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Controls of the Structure and Status of Supramolecular Nanofibers with Sound and Light

Research Project

Project/Area Number 26620066
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionKobe University

Principal Investigator

Tsuda Akihiko  神戸大学, 理学(系)研究科(研究院), 准教授 (20359657)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords超分子 / 光化学 / フォトクロミズム / 音化学 / 分子集合体 / 有機化学
Outline of Final Research Achievements

In this study, we have demonstrated syntheses of intelligent nanofibers capable of switching their properties in response to the two physical stimuli, sound and light, with an objective to develop nanoscale molecular machines. We have newly synthesized sound/photo-responsive supramolecular nanofibers composed of an azobenzene derivative (AZ) and a dithienylethene derivative (DTE). These nanofibers exhibited sound-induced alignments in the solutions. We found that AZ and DTE nanofibers exhibit ON-OFF switching and wavelength switching, respectively, of the sound induced linear dichroism with UV and visible light.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (13 results)

All 2015 2014 Other

All Journal Article (6 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 1 results,  Open Access: 1 results) Presentation (6 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] Photochromism in Sound-induced Alignment of a Diarylethene Supramolecular Nanofiber2015

    • Author(s)
      Yasuhisa Hotta, Satomi Fukushima, Jin Motoyanagi, and Akihiko Tsuda
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 14 Pages: 2790-2793

    • DOI

      10.1039/c4cc09702e

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] 渦を巻き,音でならぶ,超分子ナノファイバー2015

    • Author(s)
      津田 明彦
    • Journal Title

      現代化学

      Volume: 536 Pages: 41-46

    • NAID

      40020613393

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Chiroptical Sensing of Oligonucleotides with a Cyclic Octapyrrole2015

    • Author(s)
      Machiko Ie, Jun-ichiro Setsune, Kazuo Eda, and Akihiko Tsuda
    • Journal Title

      Organic Chemistry Frontiers

      Volume: 2 Issue: 1 Pages: 29-33

    • DOI

      10.1039/c4qo00268g

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Physical Operation of Hydrodynamic Orientation of an Azobenzene Supramolecular Assembly with Light and Sound2014

    • Author(s)
      Yasuhisa Hotta, Jin Motoyanagi, Shunsuke Suiko, Hiroshi Onishi, Daisuke Iozaki, Ryuichi Arakawa, Akihiko Tsuda
    • Journal Title

      ChemComm

      Volume: 50 Issue: 42 Pages: 5615-5618

    • DOI

      10.1039/c4cc02078b

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Mechanistic Study on the Facilitation of Enzymatic Hydrolysis by α-Glucosidase in the Presence of Betaine-Type Metabolite Analogs2014

    • Author(s)
      Yuichi Nakagawa, Shiro Sehata, Satoshi Fujii, Hiroaki Yamamoto, Akihiko Tsuda, and Kazuya Koumoto
    • Journal Title

      Tetrahedron

      Volume: 70 Issue: 35 Pages: 5895-5903

    • DOI

      10.1016/j.tet.2014.06.028

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Control of Reaction Pathways in the Photochemical Reaction of a Quinone with Tetramethylethylene by Metal Binding2014

    • Author(s)
      Hiroaki Yamamoto, Kei Ohkubo, Seiji Akimoto, Shunichi Fukuzumi, and Akihiko Tsuda
    • Journal Title

      Organic & Biomolecular Chemistry

      Volume: 12 Issue: 36 Pages: 7004-7017

    • DOI

      10.1039/c4ob00659c

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Supramolecular Photochemistry Faraday Discussion2015

    • Author(s)
      Akihiko Tsuda, Yasuhisa Hotta, Jin Motoyanagi
    • Organizer
      Photocontroles of Acoustic Alignments of Supramolecular Nanofibers
    • Place of Presentation
      Cambridge, UK
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 音や光に応答して状態や性質を変化させる超分子集合体2015

    • Author(s)
      津田 明彦
    • Organizer
      大阪市立大学理学研究科 談話会
    • Place of Presentation
      大阪市立大学理学研究科(大阪府・大阪市)
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 剛直なポルフィリンポリマー超分子二重鎖2015

    • Author(s)
      古瀬 光平・大須賀 篤宏・津田 明彦
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 置換基修飾によるペリレンビスイミド超分子ナノファイバーの音響配向制御2015

    • Author(s)
      堀田 泰久・津田 明彦
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 光と音による超分子ナノファイバーの動的配向制御2014

    • Author(s)
      堀田 泰久・本柳 仁・津田 明彦
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学札幌キャンパス
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Research-status Report
  • [Presentation] 剛直なポルフィリンポリマー二重鎖の創製2014

    • Author(s)
      古瀬 光平・大須賀 篤弘・津田 明彦
    • Organizer
      第25回基礎有機化学討論会(2014)
    • Place of Presentation
      東北大学川内北キャンパス
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Research-status Report
  • [Remarks] 津田研究室ホームページ

    • URL

      http://www2.kobe-u.ac.jp/~akihiko/index/html

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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