| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Outline of Final Research Achievements |
Based on our concept for isolation of reaction intermediate by stabilization with bridged structure, we have succeeded in isolation and structural determination of hypervalent iodonium species, and as an extension of the strategy new synthesis has been developed by utilizing new information of the intermediates in reactivity. In addition, as an extended research theme, we have discovered a new bond-forming reaction by performing generation and use of very unstable iodonium intermediate having sp3 carbon-hypervalent bonds not utilized in synthesis before.
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