| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
In this research, two types of C-H bond functionalization methodologies were explored.
The first one was the exploration of a new catalyst bearing a substrate capturing site for regioselective C-H bond activation. And it was found that newly-designed iridium-phenanthroline complex promoted meta-selective C-H borylation of mono-substituted benzenes, albeit chemical yields were not satisfactory.
The second approach was the utilization of photochemical isomerization of acylsilanes to siloxycarbenes for C-H insertion reaction and stereoselective cyclization of ortho-substituted benzoylsilanes was realized under photoirradiation conditions.
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