| Project/Area Number |
26610087
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Condensed matter physics I
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| Research Institution | Wakayama University |
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Principal Investigator |
SHINOZUKA Yuzo 和歌山大学, システム工学部, 教授 (30144918)
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| Co-Investigator(Kenkyū-buntansha) |
YAMAKADO Hideo 和歌山大学, システム工学部, 准教授 (30242035)
伊東 千尋 和歌山大学, システム工学部, 教授 (60211744)
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| Co-Investigator(Renkei-kenkyūsha) |
ITOH Chihiro 和歌山大学, システム工学部, 教授 (60211744)
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 嫌光性 / 光誘起構造変化 / 断熱不安定性 / ジアセチレン / フォトクロミズム / 低次元物質 / 励起子 / １次元物質 |
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| Outline of Final Research Achievements |
We have studied theoretically and experimentally on material instability under illumination. Targets are low dimensional materials, where fundamental electronic excitations, excitons, are automatically self-trapped. We have found the followings:
1) Second exciton creation with a smaller energy is possible in during the lattice relaxation caused by a first exciton creation. 2) New type of alloys phenazine-(TCNQ1-x FTCNQx) are successfully synthesized. Although x=0.4 alloy shows the same crystal structure as of x=0 and 1.0, alloys with x=0.6 show molecular dimerization. 3) Single crystal diacetylene has been found to show structural changes accompanied by symmetry changes, suggesting structural instability might depend on conformation of side chains.
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