| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Outline of Final Research Achievements |
Base metal, such as nickel, nanocluster (NC) catalyst was prepared and applied to the catalyst. The interface structure between the NiO-NC and silica support promoted the NiO-NC catalysis of oxidative thiophenol coupling reaction. Polymer stabilizer, which was employed as a stabilizing ligand to prevent the NC aggregation, itself can block the active site during the catalysis. Polymer stabilizer remained on the support not on NC also showed the stabilizing effect.
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