Synthesis and Utilization of Heteobimetallic Complexes Utilizing Organoelement-Hybrid Multidentate Ligands
| Project/Area Number |
26620024
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
Takaya Jun 東京工業大学, 理学院, 准教授 (60401535)
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| Project Period (FY) |
2014-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
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| Keywords | 合成化学 |
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| Outline of Final Research Achievements |
We have developed efficient synthesis and their catalysis of a series of palladium complexes having a group 13 metalloligand (Al, Ga, In) utilizing 6,6”-bis(phosphino)terpyridine as a new scaffold for Pd-E bonds (E = Al, Ga, In). Systematic investigation revealed unique characteristics of the Al-metalloligand in both structure and reactivity, which exhibited the highest catalytic activity for hydrosilylation of CO2 ever reported (TOF = 19300-1). This study demonstrated fine tuning of catalyst activity by the rationally designed metalloligand is a promising approach for new catalyst development in synthetic chemistry.
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Report
(5 results)
Research Products
(32 results)
