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New non-linear Raman spectroscopy with nanosecond chirped pulses

Research Project

Project/Area Number 26620020
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

Ohshima Yasuhiro  東京工業大学, 理工学研究科, 教授 (60213708)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords分子分光 / CARS / コヒーレント分布移動 / 量子状態制御 / チャープパルス / 光パラメトリック増幅
Outline of Final Research Achievements

This research project aims to realize highly advanced coherent anti-Stokes Raman scattering spectroscopy with capability of quantum-state selection by implementing coherent control methodology, such as chirped pulse adiabatic passage. In this project, we have succeeded in up-grading the frequency-modulated coherent nanosecond pulsed light source that has been developed in our research group, to achieve higher stability and controllability. We have also conducted theoretical consideration on the application of this novel pulsed light source to the complete population transfer to highly lying quantum state via rudder-climbing Raman excitation by multiple chirped pulses and quantum-state specified enantio-selection via combined use of microwave radiation and chirped pulses.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (30 results)

All 2016 2015 2014 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (23 results) (of which Int'l Joint Research: 9 results,  Invited: 9 results) Remarks (4 results)

  • [Journal Article] sotope-selective ionization utilizing field-free alignment of isotopologues with a train of femtosecond laser pulses2015

    • Author(s)
      H. Akagi, T. Kasajima, T. Kumada, R. Itakura, A. Yokoyama, H. Hasegawa, and Y. Ohshima
    • Journal Title

      Physical Review A

      Volume: 91 Issue: 6 Pages: 063416-063416

    • DOI

      10.1103/physreva.91.063416

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Quantum unidirectional rotation directly imaged with molecules2015

    • Author(s)
      K. Mizuse, K. Kitano, H. Hasegawa, and Y. Ohshima
    • Journal Title

      Science Advances

      Volume: 1 Issue: 6

    • DOI

      10.1126/sciadv.1400185

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Spectroscopic study on deuterated benzenes. II. High-resolution laser spectroscopy and rotational structure in the S1 state2015

    • Author(s)
      S. Kunishige, T. Katori, M. Baba, M. Hayashi, H. Hasegawa, and Y. Ohshima
    • Journal Title

      The Journal of Chemical Physics

      Volume: 143 Issue: 24 Pages: 244303-244303

    • DOI

      10.1063/1.4937950

    • NAID

      120005715316

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] High-resolution spatiotemporal imaging of molecular rotational wave packets2016

    • Author(s)
      K. Mizuse and Y. Ohshima
    • Organizer
      Computational Chemistry (CC) Symposium-The main symposium of ICCMSE
    • Place of Presentation
      Metropolitan Hotel, Athens, Greece
    • Year and Date
      2016-03-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frequency- and time-domain investigation on intermolecular vibrations of molecular clusters2015

    • Author(s)
      Y. Ohshima
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      Waikiki Convention Center, Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Direct and detailed characterization of unidirectional molecular rotation using a newly developed ion imaging apparatus2015

    • Author(s)
      K. Mizuse and Y. Ohshima
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      Waikiki Convention Center, Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Coherent nonlinear optical manipulation of molecular vibration and rotation2015

    • Author(s)
      Y. Ohshima
    • Organizer
      5th Asian Spectroscopy Conference
    • Place of Presentation
      Univ. Sydney, Sydney, Australia
    • Year and Date
      2015-09-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 気相イオンの極低温冷却法の開発と気相NMR分光法への応用2015

    • Author(s)
      冨宅喜代一、大島康裕
    • Organizer
      第9回 分子科学討論会
    • Place of Presentation
      東京工業大学、東京都目黒区
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] フェムト秒パルス列による分子整列を利用したN2同位体選択的イオン化2015

    • Author(s)
      赤木浩、笠嶋辰也、熊田高之、板倉隆二、横山淳、長谷川宗良、大島康裕
    • Organizer
      第9回 分子科学討論会
    • Place of Presentation
      東京工業大学、東京都目黒区
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 分子回転波束ダイナミクスのマルチパルス制御と実時間イメージング2015

    • Author(s)
      藤本路夢、水瀬賢太、今城尚志、大島康裕
    • Organizer
      第9回 分子科学討論会
    • Place of Presentation
      東京工業大学、東京都目黒区
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Taking a movie of rotating free radicals2015

    • Author(s)
      K. Mizuse and Y. Ohshima
    • Organizer
      The 33nd International symposium on free radicals
    • Place of Presentation
      Olympic Valley, California, USA
    • Year and Date
      2015-08-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Control and real-time imaging of molecular rotational wave-packet dynamics2015

    • Author(s)
      K. Mizuse and Y. Ohshima
    • Organizer
      Symposium on Advanced Molecular Spectroscopy
    • Place of Presentation
      Univ. Tokyo, Meguro-ku, Tokyo, Japan
    • Year and Date
      2015-07-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fourier-transform microwave spectroscopy of the Rg-NaCl (Rg = Ne, Ar, and Kr) complexes2015

    • Author(s)
      A. Mizoguchi, Y. Ohshima, and Y. Endo
    • Organizer
      Symposium on Advanced Molecular Spectroscopy
    • Place of Presentation
      Univ. Tokyo, Meguro-ku, Tokyo, Japan
    • Year and Date
      2015-07-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-resolution excitation spectra of benzene-containing van deer Waals complexes2015

    • Author(s)
      M. Hayashi, S. Miyake, and Y. Ohshima
    • Organizer
      Symposium on Advanced Molecular Spectroscopy
    • Place of Presentation
      Univ. Tokyo, Meguro-ku, Tokyo, Japan
    • Year and Date
      2015-07-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Microwave and high-resolution laser spectroscopy of deuterated benzenes2015

    • Author(s)
      S. Kunishige, M. Baba, Y. Ohshima, M. Nakajima, and Y. Endo
    • Organizer
      Symposium on Advanced Molecular Spectroscopy
    • Place of Presentation
      Univ. Tokyo, Meguro-ku, Tokyo, Japan
    • Year and Date
      2015-07-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 1Σおよび2Π分子における回転波束ダイナミクスの直接イメージング2015

    • Author(s)
      水瀬賢太、大島康裕
    • Organizer
      日本分光学会年次講演会
    • Place of Presentation
      東京工業大学、東京都目黒区
    • Year and Date
      2015-06-01
    • Related Report
      2015 Annual Research Report
  • [Presentation] High-resolution laser spectroscopy of van deer Waals complexes to probe intermolecular interaction2015

    • Author(s)
      Y. Ohshima
    • Organizer
      2nd Symposium on Weak Molecular Interactions
    • Place of Presentation
      Gakushuin University, Tokyo, Japan
    • Year and Date
      2015-03-05 – 2015-03-06
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] レーザー光で分子の運動を操作する2015

    • Author(s)
      大島康裕
    • Organizer
      北里大学平成26年度第10回理学部セミナー
    • Place of Presentation
      北里大学、神奈川県相模原市
    • Year and Date
      2015-02-20
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] キラル分子に関する気相分光の新展開2015

    • Author(s)
      大島康裕
    • Organizer
      日本分光学会中国四国支部平成26年度年次講演会「分光学とキラル~その現状と未来~」
    • Place of Presentation
      広島大学、広島県東広島市
    • Year and Date
      2015-01-08
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Taking a movie of rotating molecules2014

    • Author(s)
      Y. Ohshima
    • Organizer
      International Workshop on “Coherence and Control in the Quantum World: Current and Future Trends”
    • Place of Presentation
      Weizmann Institute of Science, Rehovot, Israel
    • Year and Date
      2014-12-15 – 2014-12-18
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 分子運動を光によって操作する2014

    • Author(s)
      大島康裕
    • Organizer
      東京工業大学化学科セミナー
    • Place of Presentation
      東京工業大学、東京都目黒区
    • Year and Date
      2014-12-03
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Coherent nonlinear optical manipulation of molecular vibration and rotation2014

    • Author(s)
      Y. Ohshima
    • Organizer
      Indo-Japan Workshop on “Frontiers in Molecular Spectroscopy: Fundamentals and Applications to Material and Biology”
    • Place of Presentation
      Todaiji Cultural Center, Nara, Japan
    • Year and Date
      2014-11-26 – 2014-11-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Sub-Doppler electronic spectrum of the benzene-D2 complex2014

    • Author(s)
      M. Hayashi, Y. Ohshima
    • Organizer
      The 69th International Symposium on Molecular Spectroscopy
    • Place of Presentation
      University of Illinois, Champaign-Urbana, USA
    • Year and Date
      2014-06-16 – 2014-06-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Improvement in selectivity of isotope-selective ionization utilizing molecular alignment and angular dependent ionization2014

    • Author(s)
      H. Akagi, T. Kasajima, T. Kumada, R. Itakura, A. Yokoyama, H. Hasegawa, Y. Ohshima
    • Organizer
      第30回 化学反応討論会
    • Place of Presentation
      イグーレ姫路、姫路市
    • Year and Date
      2014-06-04 – 2014-06-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Unidirectional molecular rotation dynamics probed with a newly developed ion imaging apparatus2014

    • Author(s)
      K. Mizuse, Y. Ohshima
    • Organizer
      第30回 化学反応討論会
    • Place of Presentation
      イグーレ姫路、姫路市
    • Year and Date
      2014-06-03 – 2014-06-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Coherent nonlinearControl and real-time imaging of unidirectional molecular rotation2014

    • Author(s)
      水瀬賢太、大島康裕
    • Organizer
      日本分光学会年次講演会
    • Place of Presentation
      理化学研究所、和光市
    • Year and Date
      2014-05-26 – 2014-05-28
    • Related Report
      2014 Research-status Report
  • [Remarks] 東京工業大学理学院化学系 大島研究室

    • URL

      http://www.chemistry.titech.ac.jp/~ohshima/index.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] Ohshima Group, Tokyo Institute of Technology

    • URL

      http://www.chemistry.titech.ac.jp/~ohshima/index_e.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 東京工業大学 理工学研究科 化学専攻 大島研究室

    • URL

      http://www.chemistry.titech.ac.jp/~ohshima/index.html

    • Related Report
      2014 Research-status Report
  • [Remarks] Ohshima Group, Tokyo Insitute of Technology

    • URL

      http://www.chemistry.titech.ac.jp/~ohshima/index_e.html

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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