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Fabrication of non-close-packed colloidal monolayers utilizing polymer brush-grafted silica particles

Research Project

Project/Area Number 26420767
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionSaga University

Principal Investigator

Morisada Shintaro  佐賀大学, 工学(系)研究科(研究院), 准教授 (60401569)

Research Collaborator OHTO Keisuke  
KAWAKITA Hidetaka  
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords粒子膜 / 高分子電解質 / 移流集積 / 非最密充填構造 / 自己集積 / 高分子ブラシ / 自己集積プロセス / シリカ粒子
Outline of Final Research Achievements

Two cationic polyelectrolytes, poly(3-acrylamidopropyl trimethylammonium chloride) (PAPTAC) or poly(vinylbenzyl trimethylammonium chloride) (PVBTA), have been grafted on the surface of the silica particles, and then these particles have been applied to the convective self-assembly (CSA) using hydrophilic substrates to prepare colloidal layers. When the PAPTAC-grafted silica particles (PAPTAC-Si) were used, we obtained the colloidal monolayers of a wiggle beads structure. By the CSA process using the PVBATA-grafted silica particles (PVBTA-Si), on the other hand, we succeeded in fabricating the colloidal monolayers having a somewhat constant interparticle distance, that is, a non-close-packed (NCP) structure without using any templates.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (18 results)

All 2016 2015 2014

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (17 results) (of which Int'l Joint Research: 7 results,  Invited: 2 results)

  • [Journal Article] Fabrication of non-close-packed colloidal monolayers by convective self-assembly using cationic polyelectrolyte-grafted silica particles2015

    • Author(s)
      Shintaro Morisada, Shoko Kojima, Takahiro Sumi, Hidetaka Kawakita, Keisuke Ohto
    • Journal Title

      Colloid and Polymer Science

      Volume: 293 Issue: 10 Pages: 2985-2993

    • DOI

      10.1007/s00396-015-3706-5

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Fabrication of Non-Close-Packed Colloidal Layers by Convective Self-Assembly Using Polyelectrolyte-Grafted Silica Particles2016

    • Author(s)
      Shintaro Morisada
    • Organizer
      The International Symposium on Preparative Chemistry of Advanced Materials
    • Place of Presentation
      Shenyang, China
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effect of the Substrate Hydrophilicity on Colloidal Layers Prepared by Convective Self-Assembly Process2016

    • Author(s)
      Miki Hayashi, Hidetaka Kawakita, Keisuke Ohto, and Shintaro Morisada
    • Organizer
      The International Symposium on Preparative Chemistry of Advanced Materials
    • Place of Presentation
      Shenyang, China
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子電解質修飾シリカ粒子を用いたコロイド粒子膜の構造制御2016

    • Author(s)
      森貞真太郎
    • Organizer
      2016年度第1回粉体操作に伴う諸現象に関する勉強会
    • Place of Presentation
      八勝園湯元館,岐阜
    • Year and Date
      2016-07-29
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 高分子修飾シリカ粒子を用いた移流集積における粒子-基板間相互作用の影響2016

    • Author(s)
      林 実樹,川喜田英孝,大渡啓介,森貞真太郎
    • Organizer
      第28回九州地区若手ケミカルエンジニア討論会
    • Place of Presentation
      休暇村志賀島,福岡
    • Year and Date
      2016-07-23
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fabricatoin of Colloidal Layers through Convective Self-Assembly Using Cationic or Anionic Polyelectrolyte-Grafted Silica Particles2015

    • Author(s)
      Takahiro Sumi, Hidetaka Kawakita, Keisuke Ohto, and Shintaro Morisada
    • Organizer
      The 6th Saga University-Liaoning University Joint Seminar
    • Place of Presentation
      佐賀大学
    • Year and Date
      2015-12-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Colloidal Layer Fabrication by Convective Self-Assembly Using Polyelectrolyte-Grafted Silica Particles2015

    • Author(s)
      Takahiro Sumi, Hidetaka Kawakita, Keisuke Ohto, and Shintaro Morisada
    • Organizer
      2015 Taiwan/Korea/Japan Joint Meeting on Chemical Engineering
    • Place of Presentation
      Kaohsiung, Taiwan
    • Year and Date
      2015-11-06
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高分子電解質修飾シリカ粒子を用いた移流集積法による単粒子膜の作製2015

    • Author(s)
      角 崇弘,川喜田英孝,大渡啓介,森貞真太郎
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] Effect of Substrate Surface Charge on Colloidal Layers Prepared by Convective Self-Assembly Process2015

    • Author(s)
      Takahiro Sumi, Hidetaka Kawakita, Keisuke Ohto, and Shintaro Morisada
    • Organizer
      3rd International Symposium on Host Compounds for Separation and Functionality in Saga
    • Place of Presentation
      佐賀大学
    • Year and Date
      2015-07-19
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高分子電解質修飾シリカ粒子を用いた粒子膜作製における基板電荷の影響2015

    • Author(s)
      角 崇弘,川喜田英孝,大渡啓介,森貞真太郎
    • Organizer
      第26回九州地区若手ケミカルエンジニア討論会
    • Place of Presentation
      伊万里グランドホテル
    • Year and Date
      2015-07-17
    • Related Report
      2015 Research-status Report
  • [Presentation] 高分子修飾シリカ粒子を用いた単粒子膜の作製と膜構造に対する基板電荷の影響2015

    • Author(s)
      角 崇弘,牟田諭司,川喜田英孝,大渡啓介,森貞真太郎
    • Organizer
      第52回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2015-06-27
    • Related Report
      2015 Research-status Report
  • [Presentation] Non-Close-Packed 2D Colloidal Array Prepared by Using Polymer-Grafted Silica Particles2015

    • Author(s)
      Shintaro Morisada, Shoko Kojima, Takahiro Sumi, Hidetaka Kawakita, and Keisuke Ohto
    • Organizer
      The 5th International Colloids Conference 2015
    • Place of Presentation
      Amsterdam, the Netherlands
    • Year and Date
      2015-06-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation of Non-Close-Packed Colloidal Array by Convective Self-Assembly Using Polymer-Grafted Silica Particles2015

    • Author(s)
      Shintaro Morisada, Shoko Kojima, Satoshi Muta, Hidetaka Kawakita, and Keisuke Ohto
    • Organizer
      The 15th Conference of the International Association of Colloid and Interface Scientists (IACIS 2015)
    • Place of Presentation
      Mainz, Germany
    • Year and Date
      2015-05-29
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation of Non-Close-Packed Colloidal Array Using Polymer-Grafted Silica Particles2014

    • Author(s)
      Nanami Hara, Satoshi Muta, Hidetaka Kawakita, and Keisuke Ohto
    • Organizer
      The 27th International Symposium on Chemical Engineering
    • Place of Presentation
      Putra World Trade Center, Kuala Lumpur, Malaysia
    • Year and Date
      2014-12-06
    • Related Report
      2014 Research-status Report
  • [Presentation] 鎖長を制御した高分子修飾シリカ粒子からなる非最密充填コロイド粒子膜の作製2014

    • Author(s)
      原奈菜美,川喜田英孝,大渡啓介,森貞真太郎
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-18
    • Related Report
      2014 Research-status Report
  • [Presentation] カチオン性高分子修飾シリカ粒子を利用した非最密充填構造の粒子膜作製2014

    • Author(s)
      原奈菜美,川喜田英孝,大渡啓介,森貞真太郎
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] アニオン性高分子修飾シリカ粒子を用いた移流集積法のよるコロイド粒子膜の作製2014

    • Author(s)
      角 崇弘,川喜田英孝,大渡啓介,森貞真太郎
    • Organizer
      第25回九州地区若手ケミカルエンジニア討論会
    • Place of Presentation
      ANAホリデイ・インリゾート宮崎
    • Year and Date
      2014-07-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 移流集積法によるシリカ粒子膜構造への基板電荷の影響2014

    • Author(s)
      角 崇弘,川喜田英孝,大渡啓介,森貞真太郎
    • Organizer
      第51回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2014-06-28
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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