Study on the catalyst design of nanocluster and support
Project/Area Number |
26420784
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Catalyst/Resource chemical process
|
Research Institution | Chiba University |
Principal Investigator |
|
Project Period (FY) |
2014-04-01 – 2017-03-31
|
Project Status |
Completed (Fiscal Year 2016)
|
Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
|
Keywords | ナノクラスター / XAFS / 酸化ニッケル触媒 / 酸化鉄触媒 / 担体界面構造 / コロイド / チオフェノールカップリング反応 / アルコール酸化反応 / メソ細孔シリカ / PVP保護基 / 酸化コバルト触媒 / XPS |
Outline of Final Research Achievements |
Base metal, such as nickel, nanocluster (NC) catalyst was prepared and applied to the catalyst. The interface structure between the NiO-NC and silica support promoted the NiO-NC catalysis of oxidative thiophenol coupling reaction. Polymer stabilizer, which was employed as a stabilizing ligand to prevent the NC aggregation, itself can block the active site during the catalysis. Polymer stabilizer remained on the support not on NC also showed the stabilizing effect.
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Report
(4 results)
Research Products
(44 results)