

    • DOI

      10.1016/j.ijhydene.2014.05.192

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Nb-TiNi複相水素透過合金の作製と組織制御2017

    • Author(s)
      石川和宏
    • Organizer
      日本金属学会春期講演体大会
    • Place of Presentation
      東京都市大学、八王子市
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Nb-ZrM (M = Ni, Co)共晶合金の圧延・熱処理による微細組織と水素透過度への影響2016

    • Author(s)
      佐伯賢英、山田良穂、石川和宏
    • Organizer
      日本金属学会秋期講演体大会
    • Place of Presentation
      大阪大学、豊中市
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Nb-TiNi水素透過合金の低温域での劣化と表面酸化処理の効果2016

    • Author(s)
      村井陸佑、大津 直史、小堀 良浩、山田良穂、石川和宏
    • Organizer
      日本金属学会秋期講演体大会
    • Place of Presentation
      大阪大学、豊中市
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Nb-Ti(Ni,Co)4元共晶合金の水素吸蔵特性と水素透過特性2016

    • Author(s)
      岡田隆介、坂本恭介、佐伯 賢英、山田良穂、石川和宏
    • Organizer
      日本金属学会秋期講演体大会
    • Place of Presentation
      大阪大学、豊中市
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] One second interval measurements of structural changes in Nb-TiNi hydrogen permeation alloys using synchrotron radiation light source2016

    • Author(s)
      K. Ishikawa, Y. Horimoto, Y. Saeki, Y. Yamada, T. Watanuki, A. Machida
    • Organizer
      Metal-Hydrogen Systems (MH2016)
    • Place of Presentation
      Interlaken, Switzerland
    • Year and Date
      2016-08-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structural changes in Nb-TiCo hydrogen permeation alloys under hydrogen atmosphere2016

    • Author(s)
      Y. Saeki, Y. Yamada, K. Ishikawa
    • Organizer
      Metal-Hydrogen Systems (MH2016)
    • Place of Presentation
      Interlaken, Switzerland
    • Year and Date
      2016-08-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of microstructural change by rolling and annealing on hydrogen permeability of Nb-TiNi and Nb-TiCo eutectic alloys2016

    • Author(s)
      Y. Saeki, Y. Yamada, K. Ishikawa
    • Organizer
      International Conference on Processing and Manufacturing of advanced materials, Thermec 2016
    • Place of Presentation
      Graz, Austria
    • Year and Date
      2016-05-29
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] V-TiNi合金の熱処理による微細組織変化と水素透過性2016

    • Author(s)
      森弘樹、山田良穂、石川和宏
    • Organizer
      日本金属学会春期講演大会
    • Place of Presentation
      東京都
    • Year and Date
      2016-03-23
    • Related Report
      2015 Research-status Report
  • [Presentation] Nb-TiNi水素透過合金へのW添加の効果2016

    • Author(s)
      米原一帆、山田良穂、石川和宏
    • Organizer
      日本金属学会春期講演大会
    • Place of Presentation
      東京都
    • Year and Date
      2016-03-23
    • Related Report
      2015 Research-status Report
  • [Presentation] 圧延-熱処理したNb-TiNi水素透過合金のbcc相とB2相の方位関係2016

    • Author(s)
      佐伯 賢英、山田良穂、石川和宏
    • Organizer
      日本金属学会春期講演大会
    • Place of Presentation
      東京都
    • Year and Date
      2016-03-23
    • Related Report
      2015 Research-status Report
  • [Presentation] プラズマ処理を用いたPd薄膜/Nb系金属水素分離デバイス界面の熱安定性向上2016

    • Author(s)
      小塚太郎、山根 美佐雄、大津 直史、石川 和宏、小堀 良浩
    • Organizer
      日本金属学会春期講演大会
    • Place of Presentation
      東京都
    • Year and Date
      2016-03-23
    • Related Report
      2015 Research-status Report
  • [Presentation] 複相型水素透過合金の組織制御2016

    • Author(s)
      石川和宏
    • Organizer
      日本鉄鋼協会・日本金属学会中国四国支部 本多光太郎記念講演
    • Place of Presentation
      広島オフィスセンター
    • Year and Date
      2016-03-14
    • Related Report
      2015 Research-status Report
  • [Presentation] Pdを被覆したNb-TiM(M=Ni,Co)水素透過合金の劣化2016

    • Author(s)
      村井陸佑、大津 直史、小堀 良浩、山田良穂、石川和宏
    • Organizer
      日本金属学会北陸信越支部、日本鉄鋼協会北陸信越支部連合講演会
    • Place of Presentation
      金沢大学、金沢市
    • Related Report
      2016 Annual Research Report
  • [Presentation] V-TiNi合金の水素化特性2016

    • Author(s)
      天野哲生、山田良穂、石川和宏
    • Organizer
      日本金属学会北陸信越支部、日本鉄鋼協会北陸信越支部連合講演会
    • Place of Presentation
      金沢大学、金沢市
    • Related Report
      2016 Annual Research Report
  • [Presentation] Wを添加したNb系複相水素透過合金の水素透過特性2016

    • Author(s)
      米原 一帆、山田良穂、石川和宏
    • Organizer
      日本金属学会北陸信越支部、日本鉄鋼協会北陸信越支部連合講演会
    • Place of Presentation
      金沢大学、金沢市
    • Related Report
      2016 Annual Research Report
  • [Presentation] Nb-Ti(Ni,Co)4元合金における水素の固溶と拡散2016

    • Author(s)
      岡田隆介、佐伯賢英、坂本恭介、山田良穂、石川和宏
    • Organizer
      日本金属学会北陸信越支部、日本鉄鋼協会北陸信越支部連合講演会
    • Place of Presentation
      金沢大学、金沢市
    • Related Report
      2016 Annual Research Report
  • [Presentation] 熱処理したNb-Ti(Ni, Co)共晶合金の水素雰囲気下での構造変化2015

    • Author(s)
      坂本恭介、山田良穂、石川和宏
    • Organizer
      日本金属学会北陸信越支部、日本鉄鋼協会北陸信越支部連合講演会
    • Place of Presentation
      富山大学
    • Year and Date
      2015-12-05
    • Related Report
      2015 Research-status Report
  • [Presentation] V-TiNi合金における水素透過特性及び冷間圧延による組織変化2015

    • Author(s)
      森弘樹、山田良穂、石川和宏
    • Organizer
      日本金属学会北陸信越支部、日本鉄鋼協会北陸信越支部連合講演会
    • Place of Presentation
      富山大学
    • Year and Date
      2015-12-05
    • Related Report
      2015 Research-status Report
  • [Presentation] 圧延-熱処理したNb-TiNi合金の微細組織と水素透過度2015

    • Author(s)
      佐伯 賢英、山田良穂、石川和宏
    • Organizer
      日本金属学会 水素化物に関わる次世代学術・応用展開研究会
    • Place of Presentation
      金沢大学
    • Year and Date
      2015-10-22
    • Related Report
      2015 Research-status Report
  • [Presentation] Pd-Ag-Cu三元系合金の組織と水素透過特性2015

    • Author(s)
      天野哲生、山田良穂、石川和宏
    • Organizer
      日本金属学会 水素化物に関わる次世代学術・応用展開研究会
    • Place of Presentation
      金沢大学
    • Year and Date
      2015-10-22
    • Related Report
      2015 Research-status Report
  • [Presentation] Nb-Ti(Ni,Co)共晶合金の水素雰囲気下での格子膨張と水素吸蔵特性2015

    • Author(s)
      坂本恭介、山田良穂、石川和宏
    • Organizer
      日本金属学会 水素化物に関わる次世代学術・応用展開研究会
    • Place of Presentation
      金沢大学
    • Year and Date
      2015-10-22
    • Related Report
      2015 Research-status Report
  • [Presentation] V-TiNi合金における冷間圧延と水素透過特性2015

    • Author(s)
      森弘樹、山田良穂、石川和宏
    • Organizer
      日本金属学会 水素化物に関わる次世代学術・応用展開研究会
    • Place of Presentation
      金沢大学
    • Year and Date
      2015-10-22
    • Related Report
      2015 Research-status Report
  • [Presentation] W添加したNb-TiNi合金の水素吸蔵特性及び水素透過特性2015

    • Author(s)
      米原一帆、山田良穂、石川和宏
    • Organizer
      日本金属学会 水素化物に関わる次世代学術・応用展開研究会
    • Place of Presentation
      金沢大学
    • Year and Date
      2015-10-22
    • Related Report
      2015 Research-status Report
  • [Presentation] Nb-TiNi系水素透過合金におけるTiNi相の役割2015

    • Author(s)
      石川和宏
    • Organizer
      SMAシンポジウム
    • Place of Presentation
      金沢歌劇座
    • Year and Date
      2015-10-12
    • Related Report
      2015 Research-status Report
  • [Presentation] 高輝度X線を用いたNb-TiCo合金の水素化過程の観察2015

    • Author(s)
      佐伯 賢英、堀本優也、山田良穂、綿貫徹、町田晃彦、石川和宏
    • Organizer
      日本金属学会秋期講演大会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Nb-Ti(Ni,Co)共晶合金の水素雰囲気下での構造変化2015

    • Author(s)
      坂本恭介、佐伯 賢英、山田良穂、石川和宏
    • Organizer
      日本金属学会秋期講演大会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Wを添加したNb-TiNi合金の水素吸蔵特性および水素透過特性2015

    • Author(s)
      米原 一帆、山田良穂、石川和宏
    • Organizer
      日本金属学会秋期講演大会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 表面分析によるPd被覆Nb-TiNi合金の水素透過性能劣化機構の解明2015

    • Author(s)
      大津直史、石川和宏、小堀良浩
    • Organizer
      日本金属学会秋期講演大会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 高輝度X線を用いたNb-TiNi合金の水素化過程の観察2015

    • Author(s)
      石川和宏、堀本優也、佐伯賢英、山田良穂、綿貫徹、町田晃彦
    • Organizer
      日本金属学会春期(153回)大会
    • Place of Presentation
      東京大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] V-TiNi合金における微細組織と水素透過度の関係2015

    • Author(s)
      森弘樹、山田良穂、石川和宏
    • Organizer
      日本金属学会春期(153回)大会
    • Place of Presentation
      東京大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Nb系複相水素透過共晶合金の圧延-熱処理による微細組織と水素透過特性への影響2015

    • Author(s)
      佐伯 賢英、山田良穂、石川和宏
    • Organizer
      日本金属学会春期(153回)大会
    • Place of Presentation
      東京大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] XPSを利用した水素透過Pd被覆NbTiNi合金の劣化機構の解明2014

    • Author(s)
      大津 直史、石川和宏、小畠奈々子、小堀良浩
    • Organizer
      X線分析討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2014-10-30 – 2014-10-31
    • Related Report
      2014 Research-status Report
  • [Presentation] Co添加したB2-TiNi相の高温高圧水素下での構造変化2014

    • Author(s)
      佐伯 賢英、山田良穂、石川和宏
    • Organizer
      日本金属学会秋期(152回)大会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] V-TiNi合金における水素透過特性2014

    • Author(s)
      森弘樹、山田良穂、石川和宏
    • Organizer
      日本金属学会秋期(152回)大会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] Effects of Surface Oxidation on Hydrogen Permeability of Nb-TiNi Two-phase Alloy2014

    • Author(s)
      K. Ishikawa, H. Habaguchi, N. Obata, Y. Kobori and K. Aoki
    • Organizer
      Metal-Hydrogen Systems (MH2014)
    • Place of Presentation
      Manchester, UK
    • Year and Date
      2014-07-20 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Relationship between Microstructure and Hydrogen Permeability in Nb-TiNi Alloys2014

    • Author(s)
      Y. Saeki, Y. Yamada and K. Ishikawa
    • Organizer
      Metal-Hydrogen Systems (MH2014)
    • Place of Presentation
      Manchester, UK
    • Year and Date
      2014-07-20 – 2014-07-25
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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