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Creation of new environmental purification materials with ordered nano-sized pores from silicate waste and unused resources

Research Project

Project/Area Number 26420845
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Earth system and resources engineering
Research InstitutionWaseda University

Principal Investigator

YAMAZAKI Atsushi  早稲田大学, 理工学術院, 教授 (70200649)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsジオポリマー / 低品位カオリン / フライアッシュ / マイクロ・メソ細孔 / 陽イオン交換 / 重イオン吸着 / メタカオリン / アルミノケイ酸塩ポリマー / マイクロ・メソ細孔質 / 陽イオン吸着・固定 / メソ細孔 / 細孔質 / シネレシス
Outline of Final Research Achievements

Using various fly ash (coal ash) and metakaolin with different properties as starting materials, preparation conditions of the nano porous geopolymer and the pore structure and their texture formation of the aluminosilicate network were clarified. In addition, the preparation method revealed the thermal stability in the higher temperature region above 500 ℃ and the influence on the phase change mechanism. The reaction activity of the fly ash as raw material largely depends on the properties of the surface-coated carbon, and the surface modification treatment by appropriate chemical treatment, pulverization and the like can improve reaction activity and stabilize. It was also found a preparation condition that a cation exchange capacity of 400 meq / 100 g or more and a distribution coefficient of Sr ion exchange / sorption characteristics in sea water shown the order of thousands of distribution coefficients.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (12 results)

All 2016 2015 2014 Other

All Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (7 results) (of which Int'l Joint Research: 1 results) Remarks (3 results)

  • [Journal Article] Hollow structure improved anti-cancer immunity of mesoporous silica nanospheres in vitro2016

    • Author(s)
      X. Wang, X. Li, A. Ito, K. Yoshiyuki, Y. Sogo, Y. Watanabe, A. Yamazaki, T. Ohno and N. M. Tsuji
    • Journal Title

      Small

      Volume: 12 Pages: 3510-3515

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Changes in the microporous structure of geopolymer by syneresis conditions2015

    • Author(s)
      T. Kuroda, S. Komine, M. Nagao and A. Yamazaki
    • Journal Title

      Clay Science

      Volume: 19 Pages: 11-16

    • NAID

      110009978116

    • Related Report
      2015 Research-status Report
  • [Presentation] The suppression effect of alkali-silica reaction using the H+-form of geopolymer2016

    • Author(s)
      Takatsune Sato, Motoki Uehara, Shintaro Oda, and Atsushi Yamazaki
    • Organizer
      The 3rd Asian Clay Conference
    • Place of Presentation
      中国 広州
    • Year and Date
      2016-11-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ジオポリマーセメントペーストの酸処理によるイオン収着特性の変化2016

    • Author(s)
      小田慎太郎、佐藤隆恒、岡戸仁志、上原元樹、山﨑淳司
    • Organizer
      第60回粘土科学討論会
    • Place of Presentation
      福岡
    • Year and Date
      2016-09-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 大きい陽イオン交換容量を有するケイ酸塩ポリマー吸着剤の開発2016

    • Author(s)
      正田武則、山﨑淳司、松方正彦、松岡一雄
    • Organizer
      資源・素材学会 平成28年度春季大会
    • Place of Presentation
      東京
    • Year and Date
      2016-03-28
    • Related Report
      2015 Research-status Report
  • [Presentation] 大きい陽イオン交換容量を有するミクロ多孔性無機ポリマー吸着剤の開発2015

    • Author(s)
      正田武則、山﨑淳司、松方正彦、松岡一雄
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      札幌
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] ジオポリマー硬化体の配合とpH,塩分浸透,および鉄筋腐食特性2015

    • Author(s)
      上原元樹、佐藤隆恒、南浩輔、梶田秀幸、舟橋政司、山﨑淳司
    • Organizer
      第59回粘土科学討論会
    • Place of Presentation
      山口
    • Year and Date
      2015-09-02
    • Related Report
      2015 Research-status Report
  • [Presentation] 大きい陽イオン交換容量を有するミクロ多孔性無機ポリマー吸着剤の開発2015

    • Author(s)
      正田武則、山崎淳司、松方正彦、松岡一雄
    • Organizer
      化学工学会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス(東京)
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] ゼオライト質ポリマーにおける微細構造の発現機構とその制御2014

    • Author(s)
      黒田隆央、小峯慎介、長尾全寛、山崎淳司
    • Organizer
      ゼオライト学会
    • Place of Presentation
      タワーホール船橋(東京)
    • Year and Date
      2014-11-26 – 2014-11-27
    • Related Report
      2014 Research-status Report
  • [Remarks] 早稲田大学山崎研究室

    • URL

      http://www.yamazaki.env.waseda.ac.jp/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 早稲田大学 理工教員研究紹介

    • URL

      http://www.sci.waseda.ac.jp/research/

    • Related Report
      2015 Research-status Report
  • [Remarks] 早稲田大学 山崎淳司研究室ホームページ

    • URL

      http://www.yamazaki.env.waseda.ac.jp/

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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