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Development of Growth Technology of N-Benzyl-2-Methyl-4-Nitroaniline (BNA) Single Crystal Fiber For Terahertz Generation Applications

Research Project

Project/Area Number 26620162
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic and hybrid materials
Research InstitutionTohoku University

Principal Investigator

Kamada Kei  東北大学, 未来科学技術共同研究センター, 准教授 (60639649)

Co-Investigator(Kenkyū-buntansha) TAKIDA YUMA  理化学研究所, 光量子工学研究領域, 訪問研究員 (50714820)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords結晶成長 / テラヘルツ / 非線形光学単結晶 / 単結晶成長 / 有機非線形結晶 / マイクロ引き下げ法 / 有機非線形単結晶 / マイクロ引下げ法
Outline of Final Research Achievements

BNA fiber single crystals were grown by the m-PD method. Crucible materials and shape were designed according to wetness between BNA and the crucible materials. Finally BNA fiber single crystal with about 1-2 mm diameter was successfully grown by using the polystyrene crucible. The grown BNA crystal showed single Orthorhombic phase. The grown BNA crystal showed 19.7 arcsec of line width of rocking curve. This value is superior to that of the reported BNA crystals grown by the solution growth (~30 arcsec) and Bridgeman method (~100 arcsec). THz-wave generation from 4 THz up to 14 THz from the m-PD grown BNA fiber was demonstrated. Positivity of high crystallinity BNA single crystal growth by the m-PD method was evidenced by this study.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (4 results)

All 2015 2014

All Presentation (3 results) (of which Int'l Joint Research: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Presentation] Growth Of N-Benzyl-2-Methyl-4-Nitroaniline (BNA) Single Crystal Fiber For Terahertz Generation.2015

    • Author(s)
      Kei Kamada, Yuma Takida, Hiroaki Minamide, Shunsuke Kurosawa, Yuui Yokota, Yuji Ohashi, Akira Yoshikawa
    • Organizer
      20th American Conference on Crystal Growth and Epitaxy (ACCGE-20)
    • Place of Presentation
      Big Sky, (USA)
    • Year and Date
      2015-08-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機非線形BNA単結晶ファイバーのマイクロ引下げ法による作製と 特性評価2014

    • Author(s)
      鎌田圭、瀧田 佑馬、南出 泰亜、黒澤俊介、横田有為、 庄子育宏、Pejchal Jan、大橋 雄二、吉川彰
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道札幌市北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Growth of N-benzyl-2-methyl-4-nitroaniline (BNA) single crystal fibers by micro pulling down method.2014

    • Author(s)
      鎌田圭、瀧田 佑馬、南出 泰亜、黒澤俊介、横田有為、 庄子育宏、Pejchal Jan、大橋 雄二、吉川彰
    • Organizer
      6th International Workshop on Crystal Growth Technology
    • Place of Presentation
      ドイツ国ベルリン市 NOVOTEL Am Tiergarten
    • Year and Date
      2014-06-15 – 2014-06-19
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] BNA結晶、及びその製造方法2014

    • Inventor(s)
      鎌田 圭、吉川 彰、横田 有為、黒澤 俊介
    • Industrial Property Rights Holder
      鎌田 圭、吉川 彰、横田 有為、黒澤 俊介
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-121449
    • Filing Date
      2014-06-12
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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