Syntheses of Cationic Metal Complexes with Z-Ligand and Its Application
| Project/Area Number |
26460004
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Kanazawa University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | Z型配位子 / 金 / 触媒反応 / 環化反応 / 金属活性化 |
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| Outline of Final Research Achievements |
The Au complexes featuring a Z-type ligand (boron atom) as a σ-acceptor were developed for elucidating the effect of electron withdrawing on catalytic reactions. An cyclization in the presence of either [Au→B]+ or [Au]+ showed that [Au→B]+ promotes the reactivity, which enabled the effective construction of not only five- and six-membered rings, but also seven-membered rings.
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Report
(4 results)
Research Products
(24 results)
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[Presentation] Z型配位子による金触媒反応の活性化2015
Author(s)
稲垣冬彦、松本千明、岡田泰彦、丸山直哉、向智里
Organizer
日本薬学会 第135年会
Place of Presentation
神戸学院大学、兵庫医療大学（神戸）
Year and Date
2015-03-25 – 2015-03-28
Related Report
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[Patent(Industrial Property Rights)] ２－オキサゾリジノン誘導体の製造方法2015
Inventor(s)
稲垣冬彦,向智里,岡田泰彦,松本千明 山田将之,中澤研太
Industrial Property Rights Holder
稲垣冬彦,向智里,岡田泰彦,松本千明 山田将之,中澤研太
Industrial Property Rights Type
特許
Patent Publication Number
2017-031062
Filing Date
2015-07-29
Acquisition Date
2017-02-09
Related Report
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