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Control of phase transition by micropore of metal-organic frameworks

Research Project

Project/Area Number 26600026
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Research InstitutionKyushu University

Principal Investigator

Yamada Teppei  九州大学, 工学(系)研究科(研究院), 准教授 (10404071)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords配位高分子 / イオン伝導 / 相転移 / 誘電体 / 相転移点制御 / 強誘電
Outline of Final Research Achievements

Organic ferroelectric materials attract great interest for the application to ferroelectric memory and actuator, because they are low cost and have low coercive field compared to inorganic ferroelectric materials. However, most of these organic ferroelectric materials show low phase transition temperature and could not be applied for real devices. We introduced various ferroelectric ion pairs and molecules into various metal-organic frameworks, and found only several host-guest pair can be achieved. DSC measurement revealed that the phase transition of guest materials disappeared by the introduction into MOFs.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (36 results)

All 2016 2015 2014 Other

All Journal Article (19 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 19 results,  Open Access: 16 results,  Acknowledgement Compliant: 4 results) Presentation (15 results) (of which Int'l Joint Research: 6 results,  Invited: 10 results) Remarks (2 results)

  • [Journal Article] Proton Conductive Metal-Organic Frameworks2016

    • Author(s)
      Teppei Yamada, Masaaki Sadakiyo, Akihito Shigematsu, Hiroshi Kitagawa
    • Journal Title

      Bulletin of Chemical Society of Japan

      Volume: 89 Issue: 1 Pages: 1-10

    • DOI

      10.1246/bcsj.20150308

    • NAID

      130005119461

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A Significant Change in Selective Adsorption Behaviour for Ethanol by Flexibility Control through the Type of Central Metals in a Metal–Organic Framework2016

    • Author(s)
      Masaaki Sadakiyo, Teppei Yamada, Kenichi Kato, Masaki Takata, Hiroshi Kitagawa
    • Journal Title

      Chemical Science

      Volume: 7 Issue: 2 Pages: 1349-1356

    • DOI

      10.1039/c5sc03325j

    • NAID

      120005841414

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes: Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium (II/III)-Based Electrochromism2016

    • Author(s)
      Masaaki Abe, Hiroki Futagawa, Toshikazu Ono, Teppei Yamada, Nobuo Kimizuka, Yoshio Hisaeda
    • Journal Title

      Inorg. Chem.

      Volume: 54 Issue: 23 Pages: 11061-11063

    • DOI

      10.1021/acs.inorgchem.5b02129

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Lithium Ion Diffusion in a Metal-Organic Framework Mediated by an Ionic Liquid2015

    • Author(s)
      K. Fujie, R. Ikeda, K. Otsubo, T. Yamada, H. Kitagawa
    • Journal Title

      Chem. Mater.

      Volume: 27 Issue: 21 Pages: 7355-7361

    • DOI

      10.1021/acs.chemmater.5b02986

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fast and Long-Range Triplet Exciton Diffusion in Metal–Organic Frameworks for Photon Upconversion at Ultralow Excitation Power2015

    • Author(s)
      P. Mahato, A. Monguzzi, *N. Yanai, T. Yamada, *N. Kimizuka
    • Journal Title

      Nature Materials

      Volume: 14 Issue: 9 Pages: 924-930

    • DOI

      10.1038/nmat4366

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Proton Conduction Study on Channel/Layer Networks of LaIIIMIII(ox)3∙10H2O (M = Cr, Co, Ru, La) and Related LaIIICoII(ox)2.5∙4H2O2015

    • Author(s)
      Hisashi Okawa, Masaaki Sadakiyo, Kazuya Otsubo, Ko Yoneda, Teppei Yamada, Masaaki Ohba, Hiroshi Kitagawa
    • Journal Title

      Inorganic Chemistry

      Volume: 54 Issue: 17 Pages: 8529-8535

    • DOI

      10.1021/acs.inorgchem.5b01176

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hybrid Materials of Ni NP@MOF prepared by a Simple Synthetic Method2015

    • Author(s)
      M. Mukoyoshi, H. Kobayashi, K. Kusada, M. Hayashi, T. Yamada, M. Maesato, Jared M. Taylor, Y. Kubota, K. Kato, M. Takata, T. Yamamoto, S. Matsumura, H. Kitagawa
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 62 Pages: 10169-10172

    • DOI

      10.1039/c5cc04663g

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Low temperature ionic conductor: ionic liquid incorporated within a metal-organic framework2015

    • Author(s)
      Kazuyuki Fujie, Kazuya Otsubo, Ryuichi Ikeda, Teppei Yamada, Hiroshi Kitagawa
    • Journal Title

      Chem. Sci.

      Volume: 6 Issue: 7 Pages: 4306-4310

    • DOI

      10.1039/c5sc01398d

    • NAID

      120005841410

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Photoliquefiable Ionic Crystals: A Phase Crossover Approach for Photon Energy Storage Materials with Functional Multiplicity2015

    • Author(s)
      K. Ishiba, M-a. Morikawa, C. Chikara, T. Yamada, K. Iwase, M. Kawakita, N. Kimizuka
    • Journal Title

      Angew. Chem.Int. Ed.

      Volume: 54 Issue: 5 Pages: 1532-1536

    • DOI

      10.1002/anie.201410184

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Morphology-Controlled Synthesis of Cubic Cesium Hydrogen Silicododecatungstate Crystals2014

    • Author(s)
      S. Uchida, Y. Ogasawara, T. Maruichi, A. Kumamoto, Y. Ikuhara, T. Yamada, H. Kitagawa, N. Mizuno
    • Journal Title

      Crystal Growth and Design

      Volume: 14 Issue: 12 Pages: 6620-6626

    • DOI

      10.1021/cg501575x

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Proton Conductivity Control by Ion Substitution in a Highly Proton-Conductive Metal?Organic Framework2014

    • Author(s)
      Masaaki Sadakiyo, Teppei Yamada, Hiroshi Kitagawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 38 Pages: 13166-13169

    • DOI

      10.1021/ja507634v

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Introduction of an Ionic Liquid into the Micropores of a Metal?Organic Framework and Its Anomalous Phase Behavior2014

    • Author(s)
      Kazuyuki Fujie, Teppei Yamada, Ryuichi Ikeda, Hiroshi Kitagawa
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 53 Issue: 42 Pages: 11302-11305

    • DOI

      10.1002/anie.201406011

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] A Systematic Study on the Stability of Porous Coordination Polymers against Ammonia2014

    • Author(s)
      T. Kajiwara, M. Higuchi, D. Watanabe, H. Higashimura, T. Yamada, H. Kitagawa
    • Journal Title

      Chem. Eur. J.

      Volume: 20 Issue: 47 Pages: 15611-15617

    • DOI

      10.1002/chem.201403542

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Anomalous Enhancement of Proton Conductivity for Water Molecular Clusters Stabilized in Interstitial Spaces of Porous Molecular Crystals2014

    • Author(s)
      M. Tadokoro, Y. Ohhata, Y. Shimazaki, S. Ishimaru, T. Yamada, Y. Nagao, T. Sugaya, K. Isoda, Y. Suzuki, H. Kitagawa, and H. Matsui
    • Journal Title

      Chemistry - A European Journal

      Volume: 20 Issue: 42 Pages: 13698-13709

    • DOI

      10.1002/chem.201402900

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Proton dynamics of two-dimensional oxalate-bridged coordination polymers2014

    • Author(s)
      Satoshi Miyatsu, Maiko Kofu, Atsushi Nagoe, Takeshi Yamada, Masaaki Sadakiyo, Teppei Yamada, Hiroshi Kitagawa, Madhusudan Tyagi, Victoria Garcı´a Sakai and Osamu Yamamuro
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 16 Issue: 32 Pages: 17295-17304

    • DOI

      10.1039/c4cp01432d

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Control of Crystalline Proton-Conducting Pathways by Water-Induced Transformations of Hydrogen-Bonding Networks in a Metal-Organic Framework2014

    • Author(s)
      M. Sadakiyo, T. Yamada, K. Honda, H. Matsui, and H. Kitagawa
    • Journal Title

      Journal of the American Chemical Society

      Volume: 136 Issue: 21 Pages: 7701-7707

    • DOI

      10.1021/ja5022014

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Coordination Lamellar Nanofiber Consisting of N-(2-Hydroxy-n-dodecyl)-L-alanine and Divalent Copper2014

    • Author(s)
      Teppei Yamada, Yusuke Minami, Nobuo Kimizuka
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 7 Pages: 1031-1033

    • DOI

      10.1246/cl.140271

    • NAID

      130004868266

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis, Water Adsorption and Proton Conductivity of Solid-Solution Type Metal-Organic Frameworks Al (OH)(bdc-OH)_x (bdc-NH_2)_<1-x>2014

    • Author(s)
      T. Yamada, Y. Shirai, H. Kitagawa
    • Journal Title

      Chemistry an Asian Journal

      Volume: 9(in press) Issue: 5 Pages: 1316-1320

    • DOI

      10.1002/asia.201301673

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] A 3D Coordination Polymer of Cd (II) with an Imidazolium Based Linker Showing Parallel Polycatenation Forming Channels with Aligned Imidazolium Groups2014

    • Author(s)
      S. Sen, T. Yamada, H. Kitagawa, P. K. Bharadwaj
    • Journal Title

      Crystal Growth and Design

      Volume: 14 Issue: 3 Pages: 1240-1244

    • DOI

      10.1021/cg401760m

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Redox activity of a nanoporous metal-organic framework MIL-100 for cathode of lithium ion battery2015

    • Author(s)
      山田鉄兵
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawaii convention center
    • Year and Date
      2015-12-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Creation of chiral ionic plastic crystals and its proton conductivity2015

    • Author(s)
      山田鉄兵
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawaii Convention Center
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] CONTROL OF IONIC MOTION IN ASYMMETRIC NANOSPACE2015

    • Author(s)
      山田鉄兵
    • Organizer
      日中クラスター会議 10th CJSMCC
    • Place of Presentation
      福州
    • Year and Date
      2015-10-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] キラリティを導入した イオン性柔粘性結晶化合物の マイクロ秒スケールでの運動と カタチに由来するイオン伝導性の制御2015

    • Author(s)
      山田鉄兵
    • Organizer
      SP-8研究交流会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Redox stability of MIL-100(Fe) toward cathode of lithium ion battery2015

    • Author(s)
      山田鉄兵
    • Organizer
      12th International Conference on Materials Chemistry (MC12)
    • Place of Presentation
      ヨーク大学
    • Year and Date
      2015-07-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] キラルな空間とイオン伝導2015

    • Author(s)
      山田鉄兵
    • Organizer
      第6回統合物質若手研究会
    • Place of Presentation
      別府ホテル清風
    • Year and Date
      2015-07-03
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Peculiar Ion Dynamics in a Confined Ionic Packings in a Plastic Crystal Phase2015

    • Author(s)
      山田鉄兵
    • Organizer
      2015 International Conference on Nanospace Materials
    • Place of Presentation
      台湾大学
    • Year and Date
      2015-06-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ion dynamics in chiral nanospace2015

    • Author(s)
      山田鉄兵
    • Organizer
      Joint Inorganic Chemistry Symposium
    • Place of Presentation
      精華大学
    • Year and Date
      2015-06-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノ細孔を利用したイオン伝導の制御と応用2015

    • Author(s)
      山田鉄兵
    • Organizer
      日本膜学会 第37年会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-05-15
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Proton conduction through disordered hydrogen bond network in ordered nanospace2014

    • Author(s)
      Teppei Yamada
    • Organizer
      MOF-2014
    • Place of Presentation
      神戸
    • Year and Date
      2014-10-01
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 規則的に並んだ乱雑さの構築と細孔内イオン伝導体の構築2014

    • Author(s)
      山田鉄兵
    • Organizer
      量子ビームによるナノバイオサイエンス技術調査委員会
    • Place of Presentation
      長崎県工業センター 大村市
    • Year and Date
      2014-08-23
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] High proton conductivity of zinc oxalate metal-organic frameworks2014

    • Author(s)
      Teppei Yamada
    • Organizer
      ACS fall meeting
    • Place of Presentation
      San Fransisco
    • Year and Date
      2014-08-10
    • Related Report
      2014 Research-status Report
  • [Presentation] 細孔内イオンの並進運動2014

    • Author(s)
      山田鉄兵
    • Organizer
      イオンチャネル勉強会
    • Place of Presentation
      京都大学
    • Year and Date
      2014-07-16
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Synthesis and phase behavior of chiral ionic plastic crystal toward unconventional ionic transport material2014

    • Author(s)
      Teppei Yamada, Masaya Matsuki, Nobuo Kimizuka
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 配位高分子の最高に規則的に並んだ乱雑さとイオン伝導性2014

    • Author(s)
      山田鉄兵
    • Organizer
      お茶の水女子大学化学科講演会
    • Place of Presentation
      お茶の水女子大学
    • Year and Date
      2014-04-15
    • Related Report
      2014 Research-status Report
    • Invited
  • [Remarks] 個人ページ

    • URL

      https://sites.google.com/site/teppeiyamada0901/

    • Related Report
      2014 Research-status Report
  • [Remarks] Researchmap

    • URL

      http://researchmap.jp/read0142644/

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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