| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2014: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
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| Outline of Final Research Achievements |
Hexasilabenzene is the silicon analog of benzene. In contrast with benzene, the energy of hexasilabenzene is by 36.0 kcal mol-1 higher than the most stable valence isomer, and therefore, hexasilabenzene has not yet been synthesized. According to theoretical calculations, hexasilabenzene with three 1,4-cyclohexasilanylene groups is estimated to be the most stable among its valence isomers. In this research, synthesis of hexasilabenzene with 1,4-cyclohexasilanylene groups was studied.
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