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The oxygen isotope anomaly of nitrate as tracer of atmospheric nitrate in marine nitrogen cycling

Research Project

Project/Area Number 26550007
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Environmental dynamic analysis
Research InstitutionTokai University

Principal Investigator

Komatsu Daisuke  東海大学, 海洋学部, 講師 (70422011)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords硝酸 / 安定同位体 / 三酸素同位体 / 化学海洋学 / 窒素循環
Outline of Final Research Achievements

The triple oxygen isotopic compositions of oceanic nitrate can be an useful tracer to quantify the mixing ratios of depositional nitrate within total nitrate in a water mass, because atmospheric nitrate shows large 17O anomaly due to the contribution of atmospheric ozone having large anomaly, whereas re-mineralized nitrate produced biologically shows little 17O anomaly. Determination on the triple oxygen isotopic compositions of nitrate allows us to estimate the mixing ratios of depositional nitrate within total nitrate.
To determine oxygen isotopic compositions of nitrate, nitrate must be reduced to nitrous oxide following to nitrite. Using Cu-coated Cd for reduction to nitrite allow us to save analytical time. We developed new automated analytical system for oxygen isotopic compositions of nitrate at Tokai university. We started to analyze stable isotopic compositions of oceanic nitrate during KH-14-6 of GEOTRACES cruise.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (13 results)

All 2017 2016 2015 2014

All Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Open Access: 3 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Accurate and precise quantification of atmospheric nitrate in streams draining land of various uses by using triple oxygen isotopes as tracers2016

    • Author(s)
      Tsunogai, U., T. Miyauchi, T. Ohyama, D.D. Komatsu, F. Nakagawa, Y. Obata, K. Sato, and T. Ohizumi
    • Journal Title

      Biogeosciences

      Volume: 13 Issue: 11 Pages: 3441-3459

    • DOI

      10.5194/bg-13-3441-2016

    • NAID

      120005763124

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Deep Microbial Life in High-Quality Granitic Groundwater from Geochemically and Geographically Distinct Underground Boreholes.2016

    • Author(s)
      Ino, K., U. Konno, M. Kouduka, A. Hirota, Y. Togo, A. Fukuda, D. Komatsu, U. Tsunogai, A.S. Tanabe, S. Yamamoto, T. Iwatsuki, T. Mizuno, K. Ito, Y. Suzuki
    • Journal Title

      Environmental Microbiology Reports

      Volume: 8 Issue: 2 Pages: 285-294

    • DOI

      10.1111/1758-2229.12379

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrothermal plumes in the Gulf of Aden, as characterized from light transmission, Mn, Fe, CH4 and δ13C-CH4 anomalies.2015

    • Author(s)
      Gamo, T., K. Okamura, H. Hatanaka, H. Hasumoto, D. Komatsu, M. Chinen, M. Mori, J. Tanaka, A. Hirota, U. Tsunogai, K. Tamaki
    • Journal Title

      Deep-Sea Research Part II

      Volume: 121 Pages: 62-70

    • DOI

      10.1016/j.dsr2.2015.06.004

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Quantifying the effects of clear-cutting and strip-cutting on nitrate dynamics in a forested watershed using triple oxygen isotopes as tracers2014

    • Author(s)
      Tsunogai, U., Komatsu, D. D., Ohyama, T., Suzuki, A., Nakagawa, F., Noguchi, I., Takagi, K., Nomura, M., Fukuzawa, K., and Shibata, H.
    • Journal Title

      Biogeosciences

      Volume: 11 Issue: 19 Pages: 5411-5424

    • DOI

      10.5194/bg-11-5411-2014

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 窒素・酸素同位体比を用いた硝酸の動態把握2017

    • Author(s)
      小松大祐、成田尚史
    • Organizer
      海洋地球化学フォーラム
    • Place of Presentation
      高知大学 海洋コア総合研究センター
    • Year and Date
      2017-03-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] 三酸素同位体比を指標に加えることで河川水中の硝酸の起源とその挙動に関する理解を深める2016

    • Author(s)
      角皆潤、宮内貴規、大山拓也、小松大祐、中川書子、小幡祐介
    • Organizer
      2016年度日本地球化学会第63回年会
    • Place of Presentation
      大阪市立大学杉本キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Quantifying Nitrate Dynamics in Lakes Using Triple Oxygen Isotopes as Tracers2016

    • Author(s)
      Urumu Tsunogai, Takanori Miyauchi, Takuya Ohyama, Daisuke Komatsu, Yusuke Obata, Fumiko Nakagawa
    • Organizer
      2016 Goldschmidt Conference
    • Place of Presentation
      Yokohama
    • Year and Date
      2016-06-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 流域の土地利用変化が河川水中の硝酸の起源に与える影響について2016

    • Author(s)
      角皆潤、宮内貴規、大山拓也、小松大祐、中川書子、小幡祐介
    • Organizer
      日本地球惑星科学連合2016年大会
    • Place of Presentation
      幕張メッセ
    • Year and Date
      2016-05-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] 乾性沈着する硝酸と湿性沈着する硝酸の三酸素同位体組成を比較する2015

    • Author(s)
      大山拓也, 角皆潤, 小松大祐, 中川書子, 野口泉, 山口高志
    • Organizer
      第21回大気化学討論会
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2015-10-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 富栄養化湖沼における窒素循環速度の定量:硝酸の天然同位体トレーサーを用いた解析2015

    • Author(s)
      中川書子, 大山拓也, 角皆 潤, 小松大祐, 梅田 信
    • Organizer
      日本地球化学会
    • Place of Presentation
      富山大学
    • Year and Date
      2015-09-16 – 2015-09-18
    • Related Report
      2014 Research-status Report
  • [Presentation] 硝酸の三酸素同位体組成を指標に用いた中栄養湖沼における窒素循環解析2015

    • Author(s)
      宮内 貴規, 大山 拓也, 角皆 潤, 中川 書子, 小松 大祐
    • Organizer
      日本地球化学会
    • Place of Presentation
      富山大学
    • Year and Date
      2015-09-16 – 2015-09-18
    • Related Report
      2014 Research-status Report
  • [Presentation] 自然同位体トレーサーを用いた新生産・再生生産速度の定量:人工同位体トレーサー添加培養法との比較.2015

    • Author(s)
      中川 書子, 小幡 祐介, 角皆 潤, 小松 大祐, 田中 敦, 梅田 信
    • Organizer
      2015年度日本地球化学会第62回年会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 三酸素同位体組成を用いた湖沼における新生産量および再生生産量の定量2015

    • Author(s)
      中川 書子, 角皆 潤, 小松 大祐, 大山 拓也, 宮内 貴規, 佐久間 博基, 南 翔, 蓼沼 雪衣, 梅田 信, 田中 敦
    • Organizer
      日本地球惑星科学連合2015年大会
    • Place of Presentation
      幕張メッセ国際会議場
    • Year and Date
      2015-05-24
    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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