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Defects in metal oxides: spectroscopy of their functions in energy science

Research Project

Project/Area Number 26420884
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Energy engineering
Research InstitutionKyoto University

Principal Investigator

Hachiya Kan  京都大学, エネルギー科学研究科, 准教授 (90314252)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Keywordsエネルギー生成・変換 / エネルギー生成 / エネルギー変換
Outline of Final Research Achievements

Mid-infrared free-electron laser was used to investigate phonon properties in metal oxide single crystals, wurtzite ZnO and perovskite SrTiO3, with an emphasis on their electron-lattice interactions. Carriers in metal oxides are created for charge compensation during defects formation. Functions of energy conversion devices emerge, affected by carrier transportation under strong interactions with lattice vibrations. A1(LO) mode in GaN, which also has wurtzite structure, was successfully excited selectively, while ZnO, which is non-stoichiometric oxide and has defects, failed because of photoluminescence from defects. Spectroscopy of the defects with UVSOR was also performed.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (28 results)

All 2017 2016 2015 2014

All Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (22 results) (of which Int'l Joint Research: 7 results,  Invited: 1 results)

  • [Journal Article] Mode-selective phonon excitation in gallium nitride using mid-infrared free-electron laser2017

    • Author(s)
      Muneyuki Kagaya, Kyohei Yoshida, Heishun Zen, Kan Hachiya, Takashi Sagawa, Hideaki Ohgaki
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 2 Pages: 022701-022701

    • DOI

      10.7567/jjap.56.022701

    • NAID

      120006799257

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Electrodeposition of porous Si film from SiO2 in molten BaCl2-CaCl2-NaCl2017

    • Author(s)
      Yoshihide Sakanaka, Akira Murata, Takuya Goto, Kan Hachiya
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 695 Pages: 2131-2135

    • DOI

      10.1016/j.jallcom.2016.11.056

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of viscosity ratio of polyacrylonitrile/poly(methyl methacrylate) solutions on core-shell fibers prepared by coaxial electrospinning2017

    • Author(s)
      Navaporn Kaerkitcha, Surawut Chuangchote, Kan Hachiya, Takashi Sagawa
    • Journal Title

      Polymer Journal

      Volume: advance online publication Issue: 6 Pages: 1-6

    • DOI

      10.1038/pj.2017.8

    • NAID

      40021203916

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ag-In-Zn-S quantum dots for hybrid organic-inorganic solar cells2016

    • Author(s)
      Eung-min Kim, Pipat Ruankham, Jae-hyeong Lee, Kan Hachiya, Takashi Sagawa
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 2S Pages: 02BF06-02BF06

    • DOI

      10.7567/jjap.55.02bf06

    • NAID

      210000146109

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of microwave irradiation on the electronic structure of ZnO2015

    • Author(s)
      Kyohei Yoshida, Taro Sonobe, Heishun. Zen, Kan Hachiya, Kensuke Okumura, Kenta Mishima, Motoharu Inukai, Hani Negm, Konstantin Torgasin, Mohamed Omer, Ryota Kinjo, Toshiteru Kii, Kai Masuda, Hideaki Ohgaki
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 83 Pages: 47-51

    • DOI

      10.1016/j.jpcs.2015.03.013

    • NAID

      120005617612

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical Formation of Ca-Si in Molten CaCl2-KCl2015

    • Author(s)
      Yoshihide Sakanaka, Takuya Goto, Kan Hachiya
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 162 Issue: 4 Pages: D186-D191

    • DOI

      10.1149/2.1021504jes

    • NAID

      120005842697

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 中赤外自由電子レーザーによる機能材料における選択的格子振動励起2017

    • Author(s)
      竹本亮太, 吉田恭平, 全 炳俊, 蜂谷 寛, 佐川 尚, 大垣英明
    • Organizer
      2017年 応用物理学会春季講演会
    • Place of Presentation
      パシフィコ横浜, 横浜市
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Observation of mode-selective phonon excitation of 6H-SiC by MIR-FEL Pump and Pico-second Probe Laser2016

    • Author(s)
      Tsubasa Katsurayama, Tomoya Murata, Kyohei Yoshida, Heishun Zen, Kan Hachiya, Takeshi Nogi, Sikharin Suphakul, Konstantin Torgasin, Toshiteru Kii, Kai Masuda, Hideaki Ohgaki
    • Organizer
      IRMMW-THZ 2016, 41st International Conference on Infrared, Millimeter and Terahertz Waves
    • Place of Presentation
      COPENHAGEN, DENMARK
    • Year and Date
      2016-09-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective phonon-mode excitation in perovskite functional materials for energy conversion by mid-infrared free-electron laser2016

    • Author(s)
      R. Takemoto, K. Yoshida, H. Zen, K. Hachiya, T. Sagawa, H. Ohgaki
    • Organizer
      The 7th International Symposium of Advanced Energy Science - Frotiers of Zero Emission Energy -
    • Place of Presentation
      百周年記念館, 京都大学吉田キャンパス
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機薄膜太陽電池用SrTiO3ナノ構造体の作製と光電変換特性評価2016

    • Author(s)
      武内 あづ彩・佐川 尚・蜂谷 寛
    • Organizer
      日本化学会第96春季年会 (2016)
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] 種々の配位子を用いたZnS-AgInS2ナノ粒子の作製と有機-無機ハイブリッド太陽電池への応2016

    • Author(s)
      八木 雄太郎・蜂谷 寛・佐川 尚
    • Organizer
      日本化学会第96春季年会 (2016)
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] ピコ秒レーザを用いた中赤外自由電子レーザ誘起選択的格子振動励起の観測2016

    • Author(s)
      村田智哉, 全炳俊, 吉田恭平, 蜂谷寛, 桂山翼,野儀武志, S.Suphakul, K.Torgasin, 紀井俊輝, 増田開, 大垣英明
    • Organizer
      第22回FELとHigh-Power Radiation 研究会
    • Place of Presentation
      高エネルギー加速器研究機構(茨城県・つくば市)
    • Year and Date
      2016-01-22
    • Related Report
      2015 Research-status Report
  • [Presentation] 中赤外自由電子レーザーを用いた6H-SiCの選択的格子振動励起の観測2016

    • Author(s)
      桂山 翼, 村田智哉, 吉田恭平, 全 炳俊, 田伐俊介,蜂谷 寛, 紀井俊輝, 増田 開, 大垣英明
    • Organizer
      第26回(平成28年度)日本赤外線学会研究発表会
    • Place of Presentation
      自然科学研究機構 国立天文台, 東京都三鷹市
    • Related Report
      2016 Annual Research Report
  • [Presentation] 中赤外自由電子レーザーによるペロブスカイト型および関連化合物における選択的格子振動励起2016

    • Author(s)
      蜂谷 寛
    • Organizer
      2016年度有機エレクトロニクスシンポジウム
    • Place of Presentation
      きはだホール, 京都大学宇治キャンパス
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 溶融塩化物中における酸素欠陥チタニアナノチューブの形成とその物性評価及び光学特 性の評価2015

    • Author(s)
      木下貢, 後藤琢也, 蜂谷寛
    • Organizer
      第47回溶融塩化学討論会
    • Place of Presentation
      神戸大学百年記念館六甲ホール(兵庫県・神戸市)
    • Year and Date
      2015-10-28
    • Related Report
      2015 Research-status Report
  • [Presentation] ピコ秒レーザを用いた中赤外自由電子レーザ誘起選択的格子振動励起の観測2015

    • Author(s)
      村田智哉, 吉田恭平, 全炳俊, 蜂谷寛, 桂山翼, 野儀武志, S.Suphakul, K.Torgasin, 紀井俊輝, 増田開, 大垣英明
    • Organizer
      第25回(平成27年度)日本赤外線学会研究発表会
    • Place of Presentation
      中部大学不言実行館ACTIVE PLAZA(愛知県・春日井市)
    • Year and Date
      2015-10-22
    • Related Report
      2015 Research-status Report
  • [Presentation] Mode-selective Phonon Excitation in Widegap Semiconductors2015

    • Author(s)
      K. Hachiya
    • Organizer
      The Joint Conference of 6th International Symposium on Physical Sciences in Space (ISPS) and 10th International Conference on Two-Phase Systems for Space and Ground Applications (ITTW)
    • Place of Presentation
      同志社大学今出川キャンパス(京都府・京都市)
    • Year and Date
      2015-09-14
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electrodeposition of Silicide Film Form Silicate Rock2015

    • Author(s)
      Yosuke Shimizu, Shu Takashima, Yoshihide Sakanaka, Takuya Goto, Kan Hachiya, Yasuhiro Fukunaka
    • Organizer
      The Joint Conference of 6th International Symposium on Physical Sciences in Space (ISPS) and 10th International Conference on Two-Phase Systems for Space and Ground Applications (ITTW)
    • Place of Presentation
      同志社大学今出川キャンパス(京都府・京都市)
    • Year and Date
      2015-09-14
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electrodeposition of Iron Based Alloy from Iron Oxides in Molten Salt2015

    • Author(s)
      Kentarao Nakajima,Yoshihide Sakanaka, Takuya Goto, Kan Hachiya, Takehiko Ishikawa
    • Organizer
      The Joint Conference of 6th International Symposium on Physical Sciences in Space (ISPS) and 10th International Conference on Two-Phase Systems for Space and Ground Applications (ITTW)
    • Place of Presentation
      同志社大学今出川キャンパス(京都府・京都市)
    • Year and Date
      2015-09-14
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Mode-selective phonon excitation in wide-bandgap semiconductor by mid-infrared free- electron-laser2015

    • Author(s)
      Muneyuki KAGAYA, Kyohei YOSHIDA, Heishun ZEN, Kan HACHIYA, Takashi SAGAWA, Hideaki OHGAKI
    • Organizer
      The 6th International Symposium of Advanced Energy Science
    • Place of Presentation
      京都大学おうばくプラザ(京都府・宇治市)
    • Year and Date
      2015-08-31
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of Phonon Dynamics Measurement System by MIR- FEL and Pico-second Laser2015

    • Author(s)
      Tomoya Murata, Tsubasa Katsurayama, Toshiteru Kii, Torgasin Konstantin, Kai Masuda, Takeshi Nogi, Hideaki Ohgaki, Sikharin Suphakul, Heishun Zen, Kyohei Yoshida, Kan Hachiya
    • Organizer
      FEL2015 37th International Free Electron Laser Conference
    • Place of Presentation
      Daejeon (Korea)
    • Year and Date
      2015-08-23
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 電界紡糸炭素複合ナノファイバーの作製と特性評価2015

    • Author(s)
      Navaporn Kaerkitcha・早川祐司・加賀屋宗志・蜂谷寛・佐川尚
    • Organizer
      第61回高分子研究発表会
    • Place of Presentation
      兵庫県民会館(兵庫県・神戸市)
    • Year and Date
      2015-07-15
    • Related Report
      2015 Research-status Report
  • [Presentation] 溶融塩中における可視光応答型チタニアナノチューブの形成2015

    • Author(s)
      木下 貢, 後藤 琢也, 蜂谷 寛
    • Organizer
      公益社団法人電気化学会第82回大会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Research-status Report
  • [Presentation] 溶融CaCl2-KCl中における単結晶Si基板上へのCa-Siの共析2015

    • Author(s)
      高島 崇, 坂中 佳秀, 後藤 琢也, 蜂谷 寛
    • Organizer
      公益社団法人電気化学会第82回大会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Research-status Report
  • [Presentation] アンチストークスラマン散乱分光を用いた中赤外自由電子レーザーによる選択的格子振動励起の直接観測2015

    • Author(s)
      吉田恭平, 園部太郎, 全 炳俊, 蜂谷 寛, 村田智哉, 栂村勇輔, 犬飼元晴, Sikharin Suphakul, Negm Hani, Konstantin Torgasin, 紀井俊輝, 増田開, 大垣英明
    • Organizer
      第28回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス
    • Year and Date
      2015-01-10 – 2015-01-12
    • Related Report
      2014 Research-status Report
  • [Presentation] Electrochemical Formation of Calcium Silicide on Silicon Substratein CaCl2-KCl Melt2014

    • Author(s)
      S. Takashima, S. Ueda, T. Goto, K. Hachiya
    • Organizer
      The 6th World Conferenceon Photovoltaic Energy Conversion (WCPEC-6)
    • Place of Presentation
      Kyoto International Conference Center, Kyoto, Japan
    • Year and Date
      2014-11-23 – 2014-11-27
    • Related Report
      2014 Research-status Report
  • [Presentation] Formation of Titania Nanotube with Visible Light Activity by Electrochemical Reduction2014

    • Author(s)
      M. Kinoshita, T. Sasa, T. Goto, K. Hachiya
    • Organizer
      The 6th World Conferenceon Photovoltaic Energy Conversion (WCPEC-6)
    • Place of Presentation
      Kyoto International Conference Center, Kyoto, Japan
    • Year and Date
      2014-11-23 – 2014-11-27
    • Related Report
      2014 Research-status Report
  • [Presentation] Mode-selective phonon excitation in wide-bandgap semiconductor by mid-infrared free-electron-laser2014

    • Author(s)
      Muneyuki KAGAYA, Kyohei YOSHIDA, Heishun ZEN, Kan HACHIYA, Takashi SAGAWA, Hideaki OHGAKI
    • Organizer
      The 5th International Symposium of Advanced Energy Science ~Contribution to Zero-Emission Energy~
    • Place of Presentation
      Obaku Plaza, Kyoto University, Uji, Kyoto, Japan
    • Year and Date
      2014-09-30 – 2014-10-02
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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