Organization of Nanocarbon Molecules Based on Metal Coordination
Project/Area Number |
26600025
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Nanomaterials chemistry
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Research Institution | Kyoto University |
Principal Investigator |
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Project Period (FY) |
2014-04-01 – 2016-03-31
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Project Status |
Completed (Fiscal Year 2015)
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Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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Keywords | 電荷輸送性材料 / 電気伝導体 / 有機金属錯体 / 直接アリール化 / π共役化合物 / 次元性 / 三次元π共役 / 金属錯体 / 多環芳香族化合物 / X線構造解析 / 有機半導体材料 / 多環芳香族炭化水素 / 有機電子材料 / 電子輸送材料 / 三次元パイ電子系 / Alq3 |
Outline of Final Research Achievements |
Development of π-conjugated molecules with a three dimensional (3D) structure have gained increased interests as the charge transporting materials. Metal complexes with π-conjugated ligands are attractive because a wide variety of 3D structures can be constructed, as represented by tris(8-hydroxyquinoline)aluminum (Alq3) for its electron transporting characteristics. We considered that the 3D π-conjugated molecules with enhanced intermolecular π-π interactions in the solid-state can be obtained by an extention of the π-system of the 8-hydroxyquinolinato ligands. In this research, π-extended 8-hydroxyquinolinato ligands were synthesized by using palladium-catalyzed intramolecular direct arylation. We found that the regioselectivity of the intramolecular cyclization can be controlled by the reaction conditions. Then the formation of aluminum complexes were examined and the solid-state structure was revealed by X-ray crystal structure analysis.
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Report
(3 results)
Research Products
(31 results)
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[Presentation] 水分子内包アザフラーレンの合成2015
Author(s)
橋川祥史、村田理尚、若宮淳志、村田靖次郎
Organizer
日本化学会 第95春季年会 (2015)
Place of Presentation
船橋
Year and Date
2015-03-26 – 2015-03-29
Related Report
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