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Super-resolution patterning by using higher-order multiphoton reactions

Research Project

Project/Area Number 26620062
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionOsaka University

Principal Investigator

Miyasaka Hiroshi  大阪大学, 基礎工学研究科, 教授 (40182000)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords高次多光子反応 / フェムト秒レーザー顕微鏡 / フォトクロミック反応 / 超解像 / レーザー光化学 / 反応スイッチング
Outline of Final Research Achievements

In this research project, we constructed a laser confocal-microscope allowing photoexcitation of a small area in samples at sub-100 fs pulse duration in the near infrared region. By using the microscope, we selectively induced the decoloration (two-photon process) and coloration (three-photon process) of diarylethene derivatives only by changing the intensity of incident light pulse. We also conducted numerical calculations, confirming that the reactions are safely ascribed to the two-photon and three-photon absorptions. Through these investigations we successfully demonstrated the universality of one-color multiphoton reversible switching of photochromic reactions.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (30 results)

All 2016 2015 2014 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 4 results) Presentation (16 results) (of which Int'l Joint Research: 6 results,  Invited: 5 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Photochromism of diarylethene derivatives having benzophosphole and benzothiophene groups2016

    • Author(s)
      Tomohiro Ichikawa, Masakazu Morimoto, Hikaru Sotome, Syoji Ito, Hiroshi Miyasaka, Masahiro Irie
    • Journal Title

      Dyes and Pigments

      Volume: 126 Pages: 186-193

    • DOI

      10.1016/j.dyepig.2015.11.023

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Solvent Polarity Dependence of Photochromic Reactions of a Diarylethene Derivative as Revealed by Steady-State and Transient Spectroscopies.2016

    • Author(s)
      Yukihide Ishibashi, Toshiyuki Umesato, Mika Fujiwara, Kanako Une,Yusuke Yoneda, Hikaru Sotome, Tetsuro Katayama, Seiya Kobatake, Tsuyoshi Asahi, Masahiro Irie and Hiroshi Miyasaka
    • Journal Title

      J. Phys. Chem. C

      Volume: 120 Issue: 2 Pages: 1170-1177

    • DOI

      10.1021/acs.jpcc.5b08504

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Stepwise Two-photon Induced Fast Photoswitching via Electron Transfer in Higher Excited States of Photochromic Imidazole Dimer2016

    • Author(s)
      Yoichi Kobayashi, Tetsuro Katayama, Takuya Yamane, Kenji Setoura, Syoji Ito, Hiroshi Miyasaka, and Jiro Abe
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 18 Pages: 5930-5938

    • DOI

      10.1021/jacs.6b01470

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Femtosecond coherent wavepacket motion in an ultrafast electrontransfer system composed of naphthacene derivative in an electrondonating solvent2015

    • Author(s)
      Yusuke Yoneda, Shohei Nambu, Eisuke Takeuchi, Yutaka Nagasawa, Hiroshi Miyasaka
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: 313 Pages: 79-86

    • DOI

      10.1016/j.jphotochem.2015.05.014

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fluorescent photochromic diarylethene that turns on with visible light2015

    • Author(s)
      Takaki Sumi, Tomohiro Kaburagi, Masakazu Morimoto, Kanako Une, Hikaru Sotome, Syoji Ito, Hiroshi Miyasaka, Masahiro Irie
    • Journal Title

      Organic Letters

      Volume: 17 Issue: 19 Pages: 4802-4805

    • DOI

      10.1021/acs.orglett.5b02361

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Properties and Evolution of Emission in Molecular Aggregates of a Perylene Ammonium Derivative in Polymer Matrices2015

    • Author(s)
      Fuyuki Ito, Hirofumi Sato, Yuri Ugachi, Narumi Oka, Syoji Ito and Hiroshi Miyasaka
    • Journal Title

      Photochem. Photobiol. Sci.

      Volume: 14 Issue: 10 Pages: 1896-1902

    • DOI

      10.1039/c5pp00196j

    • NAID

      120007101498

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Cooperative conformational change and excitation migration of biphenyl-PMO amorphous film, as revealed by femtosecond time-resolved spectroscopy2014

    • Author(s)
      Y. Ishibashi, T. Katayama, H. Saito, K. Yamanaka, Y. Goto, T. Tani, T. Okada, S. Inagaki, H. Miyasaka
    • Journal Title

      J. Phys. Chem. C

      Volume: (in press) Issue: 18 Pages: 9419-9428

    • DOI

      10.1021/jp502734u

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fluorescence Behavior of Single Guest Molecules in Nonpolar Oil Droplets Covered with Stabilizing Surfactants2014

    • Author(s)
      Syoji Ito, Atsushi Iida, Masakazu Yasuda, Hiroshi Miyasaka
    • Journal Title

      J. Phys. Chem. C.

      Volume: 118 Issue: 19 Pages: 10348-10357

    • DOI

      10.1021/jp4112266

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Inhomogeneous Deactivation Process with UV Excitation in Submicron Grains of Lead Iodide Perovskite-based Solar Cell as Revealed by Femtosecond Transient Absorption Microscopy2014

    • Author(s)
      Tetsuro Katayama, Akira Jinno, Eisuke Takeuchi, Syoji Ito, Masaru Endo, Atsushi Wakamiya, Yasujiro Murata, Yuhei Ogomi, Shuzi Hayase, Hiroshi Miyasaka
    • Journal Title

      Chem.Lett.

      Volume: 43 Issue: 10 Pages: 1656-1658

    • DOI

      10.1246/cl.140551

    • NAID

      130004693824

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Picosecond-to-Nanosecond Dynamics of Plasmonic Nanobubbles from Pump-Probe Spectral Measurements of Aqueous Colloidal Gold Nanoparticles2014

    • Author(s)
      Tetsuro Katayama, Kenji Setoura, Daniel Werner, Hiroshi Miyasaka, Shuichi Hashimoto
    • Journal Title

      Langmuir

      Volume: 30 Issue: 31 Pages: 9504-9513

    • DOI

      10.1021/la500663x

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 高次複合光応答分子システムの開拓2016

    • Author(s)
      宮坂 博
    • Organizer
      日本化学会 第96春季年会 (2016)
    • Place of Presentation
      同志社大学 京田辺キャンパス(京田辺市・京都府)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Elucidation and control of photochromic reactions by pulsed laser excitation2015

    • Author(s)
      Hiroshi Miyasaka
    • Organizer
      THE INTERNATIONAL CHEMICAL CONGRESS OF PACIFIC BASIN SOCIETIES 2015
    • Place of Presentation
      Honolulu, Hawaii (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Anomalous diffusion of guest dyes in amorphous polymer solids as revealed by single molecule tracking2015

    • Author(s)
      Hiroshi Miyasaka, Yuhei Taga, Kengo Hiratsuka, Yuhei Arai, Syoji Ito
    • Organizer
      THE INTERNATIONAL CHEMICAL CONGRESS OF PACIFIC BASIN SOCIETIES 2015
    • Place of Presentation
      Honolulu, Hawaii (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Localization of excited states within a super-resolved volume by using photochromic reactions2015

    • Author(s)
      IKEGAMI, Takahiro; ITO, Syoji; MIYASAKA, Hiroshi; UNO, Kakishi; TAKAGI, Yuta; MORIMOTO, Masakazu; IRIE, Masahiro
    • Organizer
      3rd KANSAI Nanoscience and Nanotechnology International Symposium
    • Place of Presentation
      Suita, Osaka (Japan)
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Temperature and excitation wavelength dependencies of photoinduced cycloreversion ofdiarylethene derivatives2015

    • Author(s)
      Kanako Une, Hikaru Sotome, Hiroshi Miyasaka, Seiya Kobatake, Masahiro Irie
    • Organizer
      3rd KANSAI Nanoscience and Nanotechnology International Symposium
    • Place of Presentation
      Suita, Osaka (Japan)
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 光異性化反応と2波長励起による励起状態の超解像局在化2015

    • Author(s)
      伊都 将司・池上 雄大・宮坂 博・宇野 何岸・高木 祐太・森本 正和・入江 正浩
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学 大岡山キャンパス(東京都)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 光異性化反応を用いた空間選択的な励起状態生成2015

    • Author(s)
      伊都 将司・池上 雄大・宮坂 博・宇野 何岸・高木 祐太・森本 正和・入江 正浩
    • Organizer
      2015年光化学討論会
    • Place of Presentation
      大阪市立大学杉本キャンパス(大阪府・大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 1光子による1分子応答を超える光化学をめざして2015

    • Author(s)
      宮坂 博
    • Organizer
      2015年光化学討論会
    • Place of Presentation
      大阪市立大学杉本キャンパス(大阪府・大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] ジアリールエテンの光異性化反応を用いた励起状態の超解像局在化2015

    • Author(s)
      池上 雄大・伊都 将司・宮坂 博・宇野 何岸・高木 祐太・森本 正和・入江 正浩
    • Organizer
      2015年光化学討論会
    • Place of Presentation
      大阪市立大学杉本キャンパス(大阪府・大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Control of Photochromic Reactions by Pulsed Laser Excitation2015

    • Author(s)
      Hiroshi Miyasaka
    • Organizer
      27th International Conference on Photochemistry (ICP 2015)
    • Place of Presentation
      ICC JEJU, Jeju Island (Korea)
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Excitation Wavelength Dependence of Photochromic Reactions of Diarylethene Derivatives2015

    • Author(s)
      Kanako Une (Osaka University), Tetsuro Katayama, Hiroshi Miyasaka, Seiya Kobatake, and Masahiro Irie
    • Organizer
      27th International Conference on Photochemistry (ICP 2015)
    • Place of Presentation
      ICC JEJU, Jeju Island (Korea)
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 蛍光スイッチングジアリールエテン誘導体を用いた超解像蛍光スポット作成2015

    • Author(s)
      池上雄大・伊都将司・宮坂博・宇野何岸・高木祐太・森本正和・入江正浩
    • Organizer
      日本化学会 第95春季年会(2015)
    • Place of Presentation
      日本大学 理工学部船橋キャンパス / 薬学部
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Single-molecule photoswitching of fluorescence of diarylethene derivatives2014

    • Author(s)
      T. Ikegami, S. Ito, H, Miyasaka, K. Uno, Y. Takagi, M. Morimoto, M. Irie
    • Organizer
      2nd KANSAI Nanoscience and Nanotechnology International Symposium
    • Place of Presentation
      The Congres Convention Center in the center of City of Osaka, Japan
    • Year and Date
      2014-12-10 – 2014-12-11
    • Related Report
      2014 Research-status Report
  • [Presentation] Fluorescence Switching Properties of Diarylethene Derivatives at the Single-Molecule Level2014

    • Author(s)
      Takahiro Ikegami, Syoji Ito, Hiroshi Miyasaka, Kakishi Uno, Yuta Takagi, Masakazu Morimoto, Masahiro Irie
    • Organizer
      8th Asian Photochemistry Conference 2014 (2014APC)
    • Place of Presentation
      Thiruvananthapuram, Kerala, India
    • Year and Date
      2014-11-09 – 2014-11-13
    • Related Report
      2014 Research-status Report
  • [Presentation] ジアリールエテン誘導体を用いた超解像蛍光スポット形成2014

    • Author(s)
      池上 雄大・伊都 将司・宮坂 博・宇野 何岸・高木 祐太・森本 正和・入江 正浩
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学 札幌キャンパス
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Research-status Report
  • [Presentation] SINGLE-MOLECULE FLUORESCENCE SWITCHING OF DIARYLETHENE DERIVATIVES BY USING ULTRAVIOLET AND VISIBLE LASERS2014

    • Author(s)
      Takahiro Ikegami, Syoji Ito, Hiroshi Miyasaka, Kakishi Uno, Yuta Takagi, Masakazu Morimoto, Masahiro Irie
    • Organizer
      The XXVth IUPAC Symposium on Photochemistry
    • Place of Presentation
      Palais des Congrès in Bordeaux, France
    • Year and Date
      2014-07-13 – 2014-07-18
    • Related Report
      2014 Research-status Report
  • [Book] 発光の辞典2015

    • Author(s)
      伊都将司、宮坂 博
    • Total Pages
      771
    • Publisher
      朝倉書店
    • Related Report
      2015 Annual Research Report
  • [Book] 大阪大学光科学センター 編 光科学の世界 第4章 4.22014

    • Author(s)
      伊都将司, 宮坂 博
    • Total Pages
      222
    • Publisher
      朝倉書店
    • Related Report
      2014 Research-status Report
  • [Remarks] 大阪大学大学院基礎工学研究科 宮坂研究室

    • URL

      http://www.laser.chem.es.osaka-u.ac.jp

    • Related Report
      2015 Annual Research Report
  • [Remarks]

    • URL

      http://www.laser.chem.es.osaka-u.ac.jp

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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