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Development of Mechanochromic Non-woven Fabrics by Electro-spinning

Research Project

Project/Area Number 26620175
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

Otsuka Hideyuki  東京工業大学, 理工学研究科, 教授 (00293051)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsナノファイバー / 高分子機能材料 / 反応性高分子 / エレクトロスピニング / メカノクロミズム
Outline of Final Research Achievements

Mechanochromic polymers, which change their colors in response to mechanical stress, have attracted much attention and experienced significant progress in recent years. One of the representative strategies for developing mechanochromic polymers is to incorporate mechanically sensitive units into the polymer chains. Previously, we found that diarylbibenzofuranone (DABBF) mechanically undergoes homolytic bond dissociation of the central carbon-carbon bonds to corresponding carbon radicals, which show blue color. In the present study, we synthesized some mechanochromic polymers by introducing DABBF units into the main chains. We also found that non-woven fabrics of the mechanochromic polymers can be developed by electro-spinning.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (21 results)

All 2015 2014 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 4 results,  Open Access: 1 results) Presentation (14 results) (of which Int'l Joint Research: 4 results,  Invited: 11 results) Remarks (2 results)

  • [Journal Article] Mechanophores with a Reversible Radical System and Freezing-Induced Mechanochemistry in Polymer Solutions and Gels2015

    • Author(s)
      Keiichi Imato, Atsushi Irie, Takahiro Kosuge, Tomoyuki Ohishi, Masamichi Nishihara, Atsushi Takahara, Hideyuki Otsuka
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 54 Issue: 21 Pages: 6168-6172

    • DOI

      10.1002/anie.201412413

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Diarylbibenzofuranone-Based Dynamic Covalent Polymer Gels Prepared via Radical Polymerization and Subsequent Polymer Reaction2015

    • Author(s)
      Keiichi Imato, Masamichi Nishihara, Atsushi Irie, Atsushi Takahara, Hideyuki Otsuka
    • Journal Title

      Gels

      Volume: 1 Issue: 1 Pages: 58-68

    • DOI

      10.3390/gels1010058

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Self-Healing of a Cross-Linked Polymer with Dynamic Covalent Linkages at Mild Temperature and Evaluation at Macroscopic and Molecular Levels2015

    • Author(s)
      Keiichi Imato, Atsushi Takahara, Hideyuki Otsuka
    • Journal Title

      Macromolecules

      Volume: 48 Issue: 16 Pages: 5632-5639

    • DOI

      10.1021/acs.macromol.5b00809

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Mechanochromic Dynamic Covalent Elastomers: Quantitative Stress Evaluation and Autonomous Recovery2015

    • Author(s)
      Keiichi Imato, Takeshi Kanehara, Tomoyuki Ohishi, Masamichi Nishihara, Hirofumi Yajima, Masayoshi Ito, Atsushi Takahara, Hideyuki Otsuka
    • Journal Title

      ACS Macro Lett.

      Volume: 4 Issue: 11 Pages: 1307-1311

    • DOI

      10.1021/acsmacrolett.5b00717

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 高分子鎖を介して分子を引っ張る!-力で生じる化学反応2015

    • Author(s)
      今任景一, 後関頼太, 大塚英幸
    • Journal Title

      化学

      Volume: 70 Pages: 70-71

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Molecular Design of Dynamic Covalent Polymers for Sustainability2015

    • Author(s)
      Hideyuki Otsuka
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015)
    • Place of Presentation
      Hawaii Convention Center, Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and Mechanochromic Property of Crystalline Polymers with Diarylbibenzofuranone2015

    • Author(s)
      Shigeki Furukawa, Hironori Oka, Raita Goseki, Hideyuki Otsuka
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015)
    • Place of Presentation
      Hawaii Convention Center, Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 動的共有結合化学を利用する高分子反応系の開発 ~自己修復性および力学応答性を中心に~2015

    • Author(s)
      大塚英幸
    • Organizer
      平成27年度日本接着学会東北支部講演会
    • Place of Presentation
      日本大学工学部
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Polymer Reactions Based on Mechanocleavable Dynamic Covalent Linkages2015

    • Author(s)
      Hideyuki Otsuka, Hironori Oka, Raita Goseki
    • Organizer
      Japan-Korea Joint Symposium 2015 (JKJS 2015)
    • Place of Presentation
      Kitakyushu, Japan
    • Year and Date
      2015-10-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Reorganizable and Self-healing Networked Materials Based on Dynamic Covalent Chemistry2015

    • Author(s)
      Hideyuki Otsuka, Keiichi Imato, Raita Goseki
    • Organizer
      The 11th International Conference on Advanced Polymers via Macromolecular Engineering (APME 2015)
    • Place of Presentation
      Pacifico Yokohama, Yokohama, Japan
    • Year and Date
      2015-10-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 危険を知らせて修復も!化学の力で次世代高分子へ挑む2015

    • Author(s)
      大塚英幸
    • Organizer
      第5回CSJ化学フェスタ2015
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 動的共有結合化学に基づく高分子の自己修復2015

    • Author(s)
      大塚英幸
    • Organizer
      第10回TPE技術研究会公開講演会
    • Place of Presentation
      三菱ビル
    • Year and Date
      2015-10-02
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 動的共有結合化学により進化する高分子反応 ~自己修復性および力学応答性を中心に~2015

    • Author(s)
      大塚英幸
    • Organizer
      第41回中国四国地区高分子講座
    • Place of Presentation
      島根大学松江キャンパス
    • Year and Date
      2015-09-18
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 動的共有結合ポリマー、-ゲル・エラストマーを中心に-2015

    • Author(s)
      大塚英幸
    • Organizer
      第119回配合技術研究分科会
    • Place of Presentation
      日本ゴム協会会議室
    • Year and Date
      2015-05-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 動的共有結合化学が拓く新しい反応性高分子デザイン2015

    • Author(s)
      大塚英幸
    • Organizer
      第19回関西若手高分子セミナー
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2015-05-12
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Polymer Reactions Based on Dynamic Covalent Chemistry2014

    • Author(s)
      Hideyuki Otsuka
    • Organizer
      The 10th SPSJ International Polymer Conference (IPC 2014)
    • Place of Presentation
      Epochal Tsukuba, Ibaraki, Japan
    • Year and Date
      2014-12-02 – 2014-12-05
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Dynamic Covalent Polymers: A New Class of Reactive Polymers Containing Reversibly Cleavable and Exchangeable Covalent Bonds2014

    • Author(s)
      Hideyuki Otsuka
    • Organizer
      2014 Japan-China Advanced Materials and Nanotechnology Symposium -2014 Tokyo Tech - Tsinghua Univ. Joint Symposium on Advanced Materials
    • Place of Presentation
      Hayama, Kanagawa, Japan
    • Year and Date
      2014-11-13 – 2014-11-15
    • Related Report
      2014 Research-status Report
  • [Presentation] Freezing-induced Mechanochromism in polymer gels cross-linked by Diarylbibenzofuranone-based dynamic covalent bonds2014

    • Author(s)
      Keiichi Imato, Atsushi Takahara, Hideyuki Otsuka
    • Organizer
      Joint Symposium of Polymer Networks Group and Research Group on Polymer Gels (PN&G2014)
    • Place of Presentation
      The University of Tokyo, Tokyo, Japan
    • Year and Date
      2014-11-10 – 2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Reorganizable, Self-healing, and Mechanochromic Soft Materials Based on Dynamic Covalent Chemistry2014

    • Author(s)
      Hideyuki Otsuka
    • Organizer
      NIMS Conference 2014
    • Place of Presentation
      Epochal Tsukuba, Ibaraki, Japan
    • Year and Date
      2014-06-30 – 2014-07-03
    • Related Report
      2014 Research-status Report
    • Invited
  • [Remarks] 大塚研究室ホームページ

    • URL

      http://www.op.titech.ac.jp/polymer/lab/otsuka/index.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 東京工業大学 大学院理工学研究科 大塚研究室ホームページ

    • URL

      http://www.op.titech.ac.jp/polymer/lab/otsuka/index.html

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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