Electrochromic Reaction System with Extraordinarly Current Efficiency over 10000%
| Project/Area Number |
26620067
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Nara Institute of Science and Technology |
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Principal Investigator |
KAWAI TSUYOSHI 奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (40221197)
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | エレクトロクロミズム / 電流効率 / 電気化学反応 / 酸化還元電位 / 異性化 / 電気化学効率 / 連鎖反応 / 酸化反応 |
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| Outline of Final Research Achievements |
Novel molecular science was conducted for achieving electrochemical Coulombic efficiency higher than 10000%. Target molecules showed electrochemical oxidative cycloreversion isomerization with ideal zero-order kinetics independent of concentration of substrate. Chemical modification supported systematic stabilization of O+ component and rapid fading isomerization was observed without electrochemical current, indicating Coulombic efficiency higher than 10000%.
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Report
(3 results)
Research Products
(3 results)
