Base strength evaluation of solid base by temperature-programmed desorption using propylene as probe
| Project/Area Number |
26420783
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Hokkaido University of Education |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Keywords | 昇温脱離 / 固体塩基 / プロピレン / 塩基強度 / 活性化エネルギー / 逆アルドール反応 |
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| Outline of Final Research Achievements |
Base strength of solid base was evaluated by applying a temperature-programmed desorption using hydrocarbons (propane, propylene, isobutene, and isobutene). Adsorption of hydrocarbons on CaO, which was activated by heating at 773 K for 2h, was performed at 143 K, and temperature increasing rate was 1 K/min in He stream. Peak temperatures of each hydrocarbons were 172 K, 193 K, 206 K, and 228 K for propane, propylene, isobutene, and isobutene, respectively. This result indicates that these was an acid-base like interaction between hydrocarbons and base sites. The strength of this acid-base like interaction was evaluated as an activation energy of desorption of propylene.
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Report
(4 results)
Research Products
(4 results)
