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Development of novel polymerization technique and nano-reactor driven by size exclusion principle

Research Project

Project/Area Number 26620171
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionTohoku University

Principal Investigator

HIGUCHI TAKESHI  東北大学, 多元物質科学研究所, 助教 (50547304)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords高分子微粒子 / ミクロ相分離 / コアシェル粒子 / 中空粒子 / 高分子合成 / ミクロ相分離構造
Outline of Final Research Achievements

In this research, we are aimed at a development of novel polymerization technique, which can produce a polymer having narrow molecular weight distribution with high reproducibility and low environmental burden. To achive this polymerization, we designed a hollow polymeric particle with surface nano-channels and catalysts for polymerization reaction. The core-shell particles having cylindrical structures with several tens of nm diameter were successfully prepared from homopolymer and block copolymer blend system. The hollow particles with spherical pores with 50 nm diameter at the particle surfaces were also prepared. Furthermore, one-pod synthesis of metal phthalocyanine nano-crystals were carried out by using a nano-reactor based on the research concept, that is a synthesis of organic compound in a nano-sized confined space.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (7 results)

All 2016 2015 2014

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 2 results) Presentation (5 results) (of which Invited: 1 results)

  • [Journal Article] Controlled incorporation behavior of gold nanoparticles into ABC triblock terpolymer with double-helical morphology2016

    • Author(s)
      Takeshi Higuchi, Hidekazu Sugimori, Hiroshi Yabu, Hiroshi Jinnai
    • Journal Title

      Polymer Journal

      Volume: 48 Issue: 4 Pages: 509-515

    • DOI

      10.1038/pj.2016.19

    • NAID

      40020778419

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] One-pot UV-assisted Synthesis of Metal Phthalocyanine Nanocrystals2015

    • Author(s)
      Yuta Saito, Takeshi Higuchi, Hiroshi Yabu
    • Journal Title

      ChemNanoMat

      Volume: 1 Issue: 2 Pages: 1-5

    • DOI

      10.1002/cnma.201500017

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 金属フタロシアニンナノ結晶の One-pot 合成2015

    • Author(s)
      樋口剛志、齊藤祐太、平井裕太郎、藪浩
    • Organizer
      2015高分子学会東北支部研究発表会
    • Place of Presentation
      秋田大学 (秋田市)
    • Year and Date
      2015-11-12
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] ジブロック共重合体微粒子の内部相分離構造に関する実験・理論面からの考察2015

    • Author(s)
      樋口剛志、Marco Pinna、Andrei V. Zvelindovsky、陣内浩司、藪浩
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター (札幌市)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] UV光照射による金属フタロシアニンナノ結晶のOne-pot合成2015

    • Author(s)
      樋口剛志、齊藤祐太、杉森秀一、藪浩
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] ポリマー微粒子の表面機能化と無機ナノ粒子とのハイブリッド化による機能性材料の作製2014

    • Author(s)
      佐藤浩喜、金原雅晃、齊藤祐太、樋口剛志、藪浩
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] Au nanoparticles/polymer composite particles fabricated via electrostatic interaction2014

    • Author(s)
      金原雅晃、樋口剛志、下村政嗣、陣内浩司、藪浩
    • Organizer
      IUMRS-ICA 2014
    • Place of Presentation
      福岡大学
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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