| Project/Area Number |
26620147
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Green/Environmental chemistry
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| Research Institution | Kobe University |
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Principal Investigator |
Kita Yuichi 神戸大学, 工学研究科, 特命教授 (20642200)
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| Co-Investigator(Kenkyū-buntansha) |
平野 喜章 神戸大学, 工学研究科, 特命准教授 (30642201)
相方 邦昌 神戸大学, 工学研究科, 学術研究員 (30725007)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
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| Keywords | 水素化 / 水素化分解 / ケミカルルーピング / 鉄 / 水素発生 / バイオマス |
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| Outline of Final Research Achievements |
In recent years, biomass has attracted attention as a sustainable carbon resource in the chemical industry, and conversion to fuels and chemicals by reaction such as hydrogenation is being actively studied. Therefore, in this study, we created a hydrogenation reaction process using water as a hydrogen source, utilizing oxidation / reduction cycle (chemical · looping) of metal / metal oxide. Hydrogenation or hydrogenolysis of biomass-derived substrates such as glucose, methyl laurate, and etc. was evaluated. It was revealed that the hydrogenation reaction proceeds with hydrogen generated by the reaction between water and metallic iron, that iron species exhibits catalytic action and participates in the reaction pathway. It was also confirmed that iron oxide could be regenerated into metallic iron by heat treatment with biomass and used for repeated reaction.
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