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Fabrication of multi-component oxide using supercritical fluid deposition for ferroelectric random access memory

Research Project

Project/Area Number 26600040
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanomaterials engineering
Research InstitutionThe University of Tokyo

Principal Investigator

Momose Takeshi  東京大学, 大学院工学系研究科(工学部), 講師 (10611163)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords強誘電体薄膜 / 3次元メモリ / 超臨界流体 / 製膜
Outline of Final Research Achievements

For improving the integration density of ferroelectric random access memory, fabrication of ferroelectric film onto 3-dimensional features with high growth rate and high conformality is mandatory. We therefore studied supercritical fluid deposition (SCFD). Via quantitative evaluation of its reaction kinetics and transport properties, TiO2 deposition with high growth rate and high conformality was achieved. Then, deposition of Bi4Ti3O12 (BiT) was enabled by adding a Bi precursor to TiO2-SCFD, in which BiT film formation with uniform film thickness and chemical composition was successful onto high-aspect-ratio features. We then studied SCFD of RuO2 for electrode formation and post-anneal of BiT to improve its crystallinity, and thereby achieved the stacked layer structure composed of BiT and RuO2 onto high-aspect-ratio features.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (11 results)

All 2017 2016 2015 2014

All Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Experimental Approach to Estimate Diffusivity of Metal Organics in Supercritical CO2 at High Temperatures2017

    • Author(s)
      チョウ ユウ、下山 裕介、百瀬 健、霜垣 幸浩
    • Journal Title

      The Journal of Supercritical Fluids

      Volume: V. 120 part2 Pages: 209-217

    • DOI

      10.1016/j.supflu.2016.05.048

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Thin film deposition using chemical reaction in supercritical fluid for high-aspect-ratio 3-dimensional features2017

    • Author(s)
      チョウ ユウ,下山 裕介,百瀬 健,霜垣 幸浩
    • Organizer
      化学工学会 第82年会
    • Place of Presentation
      芝浦工業大学,豊洲,東京
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Supercritical fluid deposition of conformal oxide films: 3-dimentionally-stacked RuO2/TiO2/RuO2 structures for MIM capacitors2017

    • Author(s)
      Yu Zhao, Yusuke Shimoyama, Takeshi Momose, Yukihiro Shimogaki
    • Organizer
      Electron Devices Technology and Manufacturing Conference 2017
    • Place of Presentation
      富山,日本
    • Year and Date
      2017-02-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 超臨界流体を用いたBi4Ti3O12製膜における反応機構解析2016

    • Author(s)
      チョウ ユウ,下山 裕介,百瀬 健,霜垣 幸浩
    • Organizer
      化学工学会 第48回秋季大会
    • Place of Presentation
      徳島大学,徳島,徳島
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 超臨界流体により形成したRuO2薄膜の結晶化に向けたアニール処理2016

    • Author(s)
      チョウ ユウ,下山 裕介,百瀬 健,霜垣 幸浩
    • Organizer
      化学工学会 第81年会
    • Place of Presentation
      関西大学,大阪府,大阪市
    • Year and Date
      2016-03-13
    • Related Report
      2015 Research-status Report
  • [Presentation] New approach to estimate diffusivity of metal organics in supercritical CO2 at high temperatures2015

    • Author(s)
      Yu Zhao, Takeshi Momose, Shimoyama Yusuke, and Yukihiro Shimogaki
    • Organizer
      11th International Symposium on Supercritical Fluids
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2015-10-11
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 反応速度論に基づく超臨界CO2流体中 拡散係数の新規推定方法2015

    • Author(s)
      チョウ ユウ,百瀬 健,下山 裕介,霜垣 幸浩
    • Organizer
      化学工学会 第47回秋季大会
    • Place of Presentation
      北海道大学,北海道,札幌市
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] コンフォーマルな超臨界流体堆積におけるCO2圧力の影響2015

    • Author(s)
      チョウ ユウ,百瀬 健,下山 裕介,霜垣 幸浩
    • Organizer
      化学工学会 第47回秋季大会
    • Place of Presentation
      北海道大学,北海道,札幌市
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] 超臨界流体堆積法を用いた強誘電体メモリ用Bi4Ti3O12の均一製膜2015

    • Author(s)
      チョウ ユウ,百瀬 健,霜垣 幸浩
    • Organizer
      化学工学会 第80年会
    • Place of Presentation
      芝浦工業大学,豊洲,東京
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] Conformal Deposition of Crystalline Bi4Ti3O12 Using Supercritical Fluid Deposition for 3D-Structure Ferroelectric Memories2014

    • Author(s)
      Yu Zhao, Kyubong Jung, Takeshi Momose, Yukihiro Shimogaki
    • Organizer
      Material Research Society, Fall meeting, 2015
    • Place of Presentation
      Boston, USA
    • Year and Date
      2014-11-29 – 2014-12-04
    • Related Report
      2014 Research-status Report
  • [Presentation] 超臨界流体堆積法を用いた量論組成Bi4Ti3O12製膜2014

    • Author(s)
      チョウ ユウ,鄭 珪捧,百瀬 健,霜垣 幸浩
    • Organizer
      化学工学会 第46回秋季大会
    • Place of Presentation
      九州大学,博多,福岡
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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