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Development of rapid isotope analysis by micro-fluorination method

Research Project

Project/Area Number 26610180
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Geochemistry/Cosmochemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

Ueno Yuichiro  東京工業大学, 理工学研究科, 准教授 (90422542)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords物質循環
Outline of Final Research Achievements

A nobel micro-fluorination method has been developed for rapid high precision quadruple sulfur isotope analysis (Ueno et al., 2015 Chemical Geology). In contrast to the previous F2 method, reaction with solid CoF3 reagent allows us to fluorinate sulfide samples into SF6 gas within several second. Futhermore, the analytical protocols were successfully optimized for analyzing small samples down to 100 nmolS with the highest precision that has made by conventional F2 method. In addition, the same technique was shown to be applicable to fluorinate pyrites directly.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (18 results)

All 2016 2015 2014

All Journal Article (9 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 9 results,  Acknowledgement Compliant: 5 results,  Open Access: 3 results) Presentation (9 results) (of which Int'l Joint Research: 4 results,  Invited: 4 results)

  • [Journal Article] Influence of cell's growth phase on the sulfur isotopic fractionation during in vitro microbial sulfate reduction2016

    • Author(s)
      Matsu'ura F, Sunamura M, Ueno Y, Urabe T
    • Journal Title

      Chemical Geology

      Volume: 431 Pages: 1-9

    • DOI

      10.1016/j.chemgeo.2016.03.017

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Rapid quadruple sulfur isotope analysis at the sub-micromole level by a flash heating with CoF32015

    • Author(s)
      Ueno Y, Aoyama S, Endo Y, Matsu'ura F, Foriel J
    • Journal Title

      Chemical Geology

      Volume: 419 Pages: 29-35

    • DOI

      10.1016/j.chemgeo.2015.10.032

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Authigenic carbonate precipitation at the end-Guadalupian (Middle Permian) in China: Implications for the carbon cycle in ancient anoxic oceans2015

    • Author(s)
      Masafumi Saitoh, Yuichiro Ueno, Yukio Isozaki, Takazo Shibuya, Jianxin Yao, Zhansheng Ji, Katsumi Shozugawa, Motoyuki Matsuo, Naohiro Yoshida
    • Journal Title

      Progress in Earth and Planetary Science

      Volume: 2 Issue: 1 Pages: 1-19

    • DOI

      10.1186/s40645-015-0073-2

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Simultaneous determinations of fluorine, chlorine, and sulfur in rock samples by ion chromatography combined with pyrohydrolysis2015

    • Author(s)
      Shimizu, K., Suzuki, K., Saitoh, M., Konno, U., Kawagucci, S., Ueno, Y.
    • Journal Title

      GEOCHEMICAL JOURNAL

      Volume: 49 Issue: 1 Pages: 113-124

    • DOI

      10.2343/geochemj.2.0338

    • NAID

      130004857883

    • ISSN
      0016-7002, 1880-5973
    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Photoabsorption cross-section measurements of 32S, 33S, 34S and 36S sulfur dioxide from 190 to 220 nm2015

    • Author(s)
      Y. Endo, S. O. Danielache, Y. Ueno, S. Hattori, M. S. Johnson, N. Yoshida, H. G. Kjaergaard
    • Journal Title

      J. Geophys. Res. Atmos.,

      Volume: 120 Issue: 6 Pages: 2546-2557

    • DOI

      10.1002/2014jd021671

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Microbial sulfate reduction within the Iheya North subseafloor hydrothermal system constrained by quadruple sulfur isotopes2014

    • Author(s)
      Aoyama, S., Nishizawa, M., Takai, K., and Ueno, Y.
    • Journal Title

      Earth and Planetary Science Letters

      Volume: 398 Pages: 113-126

    • DOI

      10.1016/j.epsl.2014.04.039

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Coping with low ocean sulfate2014

    • Author(s)
      Ueno, Y
    • Journal Title

      Science

      Volume: 346 Issue: 6210 Pages: 703-704

    • DOI

      10.1126/science.1261676

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Isotopic evidence for water-column denitrification and sulfate reduction at the end-Guadalupian (Middle Permian)2014

    • Author(s)
      Masafumi Saitoh, Yuichiro Ueno, Yukio Isozaki, Manabu Nishizawa, Katsumi Shozugawa, Tetsuya Kawamura, Jianxin Yao, Zhansheng Ji, Ken Takai, Naohiro Yoshida, and Motoyuki Matsuo
    • Journal Title

      Global and Planetary Change

      Volume: 123 Pages: 110-120

    • DOI

      10.1016/j.gloplacha.2014.10.014

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Determination of the sulfur isotope ratio in carbonyl sulfide using gas chromatography/isotope ratio mass spectrometry on fragment ions 32S+, 33S+, and 34S+,2014

    • Author(s)
      Shohei Hattori, Akari Toyoda, Sakae Toyoda, Sakiko Ishino, Yuichiro Ueno, and Naohiro Yoshida
    • Journal Title

      Anal. Chem.

      Volume: 87 Issue: 1 Pages: 477-84

    • DOI

      10.1021/ac502704d

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] SO2 photochemistry under reducing atmosphere & Archean S-MIF2015

    • Author(s)
      Ueno Y, Danielache S and Endo Y
    • Organizer
      大気化学討論会 International session
    • Place of Presentation
      Tokyo, JP
    • Year and Date
      2015-10-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Multiple sulfur isotope geochemistry of the early Archean Onverwacht Suite, Barberton Greenstone Belt, South Africa2015

    • Author(s)
      Mishima K, Ueno Y, DeWitt M, and Furnes H.
    • Organizer
      Goldschmidt Conference
    • Place of Presentation
      Prague, CZ
    • Year and Date
      2015-08-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Microbial activity below Archean seafloor constrained by quadruple sulfur isotopes of pyrite within ca. 3.5 Ga basalts from North Pole area, Western Australia2015

    • Author(s)
      Aoyama S and Ueno Y
    • Organizer
      Goldschmidt Conference
    • Place of Presentation
      Prague, CZ
    • Year and Date
      2015-08-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Biogeochemistry of life-inhabited planets: Lessons from Early Earth2015

    • Author(s)
      Ueno Y
    • Organizer
      JPGU Geoscience Ahead
    • Place of Presentation
      Makuhari, JP
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Perturbations of the nitrogen cycle in mid-Panthalassa in the Late Guadalupian (Middle Permian)2015

    • Author(s)
      Saito M, Nishizawa M, Ueno Y, Kofukuda D, Isozaki Y and Takai K
    • Organizer
      JPGU annual meeting
    • Place of Presentation
      Makuhari, JP
    • Year and Date
      2015-05-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 35億年前の南アフリカ、バーバートン緑色岩帯における高解像度4種硫黄同位体比分析2014

    • Author(s)
      三島郁、上野雄一郎、Maarten de Wit、Harald Furnes、齋藤拓也
    • Organizer
      2014年度日本地球化学会年会
    • Place of Presentation
      富山大学五福キャンパス
    • Year and Date
      2014-09-16 – 2014-09-18
    • Related Report
      2014 Research-status Report
  • [Presentation] 玄武岩とコマチアイトの四種硫黄同位体比から制約す る太古代海底下の微生物硫酸還元活動2014

    • Author(s)
      青山慎之介, 上野雄一郎
    • Organizer
      2014年度日本地球化学会年会
    • Place of Presentation
      富山大学五福キャンパス
    • Year and Date
      2014-09-16 – 2014-09-18
    • Related Report
      2014 Research-status Report
  • [Presentation] Reproducing the Archean D36S/D33S trend by optically-thin SO2 photolysis and photo-excitation2014

    • Author(s)
      Ueno, Y., Mishima K, Endo Y and Danielache S
    • Organizer
      7th International Symposium on Isotopomers
    • Place of Presentation
      Tokyo Tech Front
    • Year and Date
      2014-07-01 – 2014-07-04
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 初期大気進化の解読:D36S/D3S化学層序の実験的復元2014

    • Author(s)
      上野雄一郎、遠藤美朗、三島郁、ダニエラチェセバスチャン
    • Organizer
      日本地球惑星科学連合 連合大会 2014年大会
    • Place of Presentation
      パシフィコ横浜(横浜)
    • Year and Date
      2014-04-28 – 2014-05-03
    • Related Report
      2014 Research-status Report
    • Invited

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Published: 2014-04-04   Modified: 2017-05-10  

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