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Development of electrode catalysts supported on fine particles alternative to Pt

Research Project

Project/Area Number 26600093
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionYokohama National University

Principal Investigator

Tanaka Masatoshi  横浜国立大学, 工学(系)研究科(研究院), 教授 (90130400)

Co-Investigator(Kenkyū-buntansha) SEKIYA TAKAO  横浜国立大学, 工学研究院, 教授 (60211322)
OHNO SHIN-YA  横浜国立大学, 工学研究院, 准教授 (00377095)
Research Collaborator IWATA HIROSHI  京浜ラムテック
ISHII HIROKI  横浜国立大学, 工学府, 博士課程前期学生
KATO DAIKI  横浜国立大学, 工学府, 博士課程前期学生
FURUSAWA MASASHI  横浜国立大学, 理工学部, 学生
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords薄膜新材料 / Pt代替触媒 / 表面界面物性
Outline of Final Research Achievements

A sputtering system specialized in thin film formation of catalysts alternative to Pt, such as ZrON and TaON, on fine particles of carbon was developed. ZrO2 and ZrON thin films were formed on fused quartz plates, and characterized by X-ray diffraction and photo-absorption spectroscopy. Oxygen reduction reaction starting potential was evaluated by cyclic voltammetry. Some films are found to have high catalytic ability close to an ideal value.
If the technique for thin film formation directly on fine particles of carbon heated above 1100K is established, these alternative catalysts can be supported on practical membrane electrode assemblies, which will contribute to full-fledged popularization of polymer electrolyte fuel cell in instead of Pt.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (5 results)

All 2015

All Presentation (5 results) (of which Int'l Joint Research: 1 results)

  • [Presentation] 低ダメージスパッタリングカソードを用いた酸化、窒化ジルコニウム薄膜の作成2015

    • Author(s)
      古澤将司, 石井裕樹, 加藤大輝, 岩田 寛, 関谷隆夫, 田中正俊
    • Organizer
      第26回光物性研究会
    • Place of Presentation
      神戸大学百年記念会館
    • Year and Date
      2015-12-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] 低ダメージスパッタカソードの開発と評価2015

    • Author(s)
      岩田寛,岡田圭佑,石井裕樹,加藤大輝,関谷隆夫,田中正俊
    • Organizer
      2015年真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2015-12-01
    • Related Report
      2015 Annual Research Report
  • [Presentation] 反応性スパッタリングを用いた酸化ジルコニウム薄膜の作製と評価2015

    • Author(s)
      加藤大輝,石井裕樹,古澤将司,岩田寛,関谷隆夫,田中正俊
    • Organizer
      2015年真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2015-12-01
    • Related Report
      2015 Annual Research Report
  • [Presentation] DC マグネトロンスパッタリングによる窒化ジルコニウム薄膜の作製と物性2015

    • Author(s)
      石井裕樹,加藤大輝,古澤将司,岩田寛,関谷隆夫,田中正俊
    • Organizer
      2015年真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2015-12-01
    • Related Report
      2015 Annual Research Report
  • [Presentation] Development of low damage sputtering cathode and evaluation of its performance2015

    • Author(s)
      H. Iwata, K. Okada, H. Ishii, D. Kato, T. Sekiya, M. Tanaka
    • Organizer
      The 37th International Symposium on Dry Process
    • Place of Presentation
      Awaji Yumebutai International Conference Center, Hyogo
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research

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Published: 2014-04-04   Modified: 2017-05-10  

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