| Project/Area Number |
26620029
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
Terao Jun 京都大学, 工学(系)研究科(研究院), 准教授 (00322173)
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | シクロデキストリン / 分子ワイヤ / 導電性高分子 / メタロワイヤ / ホストゲスト / 分子配線 / 分子エレクトロニクス / ナノデバイス / バイメタロポリマー / 燐光発光 / 量子収率 / 電荷移動度 / ポルフィリン / 積層型ポリマー / 分子チューブ / 機能性共役分子 / ロタキサン |
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| Outline of Final Research Achievements |
Electrically conductive conjugated molecular wires are promising wiring elements in the field of molecular electronics; however, they suffer from major drawbacks such as low solubility, caused by interactions, and poor one-dimensional conductivity, caused by cross-talk between conjugated chains, as well as low rigidity and linearity. For these reasons, it is interesting to study insulated molecular wires, in which these conjugated polymers are covered with a protective sheath; this sheath limits interaction as well as leads to the enhancement of organic solubility and conductivity as compared with those of the corresponding uninsulated conjugated polymers.
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