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Fabrication of nano-crystalline plated films by codeposition of molecules.

Research Project

Project/Area Number 26420735
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Material processing/Microstructural control engineering
Research InstitutionNagaoka University of Technology

Principal Investigator

MATSUBARA Hiroshi  長岡技術科学大学, 工学研究科, 教授 (00202325)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords硬質めっき膜 / アミノ酸 / 結晶粒微細化 / ニッケルめっき / 鉄めっき
Outline of Final Research Achievements

Fabrication of hard plated films were tried by adding some amino acids to plating baths. Methionine, Tryptophan, Lysine, Histidine, and Arginine were easily codeposited with nickel film. Asparagine, Serine, Threonine, Lysine, Glutamine and Proline were easily codeposited with iron film. The hardness of the films increased with the codeposition of carbon which came from the amino acids. Such hardness was due to fine crystal grain caused by the codeposition. The Hall-Petch relationship was observed in the film. Amino acid was decomposed when it was plated, and then carbon was deposited as atomic state. It was confirmed that this method is effective in order to fabricate the plated films which contain carbon.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (4 results)

All 2016 2015

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (3 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Codeposition of Amino Acids in the Electrodeposited Nickel Films2015

    • Author(s)
      永井太一、程内和範、松原浩
    • Journal Title

      Journal of The Surface Finishing Society of Japan

      Volume: 66 Issue: 2 Pages: 59-64

    • DOI

      10.4139/sfj.66.59

    • NAID

      130005121709

    • ISSN
      0915-1869, 1884-3409
    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Effect of Amino Acid Additives on the Hardness of Fe plated films2016

    • Author(s)
      Hiroshi Matsubara, Shogo Samejima, Kazunori Hodouchi and Kouichi Kudou
    • Organizer
      The 67th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Den Haag, Netherland
    • Year and Date
      2016-08-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アミノ酸添加による高硬度めっき膜の作製2015

    • Author(s)
      鮫島彰吾、程内和範、松原浩、工藤孝一
    • Organizer
      電気化学会北陸支部/表面技術協会関東支部 合同講演・見学会
    • Place of Presentation
      長岡市、長岡グランドホテル
    • Year and Date
      2015-10-20
    • Related Report
      2015 Research-status Report
  • [Presentation] Feめっき膜中へのアミノ酸の共析2015

    • Author(s)
      鮫島彰吾、程内和範、松原浩、工藤孝一
    • Organizer
      表面技術協会第132回講演大会
    • Place of Presentation
      長野市、信州大学
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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