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Development of graphene oxide based room temperature ferromagnets and superconductors by radical manipulation

Research Project

Project/Area Number 26600076
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Applied materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

Taniguchi Takaaki  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主任研究員 (50583415)

Co-Investigator(Kenkyū-buntansha) YOKOI HIROYUKI  熊本大学, 大学院自然科学研究科, 准教授 (50358305)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywordsグラフェン / 酸化グラフェン / 強磁性 / 超伝導 / ナノシート / 超電導
Outline of Final Research Achievements

This study have focused on development of new room-temperature ferromagnets and superconductors based on reduced graphene oxide. The reduced graphene oxides by electrochemical,thermal,photo, chemical, and hydrothermal approach yielded various graphene oxides with different local- and micro-structures to show magnetic properties depending on the reduction methods. In particular, photo-reduced graphene oxide have carbon vacancies with partial hydrogen terminations, which gave ferromagnetic properties. We also found that electrochemical reduction removed carbon radicals, while re-oxidation gave carbon radicals, where these reactions were reversible. Although we could not archive to find out the room-temperature superconductivities in our samples, we revealed potential of giant magneto-resistance and large pseudo-capacitance in electrochemically reduced graphene oxide.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (5 results)

All 2016 2015 2014

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (1 results) (of which Invited: 1 results)

  • [Journal Article] Novel pot-shaped carbon nanomaterial synthesized in a submarine-style substrate heating CVD method2016

    • Author(s)
      Hiroyuki Yokoi, Kazuto Hatakeyama, Takaaki Taniguchi, Michio Koinuma, Masahiro Hara and Yasumichi Matsumoto
    • Journal Title

      Journal of Materials Research

      Volume: 31 Issue: 1 Pages: 117-126

    • DOI

      10.1557/jmr.2015.389

    • NAID

      120005764248

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Oxide: A Fertile Nanosheet for Various Applications2015

    • Author(s)
      S. Obata, K. Saiki, T. Taniguchi, T. Ihara, Y. Kitamura, and Y. Matsumoto
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 84 Issue: 12 Pages: 121012-121029

    • DOI

      10.7566/jpsj.84.121012

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] pH-driven, reversible epoxy ring opening/closing in graphene oxide2015

    • Author(s)
      Takaaki Taniguchi, Seiji Kurihara,, Hikaru Tateishi, Kazuto Hatakeyama, Michio Koinuma, Hiroyuki Yokoi, Masahiro Hara, Hayato Ishikawa, Yasumichi Matsumoto
    • Journal Title

      Carbon

      Volume: 84 Pages: 560-566

    • DOI

      10.1016/j.carbon.2014.12.054

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Correlated Optical and Magnetic Properties in Photoreduced Graphene Oxide2014

    • Author(s)
      Takaaki Taniguchi, Hiroyuki Yokoi, Masaki Nagamine, Hikaru Tateishi, Asami Funatsu, Kazuto Hatakeyama, Chikako Ogata, Masao Ichida, Hiroaki Ando, Michio Koinuma, and Yasumichi Matsumoto
    • Journal Title

      Journal of physical chemistry C

      Volume: 118 Issue: 48 Pages: 28258-28265

    • DOI

      10.1021/jp509399x

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Engineering Luminescent and Magnetic Properties of Graphene Oxide by Photochemical Reactions2014

    • Author(s)
      Takaaki Taniguchi
    • Organizer
      International Union of Materials Research Societies
    • Place of Presentation
      福岡大学
    • Year and Date
      2014-08-24 – 2014-08-28
    • Related Report
      2014 Research-status Report
    • Invited

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Published: 2014-04-04   Modified: 2017-05-10  

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