| Project/Area Number |
26550080
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Environmental risk control and evaluation
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| Research Institution | The University of Tokyo |
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Principal Investigator |
Yamamuro Masumi 東京大学, 大学院新領域創成科学研究科, 教授 (80344208)
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| Co-Investigator(Renkei-kenkyūsha) |
TONOKURA Kenichi 東京大学, 大学院新領域創成科学研究科, 教授 (00260034)
HIRATSUKA Kenichi 千葉工業大学, 工学部, 教授 (30181168)
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| Research Collaborator |
YOKOISHI Eiki
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | イソシアネート / ポリウレタン / 屋外大気 / 摩擦 / 柔軟剤 / 生活環境 / 加圧 / LC/MS/MS / PTR-MS / 発生源 |
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| Outline of Final Research Achievements |
We built a method to analyze isocyanate group using dibutylamine as derivatization reagent, and measured the outdoor atmosphere near the factory using the isocyanate. Hexamethylene diisocyanate was detected. By turning an abrasion stick of 5mm in diameter which contained fine particles of the diamond with a motor, and having performed scrape off experiment to push it to polyurethane, we detected 73rd ion although the quantity was little. We sent SafeAir aromatic isocyanates badge (the detective limit is TDI in 0.6ppb, MDI 0.4ppb) to 50 cooperator and asked to set it to the situation with the symptom turned worse with a softening agent in everyday life. Isocyanate was not detected in all cases.
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