| Project/Area Number |
26620148
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Green/Environmental chemistry
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| Research Institution | Tokyo Metropolitan University |
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Principal Investigator |
SHISHIDP Tetsuya 首都大学東京, 都市環境科学研究科, 教授 (80294536)
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | バイオマス / 光触媒 / 選択酸化 / 酸素 / アルコール / アミン / 比表面積 / 流通系 |
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| Outline of Final Research Achievements |
Cross-dehydrogenative coupling of alcohols with amines to imine, imidazole, and quinoxaline over niobium oxide (Nb2O5) photocatalyst under mild conditions via in situ doping mechanism were investigated. The C-N coupling reactions of various alcohols with amines to form secondary imines take place over Nb2O5. The C-O coupling between substituted phenols and alcohols took place over Nb2O5 under visible light irradiation. Various alcohols including unstable functional group can be coupled with substituted phenols to form asymmetric ether under visible light irradiation. The correlation between photocatalytic activity and surface property of Nb2O5 was examined. The amount of surface complex is important factor for photooxidation on Nb2O5. The adsorption behavior of both substrates and products on surface of photocatalyst should be controlled to achieve a high activity.
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