• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Formation, structure, and reactivity of Grignard reagent in gas-phase

Research Project

Project/Area Number 26620015
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical chemistry
Research InstitutionUniversity of Hyogo

Principal Investigator

Honma Kenji  兵庫県立大学, 物質理学研究科, 教授 (30150288)

Co-Investigator(Kenkyū-buntansha) 松本 剛昭  兵庫県立大学, 物質理学研究科, 助教 (30360051)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsグリニャール試薬 / 金属含有クラスター / グリニャー試薬
Outline of Final Research Achievements

The Grignard reaction is one of important reactions for organic synthesis. In this research project, we planned to generate a gas-phase "Grignard reagent" by co-expansion of the Mg atom and organic compounds, CH3I and diethylether(DEE), through a supersonic nozzle. Mixed clusters formed were ionized by a vacuum ultraviolet(VUV) laser and analyzed by a TOF mass spectrometer.
Various conditions were surveyed and long sequences of mixed clusters of CH3I and DEE, however no mixed clusters containing Mg atoms. One limitation of our experiment is the sensitivity for metal atoms. The absolute concentaration of the Mg atoms formed by the laser vaporization may be too low for the VUV-single photon ionization.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (11 results)

All 2017 2016 2015 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 2 results) Presentation (7 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results) Remarks (2 results)

  • [Journal Article] Reaction dynamics of Al+CO2->AlO+CO studied by a crossed-beam velocity map imaging technique.2017

    • Author(s)
      Kenji Honma and Daiki Hirata
    • Journal Title

      The Journal of Chemical Physics

      Volume: 147 Issue: 1 Pages: 013903-013903

    • DOI

      10.1063/1.4974943

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Excited state reaction dynamics of Ti(a5FJ)+O2->TiO(A,B,C)+O studied by a crossed-beam velocity map imaging technique.2015

    • Author(s)
      Kenji Honma and Yuhki Tanaka
    • Journal Title

      The Journal of Chemical Physics

      Volume: 142

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Dynamics of oxidation reactions of Al atom studied by a crossed-beam time-sliced velocity map imaging technique2016

    • Author(s)
      Kenji Honma
    • Organizer
      Stereodynamics 2016
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2016-11-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 二次元相関赤外分光によるアセチレン巨大クラスターの構造異性体とその温度依存性の研究2015

    • Author(s)
      松本剛昭、吉浦竜斗、本間健二
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] RFイオントラップに単離されたイオンの分光観測2015

    • Author(s)
      本間健二
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Laser-induced fluorescence study of isolated ions in a RF ion-trap.2015

    • Author(s)
      Kenji Honma
    • Organizer
      26th International Symposium on Molecular Beams
    • Place of Presentation
      Parador Hotel(Segovia, Spain)
    • Year and Date
      2015-06-28
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Excited state reaction dynamics of Ti(a5FJ)+O2->TiO(B,C)+O studied by a crossed-beam velocity mapping imaging technique.2015

    • Author(s)
      TANAKA Yuki, HONMA Kenji
    • Organizer
      31st Symposium on Chemical Kinetics and Dynamics
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2015-06-03
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Spectroscopy of isolated ions in a RF ion-trap2015

    • Author(s)
      MIZUTANI Shogo, HONMA Kenji
    • Organizer
      31st Symposium on Chemical Kinetics and Dynamics
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2015-06-03
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] The observation of photoelectrons emitted from the Rydberg oxygen.2015

    • Author(s)
      K. Myojin, T. Gejo, M. Suenaga, A. Shibuta, M. Oura, K. Honma
    • Organizer
      31st Symposium on Chemical Kinetics and Dynamics
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2015-06-03
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 物質反応論I分野ホームページ

    • URL

      http://www.sci.u-hyogo.ac.jp/material/reaction1/index-j.html

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
  • [Remarks] 兵庫県立大学大学院物質理学研究科ホームページ

    • URL

      http://www.sci.u-hyogo.ac.jp/edu/kenkyu/base14.html

    • Related Report
      2015 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi