| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
|---|
| Outline of Final Research Achievements |
Catalytic discrimination among similarly reactive functional groups is a key to realizing unique and efficient chemo- and regioselective transformations of multi-functionalized molecules; however, formidable challenges to such discrimination remain.
Upon developing axially chiral aniline-type acid base catlysts, catalytic discrimination among formyl groups bearing similar reactivity was achieved in the highly regio-, diastereo-, and enantioselective intramolecular cross-aldol reactions of enolizable aliphatic dials.
|
