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Fabrication of layered Bi oxide single crystalline thin film with anomalous valence by developing reductive solid phase epitaxy

Research Project

Project/Area Number 26600091
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionTohoku University (2015)
The University of Tokyo (2014)

Principal Investigator

FUKUMURA Tomoteru  東北大学, 理学(系)研究科(研究院), 教授 (90333880)

Research Collaborator HASEGAWA Tetsuya  
SEI Ryosuke  
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsエピタキシャル / 超格子 / 酸化物 / スピン軌道相互作用 / 磁気抵抗 / 物性実験 / 電子・電気材料
Outline of Final Research Achievements

Y2O2Bi is a layered compound possessing anomalous valence Bi2- square net. Only powder polycrystal has been synthesized in previous studies, so that intrinsic physical properties were not sufficiently investigated. In this study, we developed reductive solid phase epitaxy with powder precursor for thin film epitaxy of this compound. Subsequently, we developed multilayer solid phase epitaxy, resulting in large improvement of thin film crystallinity. Consequently, we successfully observed two dimensional electronic transport with large spin orbit interaction owing to the Bi square net. By using the solid phase epitaxy, various R2O2Bi (R = rare earth) epitaxial thin films were grown. These R2O2Bi showed peculiar magnetotransport properties reflecting interaction between f electron magnetism and Bi square net.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (11 results)

All 2015 2014

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (9 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results)

  • [Journal Article] 2D Electronic Transport with Strong Spin -Orbit Coupling in Bi2- Square Net of Y2O2Bi Thin Film Grown by Multilayer Solid-Phase Epitaxy2015

    • Author(s)
      R. Sei, T. Fukumura, T. Hasegawa
    • Journal Title

      ACS Appl. Mater. Interfac.,

      Volume: 7 Issue: 45 Pages: 24998-24501

    • DOI

      10.1021/acsami.5b07825

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Reductive Solid Phase Epitaxy of Layered Y2O2Bi with Bi2- Square Net from (Y, Bi) Powders and Y2O3 Amorphous Thin Film2014

    • Author(s)
      Ryosuke Sei, Tomoteru Fukumura, Tetsuya Hasegawa
    • Journal Title

      Crystal Growth & Design

      Volume: 14 Issue: 9 Pages: 4227-4229

    • DOI

      10.1021/cg5009297

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Oxide Electronics2015

    • Author(s)
      T. Fukumura
    • Organizer
      Seminar at National Chiao Tung University
    • Place of Presentation
      Hsinchu, Taiwan
    • Year and Date
      2015-11-20
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Oxide Electronics2015

    • Author(s)
      T. Fukumura
    • Organizer
      Seminar at National Chung Hsing University
    • Place of Presentation
      Taichung, Taiwan
    • Year and Date
      2015-11-18
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Reductive Solid Phase Epitaxy and Physical Properties of Layered Y2O2Bi Thin Film with Bi2- Square Net2015

    • Author(s)
      R. Sei, D. Oka, T. Fukumura, T. Hasegawa
    • Organizer
      Tohoku University Campus Asia Summer School 2015
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2015-08-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] World of oxide electronics2015

    • Author(s)
      T. Fukumura
    • Organizer
      Tohoku University Campus Asia Summer School 2015
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2015-08-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thin film epitaxy of functional oxides2015

    • Author(s)
      T. Fukumura, J. Wei, S. Kojima, T. S. Krasienapibal, R. Sei, K. Kaminaga, D. Oka, Y. Hirose, T. Hasegawa
    • Organizer
      588. WE-Heraeus Seminar: Element Specific Structure Determination in Materials on Nanometer and Sub-Nanometer Scales using modern X-Ray and Neutron Techniques
    • Place of Presentation
      Bad Honnef, Germany
    • Year and Date
      2015-04-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reductive Solid Phase Epitaxy of Layered Y2O2Bi Thin Film with Bi2- Square Net and its Electronic Transport Properties2015

    • Author(s)
      R. Sei, T. Fukumura, T. Hasegawa
    • Organizer
      2015 MRS Spring Meeting
    • Place of Presentation
      San Fransisco, USA
    • Year and Date
      2015-04-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 異常原子価酸化物の還元性固相エピタキシー2015

    • Author(s)
      福村知昭、清良輔、T. Krasienapibal、J. Wei、長谷川哲也
    • Organizer
      金研共同利用研究会「薄膜プロセスによる固相合成の新展開」
    • Place of Presentation
      東北大学(宮城県仙台市)
    • Year and Date
      2015-01-29 – 2015-01-30
    • Related Report
      2014 Research-status Report
  • [Presentation] Bi2-正方格子を持つ層状酸化物Y2O2Bi薄膜の還元性固相エピタキシーと電子輸送特性2014

    • Author(s)
      清 良輔,福村 知昭,長谷川 哲也
    • Organizer
      第一回「3D活性サイト科学」公開ワークショップ
    • Place of Presentation
      CIVI研修センター(大阪府大阪市)
    • Year and Date
      2014-11-21 – 2014-11-22
    • Related Report
      2014 Research-status Report
  • [Presentation] Bi2-正方格子を持つ層状酸化物Y2O2Bi エピタキシャル薄膜の物性2014

    • Author(s)
      清 良輔,福村 知昭,長谷川 哲也
    • Organizer
      2014年秋季 第75回 応用物理学会学術講演会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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