Realization of unprecedented carbon-carbon bond formation based on the stabilization strategy of iodonium species
| Project/Area Number |
26620036
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Ritsumeikan University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
|
| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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|---|
| Keywords | 新規反応開発 / 有機化学 |
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| Outline of Final Research Achievements |
Based on our concept for isolation of reaction intermediate by stabilization with bridged structure, we have succeeded in isolation and structural determination of hypervalent iodonium species, and as an extension of the strategy new synthesis has been developed by utilizing new information of the intermediates in reactivity. In addition, as an extended research theme, we have discovered a new bond-forming reaction by performing generation and use of very unstable iodonium intermediate having sp3 carbon-hypervalent bonds not utilized in synthesis before.
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Report
(3 results)
Research Products
(63 results)
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[Book] 化学2014
Author(s)
土肥寿文
Total Pages
2
Publisher
化学同人
Related Report
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