Synthesis of Hexasilabenzene with 1,4-Cyclohexasilanylene Groups
Project/Area Number |
26620023
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Organic chemistry
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Research Institution | Gunma University |
Principal Investigator |
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Project Period (FY) |
2014-04-01 – 2016-03-31
|
Project Status |
Completed (Fiscal Year 2015)
|
Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2014: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
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Keywords | ヘキサシラベンゼン / 有機ケイ素クラスター / オリゴシラン |
Outline of Final Research Achievements |
Hexasilabenzene is the silicon analog of benzene. In contrast with benzene, the energy of hexasilabenzene is by 36.0 kcal mol-1 higher than the most stable valence isomer, and therefore, hexasilabenzene has not yet been synthesized. According to theoretical calculations, hexasilabenzene with three 1,4-cyclohexasilanylene groups is estimated to be the most stable among its valence isomers. In this research, synthesis of hexasilabenzene with 1,4-cyclohexasilanylene groups was studied.
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Report
(3 results)
Research Products
(13 results)