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Development and sophistication of new microfabrication technique of polyimide using supercritical carbon dioxide

Research Project

Project/Area Number 26420765
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKanazawa University (2016)
Hiroshima University (2014-2015)

Principal Investigator

Haruki Masashi  金沢大学, 機械工学系, 准教授 (90432682)

Co-Investigator(Kenkyū-buntansha) 滝嶌 繁樹  広島大学, 工学研究院, 教授 (10188120)
木原 伸一  広島大学, 工学研究院, 准教授 (30284524)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsポリイミド / 超臨界二酸化炭素 / 微細加工 / 重合速度 / 高圧蒸着重合 / 蒸着重合 / 薄膜
Outline of Final Research Achievements

In the present work, the new deposition technique of polyimide using supercritical carbon dioxide was developed and sophisticated. The polyimides that were consisted of 2,2-bis(3,4-anhydrodicarboxyphenyl)-hexafluoropropane (6FDA) and 2,2’-bis(trifluoromethyl)-4,4’-diaminobiphenyl (TFDB) (fluorinated polyiomide), and pyromellitic dianhydride (PMDA) and TFDB (Kapton-fluorinated polyimide) could be fully deposited inside the microscale trenches of Si wafer at the high level of feed monomer concentration.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (10 results)

All 2017 2016 2015 2014

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 2 results) Presentation (7 results)

  • [Journal Article] Deposition of fluorinated polyimide consisting of 6FDA and TFDB into microscale trenches using supercritical carbon dioxide2017

    • Author(s)
      Masashi Haruki, Asuka Oda, Atsuhiko Wasada, Shin-ichi Kihara, Shigeki Takishima
    • Journal Title

      The Journal of Supercritical Fluids

      Volume: 119 Pages: 238-244

    • DOI

      10.1016/j.supflu.2016.10.001

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Deposition of PMDA-TFDB type polyimide onto microscale trenches patterned on silicon wafer using supercritical carbon dioxide2017

    • Author(s)
      Masashi Haruki, Atsuhiko Wasada, Yuki Hosokawa, Shin-ichi Kihara, Shigeki Takishima
    • Journal Title

      The Journal of Supercritical Fluids

      Volume: 印刷中 Pages: 200-207

    • DOI

      10.1016/j.supflu.2017.03.008

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Phase appearance during polymerization of fluorinated polyimide monomers and deposition into the microscopic‐scale trenches in supercritical carbon dioxide2016

    • Author(s)
      Masashi Haruki, Asuka Oda, Yumi Hasegawa, Shin-ichi Kihara, Shigeki Takishima
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 133 Issue: 20

    • DOI

      10.1002/app.43334

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 超臨界二酸化炭素を利用したフッ素系ポリイミドの蒸着重合2016

    • Author(s)
      春木将司, 小田明日香, 和佐田温彦, 木原伸一, 滝嶌繁樹
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      吹田市
    • Year and Date
      2016-03-14
    • Related Report
      2015 Research-status Report
  • [Presentation] 管型反応器を用いたポリイミドの高圧蒸着重合2016

    • Author(s)
      細川裕貴, 和佐田温彦, 小田明日香, 春木将司, 木原伸一, 滝嶌繁樹
    • Organizer
      第18回化学工学会学生発表会(福岡大会)
    • Place of Presentation
      福岡市
    • Year and Date
      2016-03-05
    • Related Report
      2015 Research-status Report
  • [Presentation] 超臨界二酸化炭素を利用した微細な空間におけるポリイミドの蒸着重合2016

    • Author(s)
      和佐田温彦, 細川裕貴, 木原伸一, 滝嶌繁樹, 春木将司
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス(徳島市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 超臨界二酸化炭素中におけるポリイミドの高圧蒸着重合2015

    • Author(s)
      和佐田温彦, 小田明日香, 春木将司, 木原伸一, 滝嶌 繁樹
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      札幌市
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] 超臨界二酸化炭素を利用したポリイミドの蒸着2015

    • Author(s)
      和佐田温彦、小田明日香、春木将司、木原伸一、滝嶌繁樹
    • Organizer
      第17回化学工学会学生発表会(徳島大会)
    • Place of Presentation
      徳島市
    • Year and Date
      2015-03-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 超臨界二酸化炭素を利用した微細構造中へのフッ素系ポリイミド蒸着2014

    • Author(s)
      小田明日香、和佐田温彦、春木将司、木原伸一、滝嶌繁樹
    • Organizer
      化学工学会中国四国支部大学院生発表会
    • Place of Presentation
      広島市
    • Year and Date
      2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 超臨界二酸化炭素を利用した微細構造中へのフッ素系ポリイミド成膜に関する基礎的検討2014

    • Author(s)
      小田明日香、長谷川優美、春木将司、木原伸一、滝嶌繁樹
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      福岡市
    • Year and Date
      2014-09-17
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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