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Constraction of p-n Heterojunction Baased on the Highly Oriented Stacking of Functional Dyes

Research Project

Project/Area Number 26620169
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic and hybrid materials
Research InstitutionOsaka Prefecture University

Principal Investigator

Maeda Takeshi  大阪府立大学, 工学(系)研究科(研究院), 助教 (90507956)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords機能性色素 / 近赤外光 / 自己組織化 / J会合体 / 有機半導体 / 有機太陽電池 / 分子素子 / 電荷移動 / J会合体 / 分子内電荷移動 / 電界効果トランジスタ
Outline of Final Research Achievements

A novel class of diad molecules that electron donating dyes covalently link with electron accepting dye components was designed and synthesized. The obtained diad molecules spontaneously stacked in response to external stimuli such as solvents and temperature and successfully gave highly ordered alignments of the individual component. Conventional organic photovoltaic devices using the self-assembled diad as photoactive layers exhibited photocurrent. Considering about the result, the diad assembly successfully provide p-n heterojunction which contributes charge separation followed by charge transportation in the device.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (25 results)

All 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 1 results) Presentation (17 results) (of which Int'l Joint Research: 6 results,  Invited: 3 results) Remarks (1 results)

  • [Int'l Joint Research] ヴュルツブルグ大学(ドイツ)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] CSIR-NIIST(インド)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Linear and Tripodal Squaraine Sensitizers with Triphenylamine Donor Components for Dye-sensitized Solar Cells2016

    • Author(s)
      T. V. Nguyen, T. Maeda, H. Nakazumi, S. Yagi
    • Journal Title

      Chem. Lett.

      Volume: 45 Issue: 3 Pages: 291-293

    • DOI

      10.1246/cl.151101

    • NAID

      130005132182

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Near-infrared Squaraine Sensitizers Bearing Benzo[c,d]indolenine as an Acceptor Moiety2015

    • Author(s)
      T. Maeda, S., Nitta, Y. Sano, S. Tanaka, S. Yagi, H. Nakazumi
    • Journal Title

      Dyes Pigm.

      Volume: 122 Pages: 160-167

    • DOI

      10.1016/j.dyepig.2015.06.022

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Squaraine Dyes with BODIPY Skeletons for the Application to Dye-Sensitized Solar Cells2015

    • Author(s)
      前田壮志、垣尾大輔、八木繁幸、中澄博行
    • Journal Title

      Journal of the Japan Society of Colour Material

      Volume: 88 Issue: 7 Pages: 208-217

    • DOI

      10.4011/shikizai.88.208

    • NAID

      130005104045

    • ISSN
      0010-180X, 1883-2199
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Halochromic and hydrochromic squaric acid functionalized perylene bisimide2015

    • Author(s)
      T. Maeda, F. Wuerthner
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 36 Pages: 7661-7664

    • DOI

      10.1039/c5cc01691f

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Molecular Design of Boronic Acid-Functionalized Squarylium Cyanine Dyes for Multiple Discriminant Analysis of Sialic Acid in Biological Samples: Selectivity Toward Monosaccharides Controlled by Different Alkyl Side Chain Lengths2015

    • Author(s)
      Kazuki Ouchi, Christa L. Colyer, Mahmoud Sebaiy, Jin Zhou, Takeshi Maeda, Hiroyuki Nakazumi, Masami Shibukawa, Shing Saito
    • Journal Title

      Analytical Chemistry

      Volume: 87 Issue: 3 Pages: 1933-1940

    • DOI

      10.1021/ac504201b

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Squaraine-based Dyes for Dye-sensitized Solar Cells2016

    • Author(s)
      T. Maeda
    • Organizer
      EMN Meeting on Photovoltaics
    • Place of Presentation
      Eaton Hotel, Hong Kong, China
    • Year and Date
      2016-01-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 近赤外光吸収スクアリリウム色素を用いた低分子系有機薄膜太陽電池2015

    • Author(s)
      前田壮志、田中翔太、藤原秀紀、八木繁幸、中澄博行
    • Organizer
      第46回 中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      三重大学,津,三重県
    • Year and Date
      2015-11-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Squaric Acid Functionalized Perylene Bisimide for Sensing Applications2015

    • Author(s)
      T. Maeda
    • Organizer
      National Conference on Analytical Science and Technology 2015
    • Place of Presentation
      Hotel Tea County,Munnar, Kerala, India
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Interchromophore Arrangement in Branched Squaraine dyes for DSSCs2015

    • Author(s)
      T. Maeda, X. Chen, K. Miyanaga, S. Yagi, H. Nakazumi
    • Organizer
      7th East Asia Symposium on Functional Dyes and Advanced Materials
    • Place of Presentation
      Osaka Prefecture University, Sakai, Osaka, Japan
    • Year and Date
      2015-09-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Near-infrared Absorbing Squaraine Dyes for Donor Materials Used in Organic Photovoltaics2015

    • Author(s)
      S. Tanaka, T. Maeda, S. Kitagawa, S. Yagi, H. Nakazumi
    • Organizer
      7th East Asia Symposium on Functional Dyes and Advanced Materials
    • Place of Presentation
      Osaka Prefecture University, Sakai, Osaka, Japan
    • Year and Date
      2015-09-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Near-infrared Absorbing Squaraine Dyes for Organic Photovoltaics2015

    • Author(s)
      T. Maeda, H. Fujiwara, S. Yagi, H. Nakazumi
    • Organizer
      12th International Symposium on Functional π-Electron Systems
    • Place of Presentation
      University of Washington, Seattle, USA
    • Year and Date
      2015-07-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Halochromic and Hydrochromic Perylene Bisimide Bearing Squaric Acid Residues2015

    • Author(s)
      T. Maeda, F. Wuerthner
    • Organizer
      12th International Symposium on Functional π-Electron Systems
    • Place of Presentation
      University of Washington, Seattle, USA
    • Year and Date
      2015-07-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrochromic Peylene Bisimides2015

    • Author(s)
      T. Maeda, M. Stolte, F. Wuerthner
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日大船橋キャンパス(千葉県・船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 極性官能基を有するU字型スクアリリウム色素の合成と色素増感太 陽電池への展開2015

    • Author(s)
      佐野陽平,本山智博,前田壮志,八木繁幸,中澄博行
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日大船橋キャンパス(千葉県・船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 有機太陽電池のための近赤外吸収スクアリリウム色素2015

    • Author(s)
      前田壮志,北川翔一,八木繁幸,中澄博行
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日大船橋キャンパス(千葉県・船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 有機エレクトロニクスへの応用を指向した新規スクアリリウム系色素2014

    • Author(s)
      前田壮志
    • Organizer
      第45回中部化学関係学支部連合秋季大会
    • Place of Presentation
      中部大学(愛知県・春日井市)
    • Year and Date
      2014-11-29 – 2014-11-30
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 有機薄膜太陽電池への応用を指向した側鎖にスクアリリウム系色素をもつポリマーの合成と特性2014

    • Author(s)
      吉田圭,前田壮志,八木繁幸,中澄博行
    • Organizer
      2014年色材研究発表会
    • Place of Presentation
      名古屋市工業研究所(愛知県・名古屋市)
    • Year and Date
      2014-10-23 – 2014-10-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 拡張π電子系を持つ複素環からなる近赤外吸収非対称スクアリリウム系増感色素2014

    • Author(s)
      新田翔平,前田壮志,八木繁幸,中澄博行
    • Organizer
      2014年色材研究発表会
    • Place of Presentation
      名古屋市工業研究所(愛知県・名古屋市)
    • Year and Date
      2014-10-23 – 2014-10-24
    • Related Report
      2014 Research-status Report
  • [Presentation] NDIを基本骨格に有する新規スクアリリウム系色素の合成及び特性評価2014

    • Author(s)
      石田拓生,周瑾,前田壮志,藤原秀紀,八木繁幸,中澄博行
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区))
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Research-status Report
  • [Presentation] シアノアクリル基をアンカー基として分子末端に有するU字型増感色素の合成と色素増感太陽電池への応用2014

    • Author(s)
      佐野陽平,峯田翔平,前田荘志,八木繁幸,中澄博行
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Research-status Report
  • [Presentation] ナフタレンジイミド-スクアリリウム色素連結分子の合成と光・電気化学特性2014

    • Author(s)
      石田拓生,周僅,前田壮志,八木繁幸,中澄博行
    • Organizer
      第34回有機合成若手セミナー
    • Place of Presentation
      阪大豊中キャンパス(大阪府・豊中市)
    • Year and Date
      2014-08-05
    • Related Report
      2014 Research-status Report
  • [Presentation] アクセプター性吸着基を有する屈曲型スクアリリウム色素の合成と色素増感太陽電池への展開2014

    • Author(s)
      佐野陽平,前田壮志,八木繁幸,中澄博行
    • Organizer
      第34回有機合成若手セミナー
    • Place of Presentation
      阪大豊中キャンパス(大阪府・豊中市)
    • Year and Date
      2014-08-05
    • Related Report
      2014 Research-status Report
  • [Remarks] 有機機能化学研究グループHP

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka6/index.html

    • Related Report
      2015 Annual Research Report 2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2022-02-01  

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