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Study on fabrication of next-generation CZTSSe thin film solar cells using abundant elements in resources

Research Project

Project/Area Number 26420888
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Energy engineering
Research InstitutionWakayama National College of Technology

Principal Investigator

YAMAGUCHI Toshiyuki  和歌山工業高等専門学校, 電気情報工学科, 教授 (60191235)

Research Collaborator NAKASHIMA Mitsuki  和歌山工業高等専門学校, 技術支援室, 技術専門職員
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords薄膜太陽電池 / 化合物薄膜 / 連続成膜法
Outline of Final Research Achievements

In order to fabricate next-generation CZTSSe thin film solar cells which consist of earth-abundant elements (Cu, Zn, Sn, S and/or Se), the preparation conditions of the sequential evaporation method using compounds were examined. The S content in the CZTSSe thin film was controlled by changing the amount of sulfur evaporation in the second step. CZTSSe and CZTSe thin film solar cell were fabricated and demonstrated the efficiency of 1.55% and 3.93%, respectively. These values were updated our previous performance. Moreover, the open circuit voltage was improved by adding the thermal treatment after the sequential evaporation.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (36 results)

All 2017 2016 2015 2014 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Open Access: 2 results,  Acknowledgement Compliant: 4 results) Presentation (27 results) (of which Int'l Joint Research: 4 results) Remarks (2 results)

  • [Journal Article] Effect of annealing on the morphology and compositions of Cu2ZnSnSe4 thin films fabricated by thermal evaporation for solar cells2017

    • Author(s)
      M. Nakashima, T. Yamaguchi, S. Yukawa, J. Sasano, M. Izaki
    • Journal Title

      Thin Solid Films

      Volume: 621 Pages: 47-51

    • DOI

      10.1016/j.tsf.2016.11.035

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Cu2ZnSn(S,Se)4 Thin Films Fabricated by Sequential Evaporation using Cu2ZnSnSe4 Compound and Their Photovoltaic Applications2017

    • Author(s)
      T. Yamaguchi, M. Nakashima, T. Sakamoto
    • Journal Title

      MATEC Web of Conferences

      Volume: 110

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] NaF addition to Cu2ZnSnSe4 thin films prepared by sequential evaporation from compound2017

    • Author(s)
      T. Yamaguchi, T. Yamada, M. Nakashima, J. Sasano, M. Izaki
    • Journal Title

      Journal of Nanoelectronics and Optoelectronics

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fabrication of Cu2ZnSnSe4 thin films by selenization of precursor using Cu_2ZnSnSe_4 compound for photovoltaic applications2015

    • Author(s)
      M. Nakashima, T. Yamaguchi, K. Kusumoto, S. Yukawa J. Sasano, M. Lzaki
    • Journal Title

      Physica Status Solidi C

      Volume: 12 Issue: 6 Pages: 729-732

    • DOI

      10.1002/pssc.201400279

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Cu2ZnSnSe4 Thin Films by Selenization of Precursor using Cu2ZnSnSe4 Compound for Photovoltaic Applications2015

    • Author(s)
      Mitsuki Nakashima, Toshiyuki Yamaguchi, Kengo Kusumoto, Shohei Yukawa, Junji Sasano and Masanobu Izaki
    • Journal Title

      Physica Status Solidi C

      Volume: 未定

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Cu2ZnSnSe4 Thin Films Prepared by Annealing from Precursor Using Cu2ZnSnSe4 Compound in Selenium and Tin Mixing Atmosphere2014

    • Author(s)
      Mitsuki Nakashima, Toshiyuki Yamaguchi, Kengo Kusumoto, Shohei Yukawa, Junji Sasano and Masanobu Izaki
    • Journal Title

      Technical Digest of The 6th World Conference on Photovoltaic Energy Conversion (WCPEC6) (Kyoto, Nov.23-27, 2014)

      Volume: 無 Pages: 419-420

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Cu2ZnSn(S,Se)4 Thin Films Prepared by Annealing in Sulfur, Selenium and Tin Mixing Atmosphere for Photovoltaic Applications2014

    • Author(s)
      Mitsuki Nakashima, Toshiyuki Yamaguchi, Yuichi Mizui, Junji Sasano and Masanobu Izaki
    • Journal Title

      Technical Digest of The 6th World Conference on Photovoltaic Energy Conversion (WCPEC6) (Kyoto, Nov.23-27, 2014)

      Volume: 無 Pages: 393-394

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Cu2ZnSnSe4化合物を用いた蒸着法によるCu2ZnSn(S,Se)4薄膜太陽電池の作製Ⅱ2016

    • Author(s)
      中嶋崇喜,桝田大樹,山口利幸
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ国際会議場(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] NaF addition to Cu2ZnSnSe4 thin films prepared by sequential evaporation from compound2016

    • Author(s)
      T. Yamaguchi, T. Yamada, M. Nakashima, J. Sasano, M. Izaki
    • Organizer
      20th International Vacuum Congress
    • Place of Presentation
      Busan (Korea)
    • Year and Date
      2016-08-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Cu2ZnSn(S,Se)4 Thin Films Fabricated by Sequential Evaporation using Cu2ZnSnSe4 Compound and Their Photovoltaic Applications2016

    • Author(s)
      T. Yamaguchi, M. Nakashima, T. Sakamoto
    • Organizer
      International Symposium on Advances in Material Science 2016
    • Place of Presentation
      Shanghai (China)
    • Year and Date
      2016-08-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Cu2ZnSnSe4化合物を用いた連続蒸着法によるCu2ZnSn(S,Se)4薄膜太陽電池の作製2016

    • Author(s)
      中嶋崇喜,桝田大樹,山口利幸
    • Organizer
      第13回次世代の太陽光発電システムシンポジウム
    • Place of Presentation
      アオーレ長岡(新潟県長岡市)
    • Year and Date
      2016-05-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] 化合物を用いた連続蒸着法によるCu2ZnSnSe4薄膜へのNaF添加2016

    • Author(s)
      中嶋崇喜,山田竜也,山口利幸
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 硫化・セレン化法によるCZTSSe薄膜の作製と評価2015

    • Author(s)
      畑山耕一,中嶋崇喜,山口利幸
    • Organizer
      第5回高専-TUT太陽電池合同シンポジウム
    • Place of Presentation
      アオーレ長岡&長岡高専(新潟県長岡市)
    • Year and Date
      2015-12-12
    • Related Report
      2015 Research-status Report
  • [Presentation] CZTSe化合物を用いた蒸着法によるCZTSSe薄膜の作製条件の検討2015

    • Author(s)
      桝田大樹,中嶋崇喜,山口利幸
    • Organizer
      第5回高専-TUT太陽電池合同シンポジウム
    • Place of Presentation
      アオーレ長岡&長岡高専(新潟県長岡市)
    • Year and Date
      2015-12-12
    • Related Report
      2015 Research-status Report
  • [Presentation] Cu2ZnSnSe4 thin film solar cells prepared by evaporation of Cu2ZnSnSe4 compound and effect of annealing2015

    • Author(s)
      M. Nakashima, T. Yamaguchi, S. Yukawa, J. Sasano, M. Izaki
    • Organizer
      25th International Photovoltaic Science and Engineering Conference
    • Place of Presentation
      釜山(韓国)
    • Year and Date
      2015-11-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Cu2ZnSn(S,Se)4 thin film solar cells by thermal crystallization using Cu2ZnSnSe4 compound in S/Se atmosphere2015

    • Author(s)
      M. Nakashima, T. Yamaguchi, S. Yukawa, J. Sasano, M. Izaki
    • Organizer
      25th International Photovoltaic Science and Engineering Conference
    • Place of Presentation
      釜山(韓国)
    • Year and Date
      2015-11-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 連続成膜法による Cu2ZnSnSe4薄膜へのNaFの添加2015

    • Author(s)
      山田竜也,中嶋崇喜,山口利幸,伊崎昌伸
    • Organizer
      平成27年電気関係学会関西連合大会
    • Place of Presentation
      摂南大学(大阪府寝屋川市)
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report
  • [Presentation] CZTSe化合物へのS添加によるCu2ZnSn(S,Se)4薄膜太陽電池の作製2015

    • Author(s)
      桝田大樹,中嶋崇喜,山口利幸
    • Organizer
      平成27年電気関係学会関西連合大会
    • Place of Presentation
      摂南大学(大阪府寝屋川市)
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report
  • [Presentation] 化合物を用いた連続蒸着法によるCu2ZnSnSe4薄膜の作製と熱処理効果2015

    • Author(s)
      中嶋崇喜,湯川翔平,山口利幸
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] Cu2ZnSnSe4化合物を用いた蒸着法によるCu2ZnSn(S,Se)4薄膜太陽電池の作製2015

    • Author(s)
      中嶋崇喜,坂本竜也,山口利幸
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] Cu2ZnSnSe4化合物の蒸着法による薄膜太陽電池の作製と熱処理効果2015

    • Author(s)
      中嶋崇喜,湯川翔平,山口利幸
    • Organizer
      第12回次世代の太陽光発電システムシンポジウム
    • Place of Presentation
      磐梯熱海ホテル華の湯(福島県郡山市)
    • Year and Date
      2015-05-28
    • Related Report
      2015 Research-status Report
  • [Presentation] CZTSe化合物プリカーサの硫化・セレン化法によるCu2ZnSn(S,Se)4薄膜太陽電池の作製2015

    • Author(s)
      中嶋崇喜,水井裕一,山口利幸
    • Organizer
      第12回次世代の太陽光発電システムシンポジウム
    • Place of Presentation
      磐梯熱海ホテル華の湯(福島県郡山市)
    • Year and Date
      2015-05-28
    • Related Report
      2015 Research-status Report
  • [Presentation] 連続成膜法によるCu2ZnSn(S,Se)4薄膜太陽電池の作製2014

    • Author(s)
      坂本竜也,中嶋崇喜,山口利幸
    • Organizer
      第4回高専-TUT太陽電池合同シンポジウム
    • Place of Presentation
      神戸市立工業高等専門学校(神戸市)
    • Year and Date
      2014-12-22 – 2014-12-23
    • Related Report
      2014 Research-status Report
  • [Presentation] CZTSe化合物を用いたCu2ZnSn(S,Se)4薄膜作製プロセスの検討2014

    • Author(s)
      畑山耕一,三善巧,中嶋崇喜,山口利幸
    • Organizer
      第4回高専-TUT太陽電池合同シンポジウム
    • Place of Presentation
      神戸市立工業高等専門学校(神戸市)
    • Year and Date
      2014-12-22 – 2014-12-23
    • Related Report
      2014 Research-status Report
  • [Presentation] 連続成膜法によるCu2ZnSnSe4薄膜太陽電池の作製2014

    • Author(s)
      湯川翔平,中嶋崇喜,山口利幸
    • Organizer
      第4回高専-TUT太陽電池合同シンポジウム
    • Place of Presentation
      神戸市立工業高等専門学校(神戸市)
    • Year and Date
      2014-12-22 – 2014-12-23
    • Related Report
      2014 Research-status Report
  • [Presentation] CZTSe化合物を出発材料に用いたCu2ZnSn(S,Se)4薄膜太陽電池の作製2014

    • Author(s)
      水井裕一,畑山耕一,三善巧,中嶋崇喜,山口利幸
    • Organizer
      第4回高専-TUT太陽電池合同シンポジウム
    • Place of Presentation
      神戸市立工業高等専門学校(神戸市)
    • Year and Date
      2014-12-22 – 2014-12-23
    • Related Report
      2014 Research-status Report
  • [Presentation] Cu2ZnSnSe4 Thin Films Prepared by Annealing from Precursor Using Cu2ZnSnSe4 Compound in Selenium and Tin Mixing Atmosphere2014

    • Author(s)
      Mitsuki Nakashima, Toshiyuki Yamaguchi, Kengo Kusumoto, Shohei Yukawa, Junji Sasano and Masanobu Izaki
    • Organizer
      The 6th World Conference on Photovoltaic Energy Conversion
    • Place of Presentation
      国立京都国際会館(京都市)
    • Year and Date
      2014-11-23 – 2014-11-27
    • Related Report
      2014 Research-status Report
  • [Presentation] Cu2ZnSn(S,Se)4 Thin Films Prepared by Annealing in Sulfur, Selenium and Tin Mixing Atmosphere for Photovoltaic Applications2014

    • Author(s)
      Mitsuki Nakashima, Toshiyuki Yamaguchi, Yuichi Mizui, Junji Sasano and Masanobu Izaki
    • Organizer
      The 6th World Conference on Photovoltaic Energy Conversion
    • Place of Presentation
      国立京都国際会館(京都市)
    • Year and Date
      2014-11-23 – 2014-11-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 化合物を出発材料に用いたCu2ZnSn(S,Se)4薄膜太陽電池の作製プロセスの検討2014

    • Author(s)
      水井裕一,畑山耕一,三善巧,中嶋崇喜,山口利幸,伊﨑昌伸
    • Organizer
      平成26年電気関係学会関西連合大会
    • Place of Presentation
      奈良先端科学技術大学院大学(奈良県生駒市)
    • Year and Date
      2014-11-23 – 2014-11-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 連続成膜法による Cu2ZnSnSe4薄膜の作製条件の検討2014

    • Author(s)
      湯川翔平,坂本竜也,中嶋崇喜,山口利幸,伊崎昌伸
    • Organizer
      平成26年電気関係学会関西連合大会
    • Place of Presentation
      奈良先端科学技術大学院大学(奈良県生駒市)
    • Year and Date
      2014-11-23 – 2014-11-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 化合物プリカーサのセレン化によるCu2ZnSnSe4薄膜の作製Ⅱ2014

    • Author(s)
      中嶋崇喜,湯川翔平,楠本健悟,山口利幸
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Fabrication of Cu2ZnSnSe4 Thin Films by Selenization of Precursor using Cu2ZnSnSe4 Compound for Photovoltaic Applications2014

    • Author(s)
      Mitsuki Nakashima, Toshiyuki Yamaguchi, Kengo Kusumoto, Shohei Yukawa, Junji Sasano and Masanobu Izaki
    • Organizer
      19th International Conference on Ternary and Multinary Compounds
    • Place of Presentation
      朱鷺メッセ新潟コンベンションセンター(新潟市)
    • Year and Date
      2014-09-01 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 化合物プリカーサを用いたセレン化法によるCu2ZnSnSe4薄膜の作製2014

    • Author(s)
      湯川翔平,楠本健悟,中嶋崇喜,山口利幸
    • Organizer
      第11回次世代の太陽光発電システムシンポジウム
    • Place of Presentation
      宮崎観光ホテル(宮崎市)
    • Year and Date
      2014-07-03 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Presentation] Se含有プリカーサのSe・S混合雰囲気中での熱処理によるCu2ZnSn(S,Se)4薄膜の作製2014

    • Author(s)
      水井裕一,川津嘉朗,中嶋崇喜,山口利幸
    • Organizer
      第11回次世代の太陽光発電システムシンポジウム
    • Place of Presentation
      宮崎観光ホテル(宮崎市)
    • Year and Date
      2014-07-03 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Remarks] 和歌山工業高等専門学校 電気情報工学科 教員・研究紹介 山口利幸

    • URL

      http://www.wakayama-nct.ac.jp/gakka/denki/denki-staff/denki-yamaguchi/denki-yamaguchi.htm

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
  • [Remarks] 和歌山工業高等専門学校 電気情報工学科 教員・研究紹介

    • URL

      http://www.wakayama-nct.ac.jp/gakka/denki/denki-staff/denki-yamaguchi/denki-yamaguchi.htm

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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